Bromine Compounds Limited

Imi Tami Institute for Research and Development Ltd.

Imi Tami Insitute for Research and Development

Gideon Friedman

Eyal Barnea

Ron Frim

Eyal Ginzberg

Akiva Mozes

Hugo Keselman

Cornelis Petrus Langeveld

Michael Bonan

Mira Bergstein Freiberg

David Fuks

Sarit Sarmili

A solvent extraction process for recovering bromide from a sulfate-containing aqueous stream, the process comprises an extraction step wherein said aqueous stream is mixed with an extraction medium comprising a tertiary amine extractant dissolved in one or more water-immiscible organic solvents, wherein said mixing is carried out in a strongly acidic environment, thereby forming bromide-containing extract and a raffinate with a reduced bromide level, wherein the bromide-containing extract is optionally treated to further minimize the presence of sulfate and is subsequently combined with an aqueous calcium source to form calcium bromide.

Recovery of bromide from sulfate comprising aqueous streams

A process for producing KNO3 from polyhalite to is disclosed. In a preferred embodiment, the process comprises steps of (a) contacting polyhalite with HNO3; (b) adding Ca(OH)2 to the solution, thereby precipitating as CaSO4 at least part of the sulfate present in said solution; (c) precipitating as Mg(OH)2 at least part of the Mg2+ remaining in said solution by further addition of Ca(OH)2 to the remaining solution; (d) concentrating the solution, thereby precipitating as a sulfate compound at least part of the sulfate remaining in solution; (e) separating at least part of the NaCl from the solution remaining; and (f) crystallizing as solid KNO3 at least part of the K+ and NO3-contained in the solution. The process enables direct conversion of polyhalite to KNO3 of purity exceeding 98.5% and that is essentially free of magnesium and sulfate impurities.

[object Object]

A method for the production of KNOfrom polyhalite is provided. The method comprises steps of decomposing said polyhalite into syngenite, gypsum, and soluble components, treating the solid decomposition products sequentially with HNOand Ca basic compound, precipitating the CaSOthus formed, and crystallizing the KNOfrom the solution remaining. The method recovers up to 75% of the potassium present in the raw polyhalite as KNOand substantially all of the remainder as a potassium magnesium sulfate salt.

Process for production of commercial quality potassium nitrate from polyhalite

Growing community of inventors

Haifa, Israel

Gideon Friedman