Tosco Corporation

Gerald B Faudel

Frank C Haas

Improved process and system for reducing the amounts of hydrogen sulfide emitted during pyrolysis of oil shale. At the elevated temperatures of oil shale pyrolysis, iron pyrite is converted to hydrogen sulfide which is emitted with the product gases and oils. Reduction in hydrogen sulfide emissions is accomplished by treating the oil shale with ultraviolet radiation of a particular wave length prior to pyrolysis in the presence of oxygen to selectively oxidize the pyritic sulfur to sulfate sulfur. The treated oil shale is then retorted at conventional temperatures. The sulfate sulfur does not decompose or otherwise convert to hydrogen sulfide at these temperatures. The sulfate sulfur remains in the spent shale residue and is discarded as waste to thereby effectively reduce the amount of sulfur emitted as hydrogen sulfide in the pyrolysis product gases.

System and method for lowered hydrogen sulfide emissions from oil shale

A method for removing nitric oxide from gas streams containing same. The nitric acid is removed by contacting the nitric oxide with elemental iron in the presence of water. The nitric oxide is believed to be reduced to nitrogen gas. The method has particular applications to removal of nitric oxide from gas streams produced during combustion of carbonaceous materials.

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Denver, CO, United States of America

Gerald B Faudel