Phelps Dodge Industries, Inc.

Ciba-geigy Corporation

George H Sollner

Allan R Knerr

Donald J Barta

Donny R Disque

Elizabeth Louise Otloski

Keith D Bultemeier

Michael W Lindvay

Richard D Remaks

Polyurethane syntactic foam compositions having high glass transition temperatures and low coefficients of thermal expansion suitable for use in tooling applications as modeling stock are prepared from polymeric isocyanate, an amine-based polyol, a polyether triol, molecular sieve material and hollow microspheres.

Polyurethane syntactic foam modeling stock

A composition of matter comprising the reaction product of a cyanuric acid reactant, an aliphatic vicinal diol reactant and a carboxyl reactant, a method for producing the same, a magnet wire coated therewith and an electromagnetic device utilizing the same.

Aliphatic isocyanurate containing polyester resins, method for making

An essentially linear resin having a plurality of amide, imide and ester groups therein comprising the condensation product of at least one polycarboxylic acid five member ring-forming reactant, at least one ethylenically unsaturated polycarboxylic acid five or six member ring lactam-forming reactant, at least one polyfunctional hydroxy compound, at least one difunctional amino five or six member ring forming reactant, at least one polycarboxylic acid reactant having no more than two carboxylic acid ester forming radicals, and at least one polycarboxylic acid reactant having two or more carboxylic acid ester forming radicals with at least two of the radicals in the 1,2 position relative to each other. The method of forming a solution of a prepolymer having a plurality of amide, imide and ester groups therein in cresylic acid or glycol ether solvents and reacting the same with at least one ethylenically unsaturated polycarboxylic acid five or six member ring forming reactant at elevated temperatures. A tinnable and solderable magnet wire having a thin, flexible, tough, thermally stable continuous coating on a conductor which also has a high degree of thermolability (removability in a solder bath) in a solder bath.

Essentially linear polymer having a plurality of amide, imide and ester

An essentially linear resin having a plurality of amide, imide and ester groups therein comprising the condensation product of at least one polycarboxylic acid five member ring-forming reactant, at least one ethylenically unsaturated polycarboxylic acid five or six member ring lactam-forming reactant, at least one polyfunctional hydroxy compound, at least one difunctional amino five or six member ring forming reactant, at least one polycarboxylic acid reactant having no more than two carboxylic acid ester forming radicals, and at least one polycarboxylic acid reactant having two or more carboxylic acid ester forming radicals with at least two of the radicals in the 1,2 position relative to each other. The method of forming a solution of a prepolymer having a plurality of amide, imide and ester groups therein in cresylic acid or glycol ether solvents and reacting the same with at least one ethylenically unsaturated polycarboxylic acid five or six member ring forming reactant at elevated temperatures.

A modified polyamide-imide resin and method for making the same. The composition comprises the reaction product of an aromatic tricarboxylic acid anhydride reactant, an aromatic diisocyanate reactant and an aliphatic dicarboxylic acid reactant in a solution comprising an aprotic solvent at a temperature ranging from about 70.degree. C. to about 155.degree. C. The tricarboxylic acid anhydride reactant is present in an amount which is greater than about 25 mol percent of the total of the tricarboxylic acid anhydride-aliphatic dicarboxylic acid reactants. The method comprises the steps of dissolving the aromatic tricarboxylic acid anhydride and aliphatic dicarboxylic acid reactants and an excess of the aromatic diisocyanate reactants in aprotic solvent thereby forming a reaction solution. The aromatic tricarboxylic acid anhydride is present in an amount which is greater than about 25 mol percent of the total of the tricarboxylic acid anhydride-aliphatic dicarboxylic acid reactants. And, reacting the tricarboxylic acid anhydride, dicarboxylic acid and diisocyanate.

Modified polyamide-imide resins and method for making the same

An essentially linear polymer having a plurality of amide, imide and ester groups therein, which is the condensation product of (1) at least one polycarboxylic acid imide-forming reactant, (2) at least one ethylenically unsaturated polycarboxylic acid carboxypyrrolidone-forming reactant, (3) at least one polycarboxylic acid ester-forming reactant, (4) at least one glycoly, (5) at least one other polyfunctional hydroxyl compound, and (6) at least one polyfunctional amino compound having at least one primary amine group thereon. The equivalent molar ratio of the functional hydroxyl groups of the glycols and hydroxyl compounds to the functional ester-forming carboxyl groups of the acid reactants is from about 1.0 to 1 to about 3.0 to 1. The equivalent molar ratio of the functional imide-forming groups of the acid reactants and the polyfunctional amino reactants and the functional carboxypyrrolidone-forming groups of the ethylenically unsaturated acid reactants and the polyfunctional amino reactants to the functional ester-forming carboxyl groups of the acid reactants is from about 0.2 to 1 to about 1.0 to 1. The equivalent molar ratio of said functional imide-forming groups of the acid reactants and the polyfunctional amino reactants to the functional carboxypyrrolidone-forming groups of the ethylenically unsaturated acid reactants and the polyfunctional amino reactants are from about 0.5 to 1 to about 3.0 to 1.

Water soluble essentially linear polymer having a plurality of amide,

An essentially linear polymer having a plurality of amide, imide and ester groups therein, which is the condensation product of (1) at least one polycarboxylic acid five member ring forming reactant, (2) at least one ethylenically unsaturated polycarboxylic acid five or six member lactam ring forming reactant, (3) at least one polyfunctional amino five or six member ring forming reactant, (4) at least one glycol, (5) at least one other polyfunctional hydroxyl compound, and (6) at least one other carboxylic acid ester reactant chosen from the group consisting of the acids, esters, anhydrides, and akylesters of terephthalic, isophthalic, and benzophenone dicarboxylic acids. The molar ratio of the functional hydroxyl groups of said glycol and hydroxyl compound to the functional ester forming carboxyl groups of said acid reactants is greater than about 1.3 to 1. The molar ratio of the functional imide-forming groups of said polycarboxylic acid five member ring forming reactant and said polyfunctional amino reactant to the functional lactam-forming groups of said ethylenically unsaturated acid reactant and said polyfunctional amino reactant are greater than about 0.5 to 1 and less than about 3.0 to 1. The molar ratio of said functional ester forming carboxyl groups to said functional imide-forming and lactam-forming groups are greater than about 1.0 to 1 and less than about 3.0 to 1. The method of forming said polymer includes placing the reactants in a solvent of the polymer having a boiling point in excess of about 150.degree. C. such as cresylic acid, heating the reactants and solvent at atmospheric pressure from about 120.degree. C. to about 220.degree. C., adding a suitable condensation catalyst after a reaction commences, and diluting or cooling resulting polymer solution to terminate the reaction.

Growing community of inventors

New Haven, IN, United States of America

George H Sollner