Ethyl Petroleum Additives, Inc.

Graeme M Wallace

Julia C Poat

David K Walters

Ian MacPherson

James P Simmonds

Hydrocarbonaceous fuels and additive compositions therefor which comprise: a) one or more fuel-soluble manganese carbonyl compounds; and b) one or more fuel-soluble alkali or alkaline earth metal-containing neutral or basic detergent salts. These compositions preferably contain, in addition to components a) and b) above, one or more of the following: c) one or more fuel-soluble ashless dispersants; d) at least one fuel-soluble demulsifying agent; e) at least one aliphatic or cycloaliphatic amine; and f) at least one metal deactivator. The compositions possess improved combustion characteristics (e.g., formation of less soot, smoke, carbonaceous products and/or noxious emissions), and form on combustion carbonaceous products of reduced acidity. The deposition of sludge on critical engine or burner parts or surfaces is reduced and the fuels have improved stability and demulsibility characteristics. And the fuel compositions can result in decreased fuel consumption in diesel engines.

Hydrocarbonaceous fuel compositions and additives therefor

In a motor vehicle, especially a heavy duty motor vehicle, having a transmission equipped with at least one cone-type synchronizer and an axle or differential gearing, the same lubricant is used for both such mechanisms. The lubricant has a viscosity grade level of from SAE 75W90 to SAE 85W140 and comprises base oil containing at least (i) Mannich base ashless dispersant; (ii) metal-free, sulphur-containing antiwear and/or extreme pressure agent; (iii) metal-free, phosphorus-containing and nitrogen-containing antiwear and/or extreme pressure agent; and (iv) overbased alkali or alkaline earth metal carboxylate, sulphonate or sulphurized phenate having a TBN of at least 145. The lubricant contains at most, if any, 100 ppm of metal as one or more metal-containing additive components other than (iv).

Use of transmission and gear oil lubricants having enhanced friction

Heavy diesel fuels, especially those containing sulphur and intended for marine or railroad use, are improved by incorporation therein of a combination of a cyclomatic manganese tricarbonyl and an ashless dispersant and optionally an antioxidant. Diesel fuels so modified show improved combustion characteristics and fuel economy.

Diesel fuel compositions

The frictional properties of gear oils are improved by including at least one overbased alkali or alkaline earth metal carboxylate, sulphonate or sulphurized phenate having a TBN of at least 200 in a gear oil which comprises: oil of lubricating viscosity at least 80% by volume of which is mineral oil, synthetic ester oil or a mixture thereof; Mannich base ashless dispersant; metal-free, sulphur-containing antiwear and/or extreme pressure agent; and metal-free, phosphorus-containing and nitrogen-containing antiwear and/or extreme pressure agent. The resultant gear oils exhibit excellent performance when used in synchromesh-based transmissions.

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Wokingham, United Kingdom

Graeme M Wallace