W. L. Gore & Associates, Inc.

Glenn W Crowther

Robert L Henn

Christopher T Hyde

A storage stable adhesive mixture of hexamethylenediamine carbamate and the reaction product of ethylene/propylene oxide polyol and a polyurethane prepolymer of diphenyl methane diisocyanate, polytetramethylene glycol, and optionally, 1,4-butanediol; and a process for using the adhesive to laminate fabric to polymeric membrane is also described.

Carbamate/urethane composition and textile lamination process

The present invention provides a two component polyurethane system with excellent wetting properties for casting a supported or unsupported, expanded polytetrafluoroethylene structure. It consists essentially of a polyisocyanate component having an isocyanate functionality of 2.2 or less and a polyol blend having an overall hydroxyl functionality of 2.2 or less and a viscosity of less than 500 cps., preferably 200 cps. or less. The polyol blend consists essentially of (i) a linear polyether or polyester (about 200-2500 molecular weight), (ii) a diol or triol (less than 200 molecular weight), and (iii) a catalyst in an amount sufficient to provide gelling at greater than 2 minutes and less than 10 minutes. The isocyanate to hydroxyl ratio is between 0.95:1 and 1.10:1. In some cases, it is desirable to include selected siloxane surfactants when polyol blends with the higher viscosities, i.e., about 200-500 cps., are used. The casting system is useful for making membrane filters.

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Newark, DE, United States of America

Glenn W Crowther