Avery Dennison Corporation

Graham Yeadon

Paul Keller

Alfredo Mueller

Jos Van Noort

Roger Maerki

Prakash Mallya

Eric L Bartholomew

Christopher Lee Lester

Ivan S Lee

Chan U Ko

Shiaonung J Su

Peter J Heederik

Dominique Wouters

Ivan S P Lee

Ian Brown

Lenneke Van Der Bent

This invention relates to removable pressure sensitive adhesive compositions and constructions that contain an emulsion acrylic pressure sensitive adhesive copolymer of a plurality of acrylic monomers and at least one polymerizable acid. The invention further relates to labels, particularly removable polymeric labels for use on reusable containers.

Emulsion adhesive for washable film

Water resistant, acrylic emulsion pressure sensitive adhesive polymers containing particles having a mean 'volume-average' particle diameter of greater than about 210 nm for use in label and tape application are provided. The emulsion polymers exhibit an increase in opacity of less than about 10%.

Water whitening-resistant pressure sensitive adhesives

A method for recycling materials having an affixed label is disclosed. The present invention also includes labels and adhesives that is readily removable from a material during a process for recycling the material.

Recycling processes and labels and adhesives and use therein

Tackfied PSAs and tapes comprising a copolymer based on an acrylic backbone, with a glycidyl monomer, unsaturated carboxylic acid monomer and a tackifier, said adhesives being dual curable and having combination of outstanding peel adhesion on the LSE substrates, high temperature shear performance, excellent stress relieving properties and excellent converting properties.

Dual crosslinked tackified pressure sensitive adhesive

Improved, removable PSA compositions and constructions contain an emulsion acrylic PSA copolymer of a plurality of acrylic monomers and at least one multifunctional crosslinking monomer, compounded with a wax and a plasticizer. Peel forces required to remove the constructions from a variety of substrates are notably smaller than those required to remove comparable compositions containing no crosslinking monomer.

Removable emulsion pressure-sensitive adhesives

Inherently tacky, pressure-sensitive adhesive compositions useful in marking film applications are provided. The compositions comprise polymer particles prepared by emulsion polymerization of at least one monomer mixture. The monomer mixture comprises at least one alkyl acrylate, the alkyl group of which has from about 4 to 12 carbon atoms, preferably in an amount of from about 73% to 90% by weight, at least one unsaturated carboxylic acid containing from about 3 to 5 carbon atoms, preferably in an amount of from about 2% to 12% by weight, and at least one hard monomer, preferably present in an amount of from about 5% to 15% by weight. The particles have a mean diameter of about 300 nm or less, as determined by laser light scattering. Preferably the hard monomer comprises a styrenic monomer, more preferably both a styrenic monomer and an alkyl methacrylate. In some embodiments, the compositions are prepared by sequential polymerization of the first and second monomer charges. The compositions may also contain one or more internal or external crosslinkers.

Pressure-sensitive adhesives for marking films

Repulpable PSA compositions and constructions that exhibit high adhesive performance on a wide range of substrates are provided. In one embodiment, a PSA composition comprises a blend of two emulsion acrylic copolymers. The first type is a repulpable, emulsion acrylic copolymer that passes TAPPI UM 213. Preferably, the copolymer is prepared by sequential polymerization. The second type of copolymer is a non-repulpable, gpp or removable, repositionable, emulsion acrylic copolymer, also preferably prepared by sequential polymerization. The PSA compositions are inherently tacky and can be used in labels and tapes. In addition, they can be added to other PSAs as external tackifiers.

Growing community of inventors

Marbach, Switzerland

Graham Yeadon