Other

Edr Acquisition Corp.

Gerhard K Kunz

George L Dimotsis

Richard L Sampson

Johannes Goebel

An electrolytic process and apparatus are disclosed for regenerating separate bed ion exchange resins used to demineralize aqueous solutions, preferably softened water, without the use of additional chemicals. The cation exchanger is regenerated by applying a DC electric voltage between an anode and a cathode across the cation exchanger whereby hydrogen ions produced at the anode displace cations previously absorbed on the cation exchanger during the previous demineralization cycle. The displaced cations move towards the cathode under the influence of the electric voltage and there form a caustic solution with hydroxyl ions produced by the cathode. The cathodically generated caustic solution is then used to chemically regenerate the anion exchanger in a traditional manner. Two embodiments of the invention are disclosed, one of which is an intermittent system of demineralization and regeneration and the other is a continuously operating system.

Process and device for demineralizing aqueous solutions using ion

A method of regenerating an ion exchanger which is used to treat a solution introduced to the ion exchanger in a downward charging direction. The ion exchanger comprises a non-constrained bed of ion exchange material in the form of ion exchange granules and has a concentration profile through the ion exchange material after the solution has been introduced to the ion exchanger in the charging direction. The method in one embodiment comprises passing a regenerating solution upwardly through the non-constrained bed of ion exchange material in an intermittent pulsed flow comprising a pulse or up flow of regenerating solution, a subsequent non-flow pause time, followed by a down flow pulse in a direction opposite to the up flow. The duration and velocity of the pulse or up flow of regenerating solution is sufficient to hydrodynamically lift the ion exchange granules a controlled distance through all of the ion exchange granules without causing significant mixing of ion exchange granules between different layers of the ion exchange material. The duration of the subsequent non-flow pause time being of short duration to allow for some perceptible settling of the ion exchange granules, with the down flow pulse being sufficient to reduce the sedimentation time of the ion exchange granules to a fraction of the normal settling time for the granules in the absence of the down flow pulse.

Countercurrent regeneration process

A method of regenerating an ion exchanger which is used to treat a solution introduced to the ion exchanger in a downward changing direction. The ion exchanger contains a non-constrained bed of ion exchange material in the form of ion exchange granules and has a concentration profile through the ion exchange material after solution has been introduced to the ion exchanger in the charging direction. The method of regenerating comprises passing a regenerating solution upwardly through the non-constrained bed of ion exchange material in an intermittent flow manner comprising an alternating up flow of regenerating solution followed by a down flow of liquid in a direction opposite to the up flow. The duration and velocity of the up flow of regenerating solution is sufficient to lift and generate a perceptible mixing of ion exchange materials in approximately the bottom portion of the ion exchange bed, with the down flow being sufficient to seat the bed very rapidly and terminate mixing.

Counter-current process for the rapid regeneration of ion exchange

The invention concerns an ion exchange process and system, particularly for the regeneration step following a softening or desalination of aqueous solutions. The regenerant solution is fed in an upward stream through the ion exchanger in a direction opposite to the charging direction, as a sequence of intermittent pulse intervals consisting of pulse flow followed by a period of no flow. During the pulse flow, there is limited hydrodynamic lifting of the ion exchange resin beds in layers, followed by subsequent sedimentation during the pause period, without mixing of the layers.

Process for ion exchangers, particularly for regeneration after

A temperature compensated differential between electrical conductivity measurements of a filter medium during passage therethrough of liquid being treated and measurement of the liquid alone after treatment, is utilized to calculate a conductivity ratio based on a reference value reflecting a minimum electrical conductivity measurement under ion saturation conditions in an ion-exchange filter. The filter is switched from an operational mode to a regenerating mode in response to detection of a predetermined conductivity ratio corresponding to approach of the filter to a clogged condition.

System for measuring the loading of an ion exchange filter

Process and apparatus adds counterions into the aqueous solution of an electrode chamber of an electrolytic desalination or demineralization unit. In the demineralization unit, oppositely charged ions are electrolytically generated within electrode chambers and defused into the stream of aqueous solution to be demineralized. In their migration in response to the application of an electric potential, the ion streams are subjected to displacement steps in cation and anion exchange masses separated by selectively permeable ion exchange membranes. A counterion-containing liquid is subjected to an electrical voltage field, separate or in conjunction with the desalination unit, and the counterions to be added are passed through a selectively permeable ion exchange membrane into the respective electrode chamber of chambers of the desalination unit.

Process and device for adding ions to liquids, particularly aqueous

Process and apparatus are provided for demineralizing aqueous solutions without using regenerating chemicals. Oppositely charged ions are electrolytically generated within electrode chambers and diffused into the stream of aqueous solution to be demineralized flowing in cross-current thereto. In their migration in response to the application of an electric potential, the ion streams are subjected to displacement steps in cation and anion exchange masses separated by selectively permeable ion exchange membranes. The aqueous solution alternately passes through the cation and anion exchange masses resulting in a demineralized aqueous stream and an enriched brine stream.

Process and apparatus for treatment of fluids, particularly

The invention refers to a process and a device for the performance of a process for the treatment of liquids, particularly for the demineralization of aqueous solutions, whereby the liquid being treated is conducted through successive chambers of treatment, wherein in a first stage of the treatment demineralization takes place by means of ion displacement and in a second stage of post-treatment by means of ion desorption the salts that are removed from the treated liquids are led into so-called brine chambers, and are washed out of these chambers into a channel or other receiver by means of a transporting liquid.

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Heiligenhaus, Germany

Gerhard K Kunz