Snia Viscosa Societa Nazionale Industria Applicazioni Viscosa S.p.a.

Societa Nazionale Industria Applicazioni Viscosa S.p.a.

Snia Viscosa

Giancarlo Matera

Antonino Cavallaro

Giorgio Cazzaro

Domenico Malgeri

Marina Zani

Luigi Giuffre

Giancarlo Sioli

Antonio Salan

Franco Righi

Modacrylic fibres from acrylonitrile, vinylidene chloride, and a sulphonated comonomer, having reduced inflammability and high glossiness and dye yield are prepared by wet spinning a polyblend obtained by mixing two binary copolymers, the first from acrylonitrile and the sulphonated comonomer, and the second from acrylonitrile and vinylidene chloride. As the sulphonated comonomer, a significantly homopolymerizable monomer is used, viz. a monomer which homopolymerizes with a conversion of at least 30-40% by weight, in the presence of azobisisobutyronitrile catalyst, under given standard reaction conditions. Preferred sulphonated monomers are acid or salts of the acrylamidoalkanesulphonic series. The spinning dope is a polyblend solution in an organic solvent chosen among dimethylformamide, dimethylacetamide, and dimethylsulphoxide, mixed with water.

Process for producing glossy fibres of the modacrylic type having

A method for preparing flame-resisting modacrylic fibers containing pentaent antimony oxide is described wherein the antimony oxide is suspended in a mixture of water and an organic solvent selected from dimethylformamide and dimethylacetamide and the suspension is then mixed with the viscose solution of the modacrylic polymeric material to be spun. The process yield high luster, flame-resisting modacrylic fibre of the 'L.O.I. uprated' type.

Process for manufacturing modacrylic fibers having high luster, thermal

Modacrylic fibers having high retraction, reduced inflammability and high glossiness, prepared by wet spinning a solution, in an organic spinning solvent miscible with water, of a mixture of copolymers from acrylonitrile, vinylidene chloride, at least a vinyl ester and at least an unsaturated monomer containing at least a sulphonic group, the acrylonitrile units being from 50% to 85% by weight and the vinyl ester units from 3% to 6% by weight; hot drawing the coagulated fiber in a mixture of water and spinning solvent; drying the fiber in hot air while leaving it free concurrently to contract; and subsequently further hot drawing it in air.

Process for spinning modacrylic fiber having high retraction and reduced

Textile fibers having reduced inflammability and high luster, constituted copolymers of acrylonitrile, vinylidene chloride and a significantly homopolymerizable sulphonic comonomer are described. Significantly homopolymerizable comonomers are defined as monomers which homopolymerize with a conversion above 30.degree.-40.degree. under standard conditions set forth in the specification. A preferred class of such comonomers are the derivatives of acrylamidoalkanesulphonic acids, e.g. 2-acrylamido-2-methylpropane-sodium sulphonate. The fibers are spun from spinning dopes containing said copolymers in solution in organic solvent miscible with water and less than 4% of water. Said spinning dopes can be obtained by preparing a binary copolymer of acrylonitrile and the sulphonic monomer, in solution in the solvent, mixing the solution with a solution of acrylonitrile and vinylidene monomers in the same solvent, and subjecting the mixture to copolymerization. The copolymers finally obtained contain 50-85% of acrylonitrile, 13.5-46.5% of vinylidene chloride, and 1.5-3.5% of the sulphonic comonomer, the percentages being by weight.

Fiber from acrylonitrile copolymers having reduced inflammability,

Modacrylic fibres from acrylonitrile, vinylidene chloride, and a sulphona comonomer, having reduced inflammability and high glossiness and dye yield are prepared by wet spinnning a polybend obtained by mixing two binary copolymers, the first from acrylonitrile and the sulphonated comonomer, and the second from acrylonitrile and vinylidene chloride. As the sulphonated comonomer, a significantly homopolymerizable monomer is used, viz. a monomer which homopolymerizes with a conversion of at least 30-40% by weight, in the presence of azobisisobutyronitrile catalyst, under given standard reaction conditions. Preferred sulphonated monomers are acid or salts of the acrylamidoalkanesulphonic series. The spinning dope is a polyblend solution in an organic solvent chosen among dimethylformamide, dimethylacetamide, and dimethylsulphoxide, mixed with water.

Glossy fibres of the modacrylic type having reduced inflammability, and

A method is disclosed for the preparation of alicyclic anhydrides, useful intermediates in the preparation of alicyclic ketenes which can be converted into lactams. The instant method comprises heat-treating an alicyclic acid in a metallic reactor, free of nickel, under subatmospheric pressure. A catalyst, such as an alkyl ester of selenphosphoric acid, has given good results.

Growing community of inventors

Monza, Italy

Giancarlo Matera