Energy & Environmental International, L.c.

Beta Technologie Ag

Other

Gerald Bruce Eaton

Michael J Monahan

Alan Ebert

Robert J Tipton

Patrick Trainor

Eduardo J Baralt

Wirot Kitkrailard

A polymerization reactor for creating drag-reducing polymer having a reservoir and at least one heat exchanger plate in fluid communication with a coolant source, wherein each heat exchanger plate may be disposed on a lid. The heat exchanger plates are treated and/or covered to provide that the exchanger plates can be readily disengaged from the drag-reducing polymer. The polymerization reactors of the present invention permit large amounts of polymer to be formed in each reactor batch. Preferably, polymers are formed in the polymerization reactor by bulk polymerization. Methods for forming drag-reducing polymers are also disclosed.

Bulk polymerization reactors for producing drag reducer

A polymerization reactor having at least three side wall surfaces and a bottom wall surface forming a reservoir and at least one heat exchanger plate in fluid communication with a coolant source, wherein each of the at least one heat exchanger plate is disposed on a lid. The polymerization reactors of the present invention permit large amounts of polymer to be formed in each reactor batch. Preferably, polymers are formed in the polymerization reactor by bulk polymerization. Methods for forming polymers is also disclosed.

Bulk polymerization reactors

The present invention relates to a drag reducing agent, composition, compound, product, process and method of use for use in petroleum pipelines and the like. A preferred embodiment of the present invention provides a cryogenically-ground polyalphaolefin polymer at 15-25 wt. % of the commercial product formulation. The bulking agents comprise ethylene bis-stearamide alone or in combination with other polyethylene and/or polypropylene polymers at 2.0-5.0 wt. % of the commercial product formulation. In addition, diisobutyl ketone 20-60 wt. % of the commercial product formulation and propylene carbonate 2.8-8.4 wt. % of the commercial product formulation are used.

Drag reducing agent and method of use

Bulk polymerization reactor methods

A composition including a polyalphaolefin and at least one alfol alcohol that function as drag reducing agent slurries and a process for the preparation of the drag reducing agent slurries are disclosed. The process includes contacting alpha olefin monomers with a catalyst in a reactant mixture to form a polyalphaolefin. The polyalphaolefin is combined with at least one alfol alcohol to form a drag reducing agent slurry. A process for reducing drag in a conduit is also disclosed.

Drag reducing agent slurries having alfol alcohols and processes for forming drag reducing agent slurries having alfol alcohols

A composition including an alcohol absorbed polyalphaolefin that functions as a drag reducing agent and a process for the preparation of the drag reducing agent are disclosed. The process includes the steps of contacting alpha olefin monomers with at least one catalyst in a reactant mixture to form a polyalphaolefin. The polyalphaolefin is then contacted with at least one water insoluble alcohol for a period of time to provide an alcohol absorbed polyalphaolefin that is used as an improved drag reducing agent. Processes for reducing drag in a conduit are also disclosed.

Alcohol absorbed polyalphaolefin drag reducing agents

A composition including a polyalphaolefin and at least one alpha olefin monomer partitioning agent that function as drag reducing agents and a process for the preparation of the drag reducing agents are disclosed. The process includes the steps of contacting alpha olefin monomers with at least one catalyst in a reactant mixture to form a polyalphaolefin. The reactant mixture may include at least one alpha olefin partitioning agent or the at least one alpha olefin partitioning agent may be mixed with the polyalphaolefin after polymerization. The alpha olefin monomer partitioning agents are alpha olefin monomers that are solid at ambient temperatures. Preferably, the alpha olefin monomers are selected from the group consisting of C -C alpha olefin monomers. A process for reducing drag in a conduit is also disclosed.

Alpha olefin monomer partitioning agents for drag reducing agents and methods of forming drag reducing agents using alpha olefin monomer partitioning agents

A composition including polyalphaolefins that function as drag reducing agents and a process for the preparation of polyalphaolefins that function as drag reducing agents are disclosed. The process includes contacting alpha olefin monomers with a catalyst system, which includes a catalyst and an activator (co-catalyst) in a reactant mixture. The catalyst is a transition metal catalyst, preferably titanium trichloride, and the co-catalyst may include an alkylaluminoxane, alone or in combination, with a dialkylaluminum halide or a halohydrocarbon. The polymerization of the alpha olefin monomers produces a non-crystalline, ultra-high molecular weight polyalphaolefin having an inherent viscosity of at least 10 dL/g. The addition of the alkylaluminoxane during the polymerization process provides for a non-crystalline, ultra-high molecular weight polyalphaolefin and a more uniform molecular weight distribution of the resulting polyalphaolefin, thereby creating a drag reducing agent superior to known drag reducing agents. A process for forming a drag reducing agent comprising a non-crystalline, ultra-high molecular weight polyalphaolefin having an inherent viscosity of about at least 10 dL/g and a process for reducing drag in a conduit are also disclosed.

Methods for forming amorphous ultra-high molecular weight polyolefins and drag reducing compositions comprising amorphous ultra-high molecular weight polyolefins

The present invention is directed to improved drag reducing agents and methods of forming improved drag reducing agents comprising the steps of isomerizing olefin monomers to form isomerized olefin monomers, polymerizing the isomerized olefin monomers in the presence of at least one catalyst to form a polyolefin drag reducing agent having unexpectedly superior drag reduction properties when combined with liquid hydrocarbons, such as viscous crude oil. Therefore, the drag reducing agents of the present invention may be introduced into conduits, such as pipelines, to increase the flow of the hydrocarbons through the conduit.

Methods for forming amorphous ultra-high molecular weight polyolefins for use as drag reducing agents

Methods for forming amorphous ultra-high molecular weight polyalphaolefin drag reducing agents using non-metallocene catalysts and alkylaluminoxane

Methods for forming amorphous ultra-high molecular weight

A composition for reducing odors comprising extract derived from the plants belonging to the Zingiberales order of plants is disclosed. The odor reducing composition includes a banana plant extract derived from plants belonging to the Musa genus of plants. A method of forming the odor reducing composition and a method of reducing the odor of a substrate are also disclosed.

Composition and method of removing odors

A composition including polyalphaolefins that function as drag reducing agents and a process for the preparation of polyalphaolefins that function as drag reducing agents are disclosed. The process includes contacting alphaolefin monomers with catalyst particles in a polymerization mixture that includes a hydrocarbon solvent. The polymerization of the alphaolefin monomers produces polyalphaolefin drag reducing agents having an inherent viscosity of at least 10 dL/g. During polymerization of the polyalphaolcfin monomers, localized micelles compromising high molecular weight polyalphaolefin polymer are formed in micellar zones around the catalyst particles. The polymerization is conducted in the presence of a viscosity reducing agent that includes a substantially hydrophobic dispersant. The viscosity reducing agent is present in an amount sufficient to reduce the viscosity of the reaction mixture and disperse the localized micelles. The addition of the dispersant during the polymerization process provides for high molecular weight polyalphaolefin and a more uniform molecular weight distribution of the resulting polyalphaolefin. A process of forming a polyalphaolefin drag reducing agent in one or more polymerization reactors and a process for reducing drag in a conduit are also disclosed.

Growing community of inventors

Houston, TX, United States of America

Gerald Bruce Eaton