E.i. Dupont De Nemours and Company

Le Centre National De La Recherche Scien

Le Centre National De La Recherche Science

Le Centre National De La Recherche Scientifique

Georgi Kostov

Ming-Hong Hung

Bruno Ameduri

Disclosed herein is a crosslinked fluoropolymer network formed by the free radical initiated crosslinking of a diacrylate fluoropolymer. The diacrylate copolymer is of formula CH&#x2550;CR'COO&#x2014;(CH)&#x2014;R&#x2014;(CH)&#x2014;OOCR&#x2032;&#x2550;CH, wherein R is selected from the group consisting of i) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), ii) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, iii) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and iv) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin, R&#x2032; is H or &#x2014;CH, n is 1-4 and wherein said oligomer has a number average molecular weight of 1000 to 25,000 daltons. The source of the free radicals may be a photoinitiator or an organic peroxide.

Crosslinked fluoropolymer networks

Disclosed herein is a telechelic diacrylate fluoropolymer and a process for manufacture of the fluoropolymer. The diacrylate copolymer is of formula CH&#x2550;CR'COO&#x2014;(CH)&#x2014;R&#x2014;(CH)&#x2014;OOCCR&#x2032;&#x2550;CH, wherein R is selected from the group consisting of i) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), ii) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, iii) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and iv) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin, R&#x2032; is H or&#x2014;CH, n is 1-4 and wherein said oligomer has a number average molecular weight of 1000 to 25,000 daltons.

Fluoropolymers having diacrylate ends

Disclosed herein is a crosslinked fluoropolymer network formed by the free radical initiated crosslinking of a diacrylate fluoropolymer The diacrylate copolymer is of formula CH&#x2550;CR'COO&#x2014;(CH)&#x2014;R&#x2014;(CH)&#x2014;OOCR&#x2032;&#x2550;CH, wherein R is selected from the group consisting of i) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), ii) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, iii) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and iv) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin, R&#x2032; is H or &#x2014;CH, n is 1-4 and wherein said oligomer has a number average molecular weight of 1000 to 25,000 daltons. The source of the free radicals may be a photoinitiator or an organic peroxide.

Disclosed herein is a telechelic diacrylate fluoropolymer and a process for manufacture of the fluoropolymer. The diacrylate copolymer is of formula CH&#x2550;CR'COO&#x2014;(CH)&#x2014;R&#x2014;(CH)&#x2014;OOCCR&#x2032;&#x2550;CH, wherein R is selected from the group consisting of i) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), ii) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, iii) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and iv) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin, R&#x2032; is H or &#x2014;CH, n is 1-4 and wherein said oligomer has a number average molecular weight of 1000 to 25,000 daltons.

Growing community of inventors

Burgas, Bulgaria

Georgi Kostov