Atlantic Richfield Company

George P Masologites

Jin S Yoo

Emmett H Burk, Jr

Jui-Yuan Sun

John A Karch

A process for reducing the sulfur and ash content of coal comprising the steps of:

Process for removing sulfur from coal

This invention provides a method for reducing the amount of oil required to form coal-oil agglomerates comprising the steps of (a) forming a slurry of water and coal particles; (b) contacting the slurry with an amount of hydrocarbon oil to form coal-oil agglomerates; (c) contacting said agglomerates with an additional amount of coal particles to form coal-oil agglomerates of a desired size; and (d) recovering coal-oil agglomerates of reduced oil content.

Process for agglomerating coal

A process for reducing the sulfur and ash content of coal comprising the steps of: (1) contacting coal particles containing ash and iron pyrite mineral matter with a promoting amount of at least one conditioning agent, said conditioning agent having a ferrous component maintained at a pH of from about 5.5 to 11.0 and being capable of modifying or altering the existing surface characteristics of the pyrite under conditions to effectuate alteration of modification of at least a portion of the contained pyritic sulfur; (2) agglomerating the coal particles while said pyrite surfaces are altered or modified in an aqueous medium with hydrocarbon oil to form coal-hydrocarbon oil agglomerates; (3) separating said coal-hydrocarbon oil agglomerates from pyrite mineral matter and ash to recover coal-hydrocarbon oil agglomerates wherein the coal exhibits reduced sulfur and ash content.

A method of agglomerating coal particles, a portion of the coal particles having a fine particle size comprising (a) separating at least part of the coal particles having a fine particle size to provide a first fraction of coal particles having a reduced coal fines content; (b) contacting a slurry of coal particles of the first fraction with hydrocarbon oil to form coal-oil agglomerates; and (c) recovering coal-oil agglomerates of reduced oil content.

A process for reducing the sulfur and ash content of coal wherein coal particles are treated with a conditioning agent in an aqueous slurry prior to agglomeration with a minor amount of hydrocarbon oil. After separation of the coal-oil agglomerate from ash and mineral matter remaining in the aqueous slurry, additional oil is added to provide a slurry of coal particles in hydrocarbon oil. Agglomeration of remaining ash and mineral matter is effected by addition of a minor amount of water. After separation of the mineral agglomerate and recovery from the oil slurry, treated coal particles are substantially reduced in ash and sulfur content.

Process for removal of sulfur and ash from coal

A process for reducing the sulfur and ash content of coal comprising: treating coal particles in a hydrocarbon oil slurry with minor amounts of a conditioning agent and water to effect agglomeration of ash and pyritic sulfur mineral matter; separating the agglomerates from the slurried coal particles; and recovering coal particles from the hydrocarbon oil.

A process for reducing the sulfur content of coal comprising:

A process for reducing the sulfur content of coal comprising the steps of:

A method for preparing an improved composition of matter whereby a solid catalyst comprising alumina derived from hydrous alumina predominating in alumina trihydrates and at least one platinum group component is used in hydrocarbon conversion service for a period of time to reduce the surface area of said solid catalyst to from about 20% to about 90% of the surface area of the original solid catalyst. This decreased area solid catalyst is treated with at least one metal promoter to produce a treated catalyst having improved properties. An improved method for hydrocarbon conversion using this treated catalyst is also disclosed.

Method of treating a used platinum group-alumina catalyst with a metal

Method of treating a used platinum group alumina catalyst with a metal

A process for producing coke from sulfur-containing hydrocarbon feedstocks which involves contacting at least a portion of the feedstock with a peroxy oxidant in the presence of a metal-containing catalyst to preferentially oxidize a portion of the hydrocarbon feedstock, subjecting the feedstock to coking conditions to form coke and recovering a coke product. The present process can provide improved yields of coke having substantially reduced sulfur content.

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Columbus, NC, United States of America

George P Masologites