Osi Specialties, Inc.

Union Carbide Corporation

Union Carbide Chemicals & Plastics Technology Corporation

Witco Corporation

Other

Asahi Glass Company, Limited

General Electric Company

Crompton Gmbh

Union Carbide Chemicals and Plastics Company, Inc.

Ck Witco Corporation

Gerald J Murphy

George A Policello

Seisaku Kumai

Yutaka Furukawa

Charles H Blevins

Paul L Matlock

Richard A Budnik

Curtis L Schilling, Jr

Anna M Czech

George H Greene

William B Herdle

Mami Kotera

Jeffrey A Cooke

Charles H Blevins, Ii

Bernard Kanner

Wojciech Grabowski

Angelo J Sabia

Robert G Eagar, Jr

Robert E Sheridan

Raymond L Cobb

Douglas J DeYoung

Jeffery A Cooke

Dorothy E Parker

Robert E Ruckle, Jr

Anna Czech

An arrangement for training a vehicle driver or improving driving ability having a sensor located in a position beneath a motor vehicle brake pedal. A warning indicator is connected to the sensor to provide a signal when the sensor detects that a driver's heel is not in contact with a floor of the vehicle during braking.

Driver control assistance sensor and method

The present invention teaches polyhydric organosilicones and their use, a preferred of which is as adjuvants for pesticides. The polyhydric organosilicone have siloxane backbones with pendant, terminal or intermediate polyhydric groups. The polyhydric groups or the silioxane may be functionalized further with amine, alkyl and/or alkyleneoxide groups.

Agricultural compositions employing organosiloxanes containing polyhydric groups

The present invention teaches modified organosilicone and their use, a preferred of which is as adjuvants for pesticides. The modified organosilicone have siloxane backbones with pendant, terminal or intermediate amine and polyether groups. The modified groups or the siloxane may be functionalized further with alkyl or alkyleneoxide groups.

Organosiloxane containing modified groups in agricultural compositions

A fluorine-containing organic silicon compound represented by the following formula 1, which is useful as various industrial base materials required to have performances such as water and oil repellency, anti-fouling properties or release properties and as raw materials therefor. Here, A,represents a specific polyfluorohydrocarbon group-containing organic group; R,and R,which are independent of each other, represent bivalent organic groups; R,to R,which are independent of one another, represent monovalent organic groups; a is an integer of at least 1, and b is an integer of at least 0:

Fluorinated organosilicon compounds and process for the preparation thereof

The present invention teaches heterocyclic amine modified siloxanes and their use, a preferred of which is as adjuvants for pesticides. The heterocyclic amine modified siloxanes have siloxane backbones with pendant, terminal or intermediate heterocyclic amine groups, which may contain one or more heteroatoms, i.e., nitrogen, sulfur or oxygen. The heterocyclic amine groups or the siloxane may be functionalized further with alkyl or alkyleneoxide groups.

Heterocyclic amine modified siloxanes

The present invention teaches silicone polyether copolymers with a low degree of polymerization (3 to 4 Si units) provide control for foams generated by organosilicone based surfactants in water without the need for an additional antifoam component. The copolymer foam control agent is a compound of the formula

Foam control agents for silicone surfactants in agriculture

Aminosiloxanes bearing 4-amino-3,3-dialkylbutyl substituents are prepared by a multistep process including addition of 2,2-dialkylacetonitrile to vinylic siloxanes, hydrogenation of the nitrile adducts so formed to yield 4-amino-3,3-dialkylbutyl siloxanes, and optional equilibration of the latter with other siloxane sources, to form aminosiloxanes, which are useful for the treatment of textiles and fabrics and for the preparation of siloxane-containing block copolymers.

Aminosiloxanes with 4-amino-3,3-dialkylbutyl groups

Polyether modified fluoroalkylsiloxanes having the general structure of Formula (I), Formula (II) or Formula (III): ##STR1## wherein x is about 0 to 500, y is about 1 to 50, z is about 1 to 50, R=C.sub.p H.sub.2p --(OC.sub.2 H.sub.4).sub.n --(OC.sub.3 H.sub.6).sub.n).sub.m --OR' in which p is about 2 to 5, n is about 0 to 50, N is about 0 to 50, and one of n or m must be &gt;0, and R'=H, an alkyl group with 1-4 carbons, or an acetyl group and R.sub.f =C.sub.a H.sub.2a --O.sub.b --C.sub.c H.sub.2c --C.sub.d F.sub.2d+1 in which a is 3 or 4, b is 0 or 1, c is 0 or 2-4 and d is 4-12 with the provisos that if b=0, then c=0, and that if b=1, then c=2-4; z.sub.1 is about 0 to 50 and y.sub.1 is about 0 to 50, are useful to reduce the coefficient of friction and to increase mar resistance of coatings, to increase spreadability and wettability of coating formulations, and as foam control agents.

Polyether modified fluoroalkylsiloxanes

Oligomeric fluoroalkylsiloxanes corresponding to the formula: ##STR1## wherein x is 0 to 3, y is 0, 1, or 2; z is 0 or 1; x+y&gt;0, and R has the formula --C.sub.a H.sub.2a --O.sub.b --C.sub.d H.sub.2c --C.sub.d F.sub.2d+1 in which a is 2-4, b is 0 or 1, c is 0-8 and d is 4-12, and compositions thereof with an oil, are useful as spreading agents and in agricultural applications.

Oligomeric fluoroalkylsiloxanes as oil spreading agents

Aminopolysiloxanes of the following structure Q.sub.2 RSiO-- (SiR.sub.2 O).sub.x -(SiRR.sup.1 O).sub.y -SiRQ.sub.2 wherein R is a monovalent hydrocarbon group having 1 to 10 carbon atoms including alkyl, aryl and aralkyl groups; R.sup.1 is CH.sub.2 --CH.sub.2 --C--(CH.sub.3).sub.2 --CH.sub.2 --NHR.sup.2, R.sup.2 is hydrogen, an alkyl of C.sub.1 -C.sub.6, an alkyl amine of C.sub.1 -C.sub.6, or an alkanolamine of C.sub.1 -C.sub.6 ; Q is R, R.sup.1, hydroxyl, or an alkoxy of C.sub.1 -C.sub.4. x can be zero or integer; y is an integer, with x+y being less than 1,100, for use in various applications, including softening textiles.

Aminopolysiloxanes with hindered 4-amino-3,3-dimethylbutyl groups

A fluorine-containing organic compound of the following formula (1):

Fluorine-containing organic compound

A method for producing a fluorine-containing silicone compound, which comprises subjecting a fluorine-containing unsaturated compound of the following formula (1) and a hydrosilicone compound having at least one hydrogen atom bonded to a silicon atom to hydrosilylation in the presence of a catalyst to obtain a fluorine-containing silicone compound having a R.sup.f --Q--CR.sup.1 R.sup.2 --CHR.sup.3 --CR.sup.4 R.sup.5 -- group bonded to the silicon atom:

Method for producing a fluorine-containing silicone compound

Disclosed are methods for increasing the ability of a porous hydrophobic substrate to transmit aqueous liquids by applying to a hydrophobic substrate selected polyether modified polydimethylsiloxanes. Further, disclosed are coated substrates prepared by the described methods.

Non-migrating hydrophilic silicone finish for hydrophobic substrates

Linear alkylsilicone compounds of the formula ##STR1## wherein x=0 to 20, preferably 0 to 10, most preferably 0 to 1; y=1 to 10, preferably 1 to 5, most preferably 1; and R is an alkyl or alkyl ester group containing 6 to 16 carbons, or cyclic alkylsilicone compounds of the formula ##STR2## where m is 0 to 4, preferably 0 to 2, most preferably 0, and n is 1 to 5, preferably 3 to 5, most preferably 4, provided that m+n=3 to 5, are adjuvants for agricultural applications of oil-containing compositions. Especially preferred alkylsilicone compounds have a degree of polymerization of .ltoreq.6 and an alkyl content of .ltoreq.50% by weight. The compounds potentiate spreading of mineral or vegetable oils or oil-containing emulsions in dormant spray oils, crop oil concentrates, pesticides, and the like on difficult-to wet surfaces such as waxy leaf cuticles and arthropod exoskeletons.

Alkylsiloxanes as adjuvants for agriculture

The present invention teaches the use of novel lipophilically modified organosilicone materials and their use as agricultural adjuvants with carrier oils. The lipophilically modified silicones (LMS) of the present invention include linear organosilicone compounds or certain cyclic organosilicone compounds of the formulae: R.sub.a (Me).sub.3-a Si-[OSi(Me).sub.2 ].sub.x -[OSi(Me)R].sub.y -OSi(Me).sub.3-a R.sub.a wherein a=0 or 1; when a=0, x=0 to 4, y=1 to 4, and when a=1, x=0 to 4, and y=0 to 4, provided that the sum of x+y is .ltoreq.6; or (b) ##STR1## where m is 0 to 4, and n is 1 to 5, provided that m+n=3 to 5. R is the lipophilic group and may be an aryl, substituted aryl, aralkyl, alkyl phenyl ether, substituted alkyl phenyl ether or an alkyl alkyleneoxide group. The compounds potentiate spreading of mineral or vegetable oils or oil-containing emulsions in dormant spray oils, crop oil concentrates, pesticides, and the like on difficult-to-wet surfaces such as waxy leaf cuticles and arthropod exoskeletons.

Growing community of inventors

Hopewell Junction, NY, United States of America

Gerald J Murphy