Dow Global Technolgoies LLC

Ddp Speciality Electronic Materials Us, LLC

Glenn G Eagle

Andreas Lutz

Gary Lee Jialanella

Eric E Cole

Michael R Golden

Shaoguang Feng

Yan Fei Liu

Ming Ming

Robert D J Froese

Daniel Schneider

Rajesh H Turakhia

Robert Froese

Michelle L Boven

Dakai D Ren

Jason C Brodil

Yanli Feng

Zhicheng Li

Robert D Froese

Epoxy adhesives are made using core-shell rubbers and small amounts if any of other elastomeric materials. The epoxy adhesives contain a mixture of latent curing agents and/or high levels of calcium oxide. The adhesives exhibit excellent bonding properties even when an open or closed bead is exposed to humid air for prolonged periods before the epoxy adhesive is cured.

Epoxy adhesive resistant to open bead humidity exposure

Aspects of the present invention provide a one component epoxy adhesive composition having improved impact resistance at low temperatures, such as &#x2212;40&#xb0; C. or less. In a first aspect, the adhesive includes one or more epoxy resins; at least one polyurethane based toughener; at least one amphipathic block copolymer; and one or more epoxy curing agents. In a further, aspect epoxy adhesive compositions having improved wash off resistance are also provided.

Crash durable epoxy adhesive compositions having improved low-temperature impact resistance and wash off resistance

An uncured adhesive contains 2 to 10 weight percent of particles of a semi-crystalline organic material, preferably a polyester having a number-average molecular weight of 2000 to 10,000, a hydroxyl number of 10 to 60, and a melting temperature of 50 to 125&#xb0; C. The adhesive is applied by heating it just prior to application, to melt the particles. After application, the adhesive is cooled to below the melting temperature of the semi-crystalline organic material, and then cured. The process allows the adhesive to be stored and pumped at ambient temperatures, due to the moderate viscosity of the material. Upon melting and re-cooling the semi-crystalline organic material, the adhesive assumes a high yield stress that imparts very good wash-off resistance. In preferred embodiments, the adhesive composition includes an epoxy resin and an epoxy curing agent.

Structural adhesives having improved wash-off resistance and method for dispensing same

A new adhesive composition containing glass beads and having unique properties in automotive related applications. The method of making such new adhesive composition.

Adhesive composition with glass spheres

Epoxy adhesive compositions contain a heat-activatable catalyst. The heat-activatable catalyst includes a tertiary amine catalyst and a novolac resin that has a weight average molecular weight of at least 3000. One-component epoxy adhesive formulations that contain the heat-activatable catalyst have unexpectedly good storage stability.

Storage-stable heat-activated tertiary amine catalysts for epoxy resins

A heat-curable structural adhesive includes a non-rubber-modified epoxy resin, a reaction product of a carboxyl-or amine-terminated butadiene polymer or copolymer and a bisphenol F-based epoxy resin, a elastomeric toughener containing capped isocyanate groups, one or more epoxy curing agents a moisture scavenger and a heat activatable catalyst comprising a mixture of a solid or liquid tertiary amine compound that has a boiling temperature of at least 130&#xb0; C. and a novolac resin. The structural adhesive develops excellent bonding properties when cured at moderate temperatures, especially from 120 to 170&#xb0; C., and in addition performs very well in environmental aging stress testing. The adhesive is particularly good for bonding aluminum to another metal, or bonding aluminum to aluminum.

Crash-durable adhesive with enhanced stress durability

The present invention provides low polyphenols (such as bisphenol A) tougheners for epoxy adhesives. The tougheners, and adhesives comprising the tougheners exhibit enhanced viscosity stability, e.g., compared to tougheners prepared from higher amounts of bisphenol A (and epoxy adhesives comprising them).

Epoxy resin with enhanced viscosity stability and use thereof

A heat-curable structural adhesive includes at least one non-rubber-modified epoxy resin; an optional rubber or toughener, one or more epoxy curing agents, one or more epoxy curing catalysts; and a flame retardant mixture that includes (i) alumina trihydrate, (ii) zinc borate and (iii) melamine or a melamine derivative. The structural adhesive is useful for bonding metals to other materials or metals to other metals. The structural adhesive strongly resists ignition when welding is performed in the presence of the uncured material, and does not interfere significantly with weld performance.

Flame retardant structural epoxy resin adhesives and process for bonding metal members

Epoxy adhesive compositions containing a rubber-modified epoxy resin contain a bisphenol. The bisphenol can be pre-reacted with the rubber-modified epoxy resin to advance the resin. The adhesives are resistant to thermal degradation as can occur in so-called 'overbake' conditions, in which the adhesive is heated to high temperatures for prolonged periods of time. In addition, expanded microballoons are included in epoxy structural adhesives to promote a desired fracture mode.

Heat-resistant structural epoxy resins

The invention is a process for the preparation of article comprising placing a film on each inner surface of each part of a two part mold; placing an article in the mold with film located between the surface of the mold and the article such that there is a small space between the article and the surface of the mold; closing the mold about the article; injecting between the film and the article an expandable plastic material under conditions that the article is coated with the expandable material and the expandable material does not expand; removing the plastic article with the expandable material coated thereon with the two films attached to the expandable plastic material. In another embodiment the invention is an article comprising a shaped plastic article; an expandable material coated in the shaped plastic article; and a film covering the material coated shaped plastic article. In another embodiment the invention is a method of reinforcing a structural member which comprises inserting an article according to this invention into a cavity of the structural member and heating the structural member and the article to a temperature at which the expandable plastic material expands and the film or the expandable material bonds to the inner surface of the structural member so as to fix the location of the article in the structural member.

Structural reinforcement article and process for preparation thereof

An expandable adhesive for a structural foam insert useful for vehicular reinforcement is described. The adhesive is characterized by containing a viscosity enhancing agent such as a polymethylmethacrylate, which results in a cured adhesive having unusually small voids and unusually high Young's modulus.

Growing community of inventors

Bloomfield Hills, MI, United States of America

Glenn G Eagle