The Goodyear & Tire Rubber Company

George Philemon Patitsas

Paul Harry Sandstrom

Bharat K Kansupada

Thomas Joseph Segatta

John R White

Syed K Mowdood

Walter H Waddell

Raymond Benjamin Roennau

Jerry L Brenner

William M Larson

Eric C Mizner

Samson Samuel Apticar

Herbert N Kagarise

A pneumatic tire, which has belts, gum strips and an overlay, which contain 2-15 phr of thermoplastic reinforcing polymer as an addition to a compound or as a replacement for 5-25 phr of carbon black, has good high speed properties.

Tires having improved high speed properties

The invention relates to expandable butyl rubber bladders for use in curing presses for hydrocarbon rubbers such as pneumatic tires. The bladders are a crosslinked elastomer comprising isobutylene repeat units and the bladder composition contains lecithin, particularly a modified lecithin, preferably in liquid form, dispersed within the bladder composition. The bladder composition may also contain castor oil, corn oil and/or soya-bean oil. The bladder composition may also contain at least one of graphite and polytetrafluoroethylene powder. The invention also relates to a method of curing tires by utilizing such butyl rubber bladder.

Tire curing bladder containing lecithin and use thereof

Disclosed are expandable bladders for use in curing presses for rubber compositions such as pneumatic tires. The bladders are a crosslinked elastomer comprising an isobutylene rubbery polymer. The bladder composition includes alkylphenoxypoly(alkyleneoxy)-alkanol which improves the release characteristics of the cured bladder from a tire innerliner cured in contact with said bladder. The improved release characteristics allow rubber compositions such as tires to be molded with fewer defects caused during release of the bladder from the tires or caused by abraded or deformed bladders. The use of alkylphenoxypoly(alkyleneoxy)alkanol also increases the useful life time of the bladder allowing more tires to be cured without changing bladders.

Tire cure bladder composition with alkylphenoxypoly (alkyleneoxy) alkanol

Expandable bladders for use in curing presses for hydrocarbon rubbers, such as pneumatic tires, are a crosslinked elastomer composition including isobutylene repeat units. When PTFE and/or graphite is present, they can be cured with brominated phenolic resins in shorter periods of time. The fluorinated ethylene polymer is added in particulate form and thereafter dispersed throughout the bladder. The fluorinated ethylene polymer may or may not form fibers. The bladders may further include graphite. The bladders generally have enhanced lubricity, reduced adhesion to cured tire innerliners, better resistance to cracking during flexing, and have lower tension set than similar compositions without fluorinated ethylene polymers. The above enhancements allow hydrocarbon rubbers such as tires to be molded with fewer defects caused by abraded or deformed bladders. They also enhance the useful life of the bladder reducing the cost of tire curing.

Tire cure bladders cured with brominated phenolic resigns and containing

This invention relates to a pneumatic rubber tire having a rubber sidewall with at least a portion of its outer surface being composed of white rubber devoid of carbon black reinforcement and composed of an elastomer composition prepared as a combination of EPDM, chlorobutyl rubber, diene-based elastomers and liquid EPDM. The liquid EPDM component replaces at least a portion of a traditionally used naphthenic/paraffinic processing oil.

Tire with white sidewall

Expandable bladders for use in curing presses for hydrocarbon rubbers, such as pneumatic tires, are a crosslinked elastomer composition comprising isobutylene repeat units and including a fluorinated ethylene polymer added in particulate form and thereafter dispersed throughout the bladder. These fluorinated ethylene polymer may or may not form fibers. The bladders may further comprise graphite. A preferred isobutylene elastomer is a brominated copolymer of from 80 to 99 weight percent isobutylene and from 1 to 20 weight percent paramethylstyrene. The bladders have enhanced lubricity, reduced adhesion to cured tire innerliners, better resistance to cracking during flexing, and have lower tension set than similar compositions without fluorinated ethylene polymers. The above enhancements allow hydrocarbon rubbers such as tires to be molded with fewer defects caused by abraded or deformed bladders. They also enhance the useful life of the bladder reducing the cost of tire curing.

Tire cure bladders containing polytetrafluoroethylene powder and use

Disclosed are expandable bladders for use in curing presses for rubber compositions such as pneumatic tires. The bladders are a crosslinked elastomer comprising an isobutylene rubbery polymer. The bladder composition includes corn oil which improves the release characteristics of the cured bladder from a tire innerliner cured in contact with said bladder. The improved release characteristics have been observed to allow rubber compositions such as tires to be molded with fewer defects caused during release of the bladder from the tires or caused by abraded or deformed bladders. The use of corn oil also has been observed to increase the useful life time of the bladder allowing more tires to be cured without changing bladders. A preferred isobutylene rubbery polymer is a brominated copolymer of isobutylene and p-methylstyrene. The bladder compositions have also been observed to have an enhanced flexibility due to the corn oil.

Tire curing bladder with improved release characteristics

Expandable bladders for use in curing presses for hydrocarbon rubbers such as pneumatic tires are a crosslink elastomer comprising isobutylene repeat units and include graphite. A preferred isobutylene elastomer is a brominated copolymer of isobutylene and p-methylstyrene. The bladders have enhanced lubricity, low adhesion to tire innerliners, and lower hot tension set. The above enhancements allow hydrocarbon rubbers such as tires to be molded with fewer defects caused by abraded or deformed bladders. They also enhance the useful life of the bladder reducing the cost of tire curing.

Tire curing bladder with improved release from the tire innerliner

A rubber laminate comprising a rubber substrate having coated thereon a blend of a water dispersible insoluble polyurethane and a water soluble polyvinyl alcohol. The combination of water soluble and water insoluble polymers upon drying result in a film that is humidity resistant, and has good abrasion resistance but can be removed by high-pressure washing or scrubbing.

Blends of polyvinyl alcohol and polyurethane water dispersions for

A composition comprised of polyvinylalcohol coating and at least one water insoluble particulate organic or inorganic material having a plate-like structure. Preferred particulate materials are flake mica and flake glass. In addition, there is provided a coated rubber tire having at least one of its surfaces coated with such composition.

Coating composition and coated tire

A composition comprised of polyvinyl alcohol coating and at least one water insoluble particulate organic or inorganic material having a plate like structure for use on at least one side of a rubber tire. Preferred particulate materials are flake mica and flake glass.

Polyvinyl alcohol coating containing mica or glass for use on a rubber

A lubricant composed of a siloxane, a fatty acid lubricant, mica and at least one selected thickener and use thereof for curing tires.

Lubricant and use thereof for curing tires

A lubricant composition comprised of (A) fatty acid, (B) polytetrafluoroethylene fluorocarbon resin powder (C) pyrogenic amorphous silica powder and (D) carrier. The lubricant is prescribed for use with a pneumatic tire and wheel assembly containing a run-flat device. The lubricant is contemplated as a component in such an assembly.

Lubricant for run-flat tire application and run-flat tire therewith

A pneumatic rubber tire having a polyurethane inlay laminate on at least one of its sidewalls. Said polyurethane inlay is applied as a hot melt of a polymer blend comprised of a thermoplastic polyurethane and an uncured halobutyl rubber.

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Kent, OH, United States of America

George Philemon Patitsas