US Government As Represented by the Secretary of the Army

George E Wicks, Jr

Harold Z Sommer

Omer O Owens

Benjamin Witten

New chemical compounds having the generic formula: ##STR1## wherein X is one equivalent of an anion selected from the group consisting of monovalent or polyvalent anions, and having utility as incapacitating agents and in munitions.

Chemical agent

New chemical compounds, bis-quaternary carbamates, having the generic fora: ##STR1## wherein X is one equivalent of a monovalent or polyvalent anion, wherein R and R.sub.1 are aliphatic radicals selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, hexyl, wherein Z is a radical selected from the group consisting of hydrogen, methyl, or ethyl, wherein n is 2-12, wherein the dimethylcarbamoxy group is in the ortho, meta, or para position in the benzyl moiety, and having utility as toxic agents.

Ketobenzylcarbamates

New chemical compounds, bis quaternary carbamates, having the generic fora: ##STR1## wherein NRR.sub.1 R.sub.2 is a radical selected from the group consisting of N-methylpyrrolidinio, N-methylpiperidinio, N-methyl-3-hydroxypiperidinio, quinuclidinio, 3-hydroxyquinuclidinio, and 3-oxoquinuclidinio and wherein X is one equivalent of a monovalent or polyvalent anion.

Chemical agents

New chemical compounds having the generic formula: ##STR1## wherein X is one-equivalent of an anion selected from the group consisting f monovalent and polyvalent anions, and having utility as incapacitating agents and in munitions.

New chemical compounds, bis quaternary carbamates, having the generic fora: ##STR1## wherein X is one equivalent of an anion selected from monovalent or polyvalent anions, wherein n is 1 to 8, and wherein R, R' are aliphatic radicals selected from the group consisting of methyl, ethyl, propyl, and butyl, and having utility as toxic agents.

New chemical compounds having the generic formula: ##STR1## wherein X is one equivalent of a monovalent or polyvalent anion; R and R' re methyl or ethyl radicals; R.sub.1, R.sub.1 ', R.sub.2, R.sub.2 ' are hydrogen or a methyl radical; and Z is a radical selected from methyl, ethyl, propyl, butyl, or pentyl and having utility as incapacitating agents and in munitions.

New chemical compounds having the generic formula: ##STR1## wherein X is one equivalent of an anion selected from monovalent and pollent anions, and R,R' and Z are aliphatic radicals selected from the group consisting of ethyl, propyl, and butyl, with the provision that when Z is a radical selected from the group of octyl, dodecyl, and cyclohexyl, R,R' are selected from methyl and ethyl groups, and having utility as incapacitating agents and in munitions.

New chemical compounds, bis quaternary carbamates, having the generic fora: ##STR1## wherein X is one equivalent of a monovalent or polyvalent anion, wherein R and R.sub.1 are aliphatic radicals selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tertiary butyl, pentyl and hexyl, and wherein n is 2-12, and having utility as incapacitating agents and in munitions.

New chemical compounds, bis-quaternary carbamates having the generic form: a ##STR1## wherein X is one equivalent of an anion selected from monovalent or polyvalent anions, wherein R and R.sub.1 are aliphatic radicals selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, and hexyl, and having utility as toxic agents.

Picolyl unsymmetrical bis-quaternary carbamates

New chemical compounds, bis-quaternary carbamates, having the generic fora: ##STR1## wherein R and R.sub.1 are aliphatic radicals selected from the group consisting of methyl, ethyl, propyl, isopropyl, and butyl, wherein n is 1-9, wherein X is one equivalent of a monovalent or polyvalent anion, and having utility as toxic agents.

Unsymmetrical bis-quaternary amino acids

New chemical compounds, bis-quaternary carbamates, having the generic fora: ##STR1## wherein X is one equivalent of an anion selected from monovalent and polyvalent anions, n is 5-16, and R, R.sub.1, R.sub.2 are aliphatic radicals selected from the group consisting of methyl, ethyl, propyl, isopropyl, and butyl, and having utility as toxic agents.

New chemical compounds, bis-quaternary carbamates, having the generic fora: ##STR1## wherein R and R' are radicals selected from the group consisting of methyl, ethyl, propyl, and hydroxyethyl, R.sub.1 and R.sub.1 ' are selected from the group consisting of hydrogen, methyl, and ethyl, n is 1 to 8, R.sub.2 and R.sub.2 ' are selected from the group consisting of hydroxyl, hydrogen, methyl, ethyl, and propyl, and X is one equivalent of a monovalent or polyvalent anion, and having utility as toxic agents.

New chemical compounds having the generic formula: ##STR1## wherein X is one equivalent of a monovalent or polyvalent anion and wher R is meta, ortho, or para substituent selected from the group consisting of hydrogen, hydroxyl, methyl, and aldoximino, and having utility as incapacitating agents and in munitions.

New chemical compounds, bis-quaternary carbamates, having the generic fora: ##STR1## wherein X is one equivalent of an anion selected from monovalent or polyvalent anions; wherein R and R' are aliphatic radicals selected from the group consisting of methyl, ethyl, propyl, isopropyl, and butyl; and wherein the dimethylcarbamoxymethyl group is in the ortho, meta or para position of the phenyl ring, and having utility as toxic agents.

Growing community of inventors

Baltimore, MD, United States of America

George E Wicks, Jr