Metallgesellschaft Aktiengesellschaft

Ruhrgas Aktiengesellschaft

Gerhard Baron

Carl Hafke

Herbert Bierbach

Rudolf Kohlen

Gunter Pockrandt

Eberhard Blaum

Martin Hirsch

Lothar Reh

Paul Rudolph

Heinz Jockel

Rainer Reimert

Friedrich-Wilhelm Moller

Dieter Sauter

Karlheinz Zolzer

Dietrich Engler

Wolfgang Sindel

A process of gasifying fine-grained solid fuels for the production of a product gas that contains hydrogen, carbon oxides and methane comprises a treatment with steam, oxygen and/or carbon dioxide in two interconnected gasifying stages under a pressure in the range from 2 to 150 bars and at temperatures of 500.degree. to 1500.degree. C. In the first gasifying stage, the fuel is gasified in a circulating fluidized bed by a treatment with gasifying stage. The residual solids which become available in the first gasifying stage are fed to the second gasifying stage and are virtually completely gasified therein, except for residual ash, by a treatment with a gasifying agent which includes oxygen. At least one-half of the product gas from the second gasifying stage is fed to the first gasifying stage and used as fluidizing fluid therein.

Process of gasifying fine-grained solid fuels

Briquettes made of mainly coal are described to which there has been added 10 to 30% by weight of ash (other than ash which is contained in the coal normally). The briquettes formed from such a mixture have strength which permits them to be subjected to gasification or carbonization in a fixed bed. Also described is a method for forming the briquettes.

Process of producing coal briquettes for gasification or devolatilization

A process for producing lean gases in which solid fuels are gasified under superatmospheric pressure by a treatment with free oxygen-containing gases, water vapor, and other gasifying agents. In the process, fuel and gasifying agent are caused to flow in opposite directions, about 1.5 to 3.5 kg of water vapor are added per standard m.sup.3 of free oxygen in the gasifying agent, about 70% of the lump coal to be gasified has a particle size from above 2 mm to about 30 mm and the remaining coal has a particle size below about 2 mm. The ballast content, consisting of water and ash, amounts to at least about 15% by weight, most of the mineral constituents have a particle size of about 2 to 30 mm and the ash which becomes available in the gasification process is withdrawn from the reactor shaft at temperatures above about 250.degree. C. Raw gas is withdrawn at temperatures above about 350.degree. C, coal is reacted in a water-cooled, double-walled reactor chamber and the resulting jacket steam is used to cool the grate and as a reactant. The rate at which steam consisting of extraneous steam and jacket steam is added to the gasifying agent is so adjusted in the above-mentioned range of about 1.5 to 3.5 kg per standard m.sup.3 of oxygen, that the nitrogen content of the dry raw product gas does not exceed about 50% by volume.

Process for producing a lean gas by the gasification of a fuel mainly in

A process and apparatus for the continuous gasification of fuels, which are mainly in lump form. The fuels are subjected to a superatmospheric pressure in a fixed bed treatment with a gasifying agent consisting of gases which contain free oxygen and water vapor and/or carbon dioxide in a water-cooled reactor housing. The housing contains a substantially conical rotary grate, which is rotatably mounted in the lower portion of the reactor housing and serves to discharge the gasifying agent into the reactor shaft and permits the removal of gasification residue from the shaft. The gasifying agent is positively distributed in correspondence with the quantity of fuel, which increases in the radial direction of the shaft resulting in an approximately uniform time of contact between the gas and fuel across the entire shaft area.

Process and apparatus for a pressure gasification of fuels mainly in

A process is disclosed for purifying raw gas produced by the gasification of solid fuels under superatmospheric pressure by treatment with gasifying agents containing water vapor and free oxygen. The raw gas contains dust and hydrocarbons and is at a temperature of 400.degree.-700.degree. C as it leaves the gas producer. The raw gas is purified by spraying in at least two scrubbing stages with virtually dustfree, highly dispersed scrubbing water at temperatures of 160.degree.-300.degree. C. In this manner, the gas is cooled to a temperature that is 0.degree.-20 C above the scrubbing water temperature and is saturated with water vapor in the scrubbing stages. Thereafter, the gas is subjected to centrifugal force to increase the relative velocity between gas and water droplets. The scrubbing water which contains dust and tar is withdrawn from each scrubbing stage. For the first scrubbing stage a cyclone-type scrubber can be used and for the second scrubbing stage a radial flow-type scrubber or a Venturi-type scrubber can be used.

Process for purifying raw gas from the gasification of solid fuels

In the production of a gas having a high calorific value and containing more than about 50% methane by volume by a process comprising gasifying a solid fuel under a pressure of about 5 - 150 bars by a treatment with oxygen and water vapor to produce a water vapor-containing raw gas at a temperature of about 350.degree.- 700.degree. C, the improvement which comprises further reacting the water vapor-containing raw gas under a pressure of about 5 - 150 bars with oxygen in a succeeding reactor to produce an intermediate product gas which contains mainly hydrogen, carbon dioxides, and methane and which leaves the reactor at a temperature between about 600.degree. and 950.degree. C, cooling the intermediate product gas and freeing the intermediate product gas from sulfur compounds. A dust fuel and/or liquid hydrocarbon can be added to the raw gas as such or after prereaction with oxygen, the addition advantageously taking place in the succeeding reactor. The reactor may contain a granular bed of a catalyst such as nickel, cobalt or chromium oxide and/or sulfide, and/or a contact material or catalyst support such as an oxide, spinel or silicate of aluminum and/or magnesium. The bed can be fluidized or otherwise mechanically moved.

Process of producing gases having a high calorific value

In the production of a synthesis gas comprising carbon monoxide and hydrogen, by a process comprising gasifying a solid fuel under a pressure of about 5-150 bars by a treatment with oxygen and water vapor to produce a water vapor-containing raw gas at a temperature of about 350.degree.-700.degree. C, the improvement which comprises further reacting the water vapor-containing raw gas under a pressure of about 5-150 bars with oxygen in a succeeding reactor to produce an intermediate product gas which leaves the reactor at a temperature between about 800.degree. C and 1400.degree. C, cooling the intermediate product gas, and freeing the intermediate product gas from sulfur compounds. A dust fuel and/or liquid hydrocarbon can be added to the raw gas as such or after prereaction with oxygen, the addition advantageously taking place in the succeeding reactor. The reactor may contain a granular bed of a catalyst such as nickel, cobalt or chromium oxide and/or sulfide, and/or a contact material or catalyst support such as an oxide, spinel or silicate of aluminum and/or magnesium. The bed can be fluidized or otherwise mechanically moved. The resulting gas is suited for use as a starting material in a methanol, ammonia, oxo or Fischer-Tropsch synthesis.

Process for producing synthesis gases

A device for feeding granular and dust coal to a coal-gasifying reactor which operates under a pressure of 5 to 150 bars. A stationary housing is connected to the coal inlet of the reactor and a lock chamber member is rotatedly mounted therein. The lock chamber member is movable between coal-receiving position and a coal-discharging position. The lock chamber member has at least one chamber which is open only at one end and contains a displacing device which extends approximately to the entrance of the chamber. The displacing device substantially prevents an ingress of product gas into the chamber when in the discharge position.

Feeder for coal-gasification reactor

Particulate solids are fed into a pressure reactor operated under a pressure of 5-150 bars by means of a guide cylinder which is secured to the reactor and surrounds the reactor inlet. The guide cylinder is adapted to be closed and a stationary feed conduit is directed towards the guide cylinder. A cylinder container, which is gastightly guided in the guide cylinder and has a bottom which is adapted to be closed, is moved up and down in the guide cylinder and when the bottom of the cylinder is open and the reactor inlet is closed the material flows out of the container into the guide cylinder whereas the bottom of the container is closed and the same is moved toward the open reactor inlet to displace gases into the reactor. The device for carrying out the process includes a guide cylinder secured to the reactor and surrounding the reactor inlet. The guide cylinder is adapted to be closed. A stationary feed conduit is directed towards the guide cylinder and a container is gastightly guided in the guide cylinder and is movable up and down therein and has a bottom that is adapted to be closed.

Process and apparatus for feeding particulate solids into a pressure

High-methane, low-hydrogen gas, interchangeable with natural gas, is prepared by reacting hydrocarbons with steam in the presence of a nickel-based catalyst at elevated temperatures and pressures. The hydrocarbons and the steam are fed to the reaction in mixture with product gas from the process from which substantially all carbon dioxide has been removed.

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Hofheim, Germany

Gerhard Baron