Cogema Compagnie Generale Des Matieres Nucleaires

Compagnie Generale Des Matieres Nucleaires

Cogema Compagnie General Des Matieres Nucleaires

Gerard Cauquil

Henri Chazot

Jacques Foos

Alain Guy

Rodolph Chomel

Marc Lemaire

Michel Sourrouille

Pierre Patigny

Jean-Paul Muller

Alain Vian

Pierre Epherre

The invention relates to the dissolving of plutonium and/or other radioactive elements in an aqueous solution by microwave heating. According to the invention, solid or liquid products containing plutonium and/or other radioactive elements are introduced into a container (7) containing an acid solution, comprising hydrofluoric acid and nitric solution, followed by the microwave heating of the solution containing these products using a chamber or tank (5) placed in a tight enclosure (1), which is supplied with microwaves by means of a coaxial cable or a waveguide (11) connected to the generator (9) located outside the enclosure. The solid products can be plutonium dioxide PuO.sub.2 or organic or mineral radioactive waste materials such as gloves, cellulose products, ion exchange resins, etc. The liquid products can be contaminated organic solvents such as tributyl phosphate in dodecane.

Process for dissolving plutonium and/or other radioactive elements

In order to automatically carry out the emptying and rinsing of non-recoverable bottles or flasks (78) made from a perforatable material such as polyethylene and e.g. containing a low activity solution (88), an apparatus is proposed making it possible to pass the inverted bottles under a double-walled needle (44). The needle (44), operated by a jack, perforates the bottom (82) of the flask (78). Compressed air is then injected into the bottle above the solution (88) through the annular passage formed between the walls of the needle (44), so as to discharge the solution through the central passage of the needle. The flask is then rinsed by injecting pressurized water in place of the compressed air. Finally, the rinsing water is discharged by a further compressed air injection. The emptied and rinsed flasks are then passed to a station, where they are directly discharged into a storage drum.

Apparatus for emptying and rinsing non-recoverable flasks containing a

Process for separating plutonium from uranium contained in a nitric acid aqueous solution from the reprocessing of irradiated fuels comprising plutonium, uranium and fission products by means of crown ethers. Nitric acid aqueous solution (5) containing plutonium, uranium and fission products is contacted at (2) with an organic liquid membrane (3) containing a crown ether. The uranium and plutonium are extracted in the liquid membrane (3) and then transferred by said membrane into a receiving solution (7), which becomes enriched with uranium, because the latter is transferred more rapidly than the plutonium. The crown ether can be DCH 18 C6 or DB 18 C6.

Process for separating by means of crown ethers the uranium and

For passing stepwise bottles (F, F') in front of different stations, in order to more particularly take liquid samples, the bottles are placed in receptacles formed on a plate (24). The rotation of the plate is ensured by a lifting support action using compressed air delivered by injectors (18). Immediate rotation stoppage is obtained when a hole (38) formed in plate (24) faces the end of an optical fiber, whereof the opposite end issues onto an optical detector. Associated with an automatic sampling and dilution system, the assembly can be advantageously installed in a glove box or shielded enclosure in the nuclear industry.

Stepwise advancing rotary conveyor and installation for taking liquid

Growing community of inventors

Bagnols sur Ceze, France

Gerard Cauquil