Polaroid Corporation

Presstek, Inc.

Gerald P Harwood, Jr

Michael S Viola

Yung T Chen

Eugene L Langlais

Xiaojia Z Wang

Richard J Murphy

Kenneth J McCarthy

Shawn P Lambert

Affinity transitions from hydrophobic to hydrophilic states, rather than ablation mechanisms, facilitate the creation of an imagewise lithographic pattern on a printing plate. In various embodiments, a lithographic printing member comprises a topmost 'imaging' layer that undergoes, in response to heat, a transition from a hydrophobic and oleophilic state to a hydrophilic state (which may or may not also be oleophilic); and a substrate disposed below the imaging layer. The affinity change in the imaging layer may be due essentially to a foaming agent therein. The foaming agent decomposes upon heating, creating a gas that foams the surface of the imaging layer. The resulting spongelike texture enables the surface to retain water, i.e., renders it hydrophilic.

Printing members having permeability-transition layers and related methods

The present invention provides a printing member having a single radiation-absorptive multiphase layer over a substrate layer that may be imaged with or without ablation.

Lithographic imaging with printing members having multiphase laser-responsive layers

An ink jet recording sheet comprises a support carrying an ink-receiving layer, this layer comprising a hydrophilic polymer, preferably poly(vinyl alcohol) and a poly(vinylbenzyl quaternary ammonium salt) of the formula: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 is independently alkyl of from 1 to 4 carbon atoms; each of R.sup.7, R.sup.8 and R.sup.9 is independently alkyl of from 1 to 18 carbon atoms and the total number of carbon atoms in R.sup.7, R.sup.8 and R.sup.9 is from 13 to 20; each M.sup.- is an anion; and each of a, b and c is the molar proportion of the respective repeating units.

Ink jet recording sheet

An ink jet recording sheet comprises a support carrying an ink-receiving layer, this layer comprising a mixture of a derivatized (preferably acetoacetylated) poly(vinyl alcohol) and a non-derivatized poly(vinyl alcohol). The ink-receiving layer preferably also comprises a poly(vinylbenzyl quaternary ammonium salt) and poly(vinylpyrrolidone).

An ink jet recording sheet comprises a support carrying an ink-receiving layer, this layer comprising a hydrophilic polymer, preferably poly(vinyl alcohol) and a poly(vinylpyridine). The images formed using this sheet display good water fastness.

Growing community of inventors

Billerica, MA, United States of America

Gerald P Harwood, Jr