Lubrizol Advanced Materials, Inc.

The B. F. Goodrich Company

Noveon IP Holdings Corp.

George Hunter Loeber

Umit G Makal

Kemal Onder

Louis J Brandewiede

Lalith B Suragani Venu

Joseph J Vontorcik

The present invention relates to a melt processable thermoplastic polyurethane-urea composition formed by a continuous bulk process without the presence of solvent using a polyol component, an isocyanate component, and chain extender component comprising a hindered aromatic diamine.

Melt processable thermoplastic polyurethane-urea elastomers

The TPU of this invention contains unsaturation in its polymeric backbone. The unsaturation can be present in the soft segment or in the hard segment or in both the soft and hard segments of the TPU. The TPU can be molded like a thermoplastic, and can be subsequently crosslinked by exposure to electron beam irradiation into thermoset articles having excellent chemical resistance, dimensional stability, set properties, heat resistance, oxidative resistance, and creep resistance. In one embodiment, the TPUs of this invention are the reaction product (1) a hydroxyl terminated intermediate, (2) a polyisocyanate, (3) a saturated glycol chain extender, and (4) a glycol chain extender containing carbon-carbon double bonds, such as the allyl moieties present in trimethylolpropane monoallyl ether. In another embodiment of this invention, the thermoplastic polyurethane which is crosslinkable by e-beam irradiation is comprised of the reaction product of (1) a saturated hydroxyl terminated intermediate, (2) an unsaturated hydroxyl terminated intermediate, wherein the unsaturated hydroxyl terminated intermediate contains carbon-carbon double bonds, (3) a polyisocyanate, and (4) a saturated glycol chain extender.

Crosslinkable thermoplastic polyurethane

Talc is combined with polyurethane to facilitate crystallization of a polyurethane composition, particularly a polyester-based polyurethane composition. The addition of talc can allow for more rapid formation of products by, for example, injection molding, compression molding, extrusion, and film formation techniques.

Polyurethanes with talc crystallization promoter

A fluoropolymer composition, containing one or more fluoropolymers, is used in a polyurethane composition to facilitate extrusion of the polyurethane composition. The addition of the fluoropolymer composition to the polyurethane composition typically results in less build up in an extruder than would be produced without the fluoropolymer composition.

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Elyria, OH, United States of America

George Hunter Loeber