Air Products and Chemicals, Inc.

Gottier, Gerry N.

Gerry N Gottier

Donn Michael Herron

David M Nicholas

Thomas M Roden

A crude helium product is produced from a natural gas stream containing helium by rectification of the feed gas in a dephlegmator heat exchanger. The process is fully auto-refrigerated, and is capable of achieving a helium recovery of 99% without the use of a recycle compressor or a heat pump compressor. A nitrogen product stream can be produced by addition of a second rectification circuit in the dephlegmator heat exchanger.

Dephlegmator process for the recovery of helium

The present invention is a process for prefractionating a pressurized, helium-containing feed gas mixture (typically containing helium, natural gas and nitrogen) to produce a helium-enriched stream which comprises the following steps: (a) the pressurized, helium-containing feed gas mixture is liquefied and subcooled by indirect heat exchange; (b) the liquefied, subcooled, pressurized, helium-containing feed gas mixture is expanded whereby it is partially vaporized, thus producing a partially vaporized frationation feed stream; (c) the partially vaporized frationation feed stream is stripped in a cryogenic distillation column thereby producing as an overhead, the helium-enriched stream, and a bottoms liquid, the helium-lean stream; and (d) the cryogenic distillation column is reboiled by vaporizing at least a portion of the helium-lean stream. The present invention is also applicable as an improvement to a process for the production of a crude helium product (i.e.,&gt;30 vol % helium).

Low pressure stripping process for production of crude helium

High purity methane is recovered from a fuel gas stream containing the same in admixture with mainly nitrogen and carbon dioxide, by first removing the carbon dioxide by selective adsorption in a PSA system and separating the remaining nitrogen from the methane by cryogenic distillation, the rejected nitrogen being employed for purging the CO.sub.2 -laden adsorbent beds of the PSA system. Cyclic regeneration of the sorbent-laden bed may entail nitrogen purge with or without including a carbon dioxide rinse, or the nitrogen purge of the sorbent-laden bed may be used in combination with pressure let-down by gas withdrawal into one or more companion beds.

Hydrocarbon recovery from fuel gas

An absorptive distillation using a C.sub.7 to C.sub.8 physical solvent without overhead condenser-reflux duty is described for separation of carbon dioxide from methane, wherein the separation preferentially uses heat energy in contrast to mechanical energy or power.

Process for removal of carbon dioxide from mixtures containing carbon

A process is set forth for the separation of carbon dioxide from propane and higher alkanes using a carbon dioxide-loaded lean oil solvent and higher solvent flows and heat utilizations rather than mechanical energy utilization. A high pressure carbon dioxide product is produced, making the invention valuable in carbon dioxide miscible flood enhanced petroleum recovery operations.

Growing community of inventors

Emmaus, PA, United States of America

Gerry N Gottier