3m Innovative Properties Company

George D Vernstrom

Radoslav Atanasoski

Mark Kevitt Debe

Fred Boyle McCormick

Alison K Schmoeckel

Paul Frederic Baude

Andrew J L Steinbach

Dennis P O'Brien

David G O'Neill

Thomas Edward Wood

Yong Hsu

Krzysztof A Lewinski

Gregory M Haugen

Russell Dean Birkholz

Susan M Hendricks

Michael Albert Haase

Manoj Nirmal

Jeffrey R Dahn

John H Thomas, Iii

E Bradley Easton

Clayton V Hamilton, Jr

Ruizhi Yang

Fred B Mccormick

Methods of making catalyst electrodes comprising sputtering at least Pt and Ir onto nanostructured whiskers to provide multiple alternating layers comprising, respectively in any order, at least Pt and Ir. In some exemplary embodiments, catalyst electrodes described, or made as described, herein are anode catalyst, and in other exemplary embodiments cathode catalyst. Catalysts electrodes are useful, for example, in generating Hand Ofrom water.

Catalyst electrodes, and methods of making and using the same

Encapsulated organic electronic devices including organic light emitting diodes are made using an adhesive component as a mask while the device is being constructed. An adhesive-coated liner can be applied to the device substrate and openings created therein by removing portions of the liner and adhesive, or a patterned adhesive layer having openings therein can be formed on the device substrate, followed by deposition of the device layers and application of a sealing layer.

Encapsulated organic electronic devices and method for making same

In some embodiments, the present disclosure provides a fuel cell catalyst having a catalyst surface bearing a non-occluding layer of iridium. In some embodiments, the present disclosure provides a fuel cell catalyst comprising a catalyst surface bearing a sub-monolayer of iridium. In some embodiments, the present disclosure provides a fuel cell catalyst comprising a catalyst surface bearing a layer of iridium having a planar equivalent thickness of between 1 and 100 Angstroms. In some embodiments, the fuel cell catalyst comprises nanostructured elements comprising microstructured support whiskers bearing a thin film of nanoscopic catalyst particles. The layer of iridium typically has a planar equivalent thickness of between 1 and 100 Angstroms and more typically between 5 and 60 Angstroms. The fuel cell catalyst typically comprises no electrically conductive carbon material and typically comprises at least a portion of the iridium in the zero oxidation state.

Fuel cell nanocatalyst with voltage reversal tolerance

A Pt&#x2014;Ni catalyst is provided which demonstrates an unusually high oxygen reduction mass activity. In some embodiments, the Pt&#x2014;Ni catalyst is a Pt&#x2014;Ni binary alloy. In some embodiments, the catalyst may be characterized as having a Pt fcc lattice parameter of less than 3.71 Angstroms or 0.371 nm. In some embodiments the catalyst has a Pt fcc lattice parameter of between 3.69 Angstroms (or 0.369 nm) and 3.73 Angstroms (or 0.373 nm). In some embodiments, the catalyst may be characterized as having a composition of close to PtNi, where x is between 0.2 and 0.4. In some embodiments the catalyst comprises nanostructured elements comprising microstructured support whiskers bearing a thin film of nanoscopic catalyst particles comprising a catalyst material described above. The catalyst may be particularly useful as a fuel cell catalyst and more specifically as a fuel cell cathode catalyst.

Platinum nickel catalyst alloy

An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

Oxygen-reducing catalyst layer

A method is provided for making a supported catalyst comprising nanostructured elements which comprise microstructured support whiskers bearing nanoscopic catalyst particles, where the method comprises step a) of vacuum deposition of material from at least a first carbon target in the presence of nitrogen and step b) of vacuum deposition of material from a second target comprising at least one transition metal, the second target comprising no precious metals. In one embodiment, step a) is carried out prior to step b). In another embodiment, steps a) and b) are carried out simultaneously. Typically the deposition steps are carried out in the absence of oxygen. Typically, the transition metal is iron or cobalt, and most typically iron. The present disclosure also provides a supported catalyst comprising nanostructured elements which comprise microstructured support whiskers bearing nanoscopic catalyst particles made according to the present method. The present disclosure also provides a fuel cell membrane electrode assembly comprising the present supported catalyst.

Fuel cell catalyst

Methods are provided for making oxygen-reducing catalyst layers, which include simultaneous or sequential stops of physical vapor depositing an oxygen-reducing catalytic material onto a substrate, the catalytic material comprising a transition metal that is substantially free of platinum; and thermally treating the catalytic material. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

Method for making oxygen-reducing catalyst layers

A fuel cell cathode catalyst is provided comprising nanostructured elements comprising microstructured support whiskers bearing nanoscopic catalyst particles; wherein the catalyst comprises platinum and manganese and at least one other metal selected from the group consisting of Group VIb metals, Group VIIb metals and Group VIIIb metals other than platinum and manganese; wherein the volume ratio of platinum to the sum of all other metals in the catalyst is between about 1 and about 4 and wherein the Mn content is equal to or greater than about 5 micrograms/cm2 areal density. Typically, the volume ratio of manganese to the at least one other metal is between 10:90 and 90:10. Typically, the at least one other metal is Ni or Co. In addition, a fuel cell MBA comprising the present cathode catalyst is provided. In addition, methods of making the present cathode catalyst are provided.

Fuel cell nanocatalyst

A fuel cell cathode catalyst is provided which comprises nanostructured elements comprising microstructured support whiskers bearing nanoscopic catalyst particles. The nanoscopic catalyst particles are made by the alternating application of first and second layers, the first layer comprising platinum and the second layer being an alloy or intimate mixture of iron and a second metal selected from the group consisting of Group VIb metals, Group VIIb metals and Group VIIIb metals other than platinum and iron, where the atomic ratio of iron to the second metal in the second layer is between 0 and 10, where the planar equivalent thickness ratio of the first layer to the second layer is between 0.3 and 5, and wherein the average bilayer planar equivalent thickness of the first and second layers is less than 100 &#x212b;.

Fuel cell cathode catalyst

Encapsulated organic electronic devices including organic light emitting diodes are made using an adhesive component as a mask while the device is being constructed. An adhesive-coated liner can be applied to the device substrate and openings created therein by removing portions of the linear and adhesive, or a patterned adhesive layer having openings therein can be formed on the device substrate, followed by deposition of the device layers and application of a sealing layer.

Organic electronic devices having a conducting self-doped polymer buffer layer, particularly a self-doped polyaniline buffer layer, are described. Also described are organic light emitting diodes with buffer layers comprised of an intrinsically conducting polymer having no mobile counterions.

Organic electronic devices having conducting self-doped polymer buffer layers

Large area organic electronic devices having a doped conducting polymer buffer layer are described. Methods for applying a doped conducting polymer buffer layer to an electrode-coated large area substrate are described. The methods include web coating techniques such as microgravure coating or meniscus coating, which may be used in continuous coating processes.

Large area organic electronic devices having conducting polymer buffer layers and methods of making same

The present invention provides fuel cell electrode catalysts comprising alternating platinum-containing layers and layers containing suboxides of a second metal, where the catalyst demonstrates an early onset of CO oxidation. Preferred second metals are selected from the group consisting of Group IIIb metals, Group IVb metals, Group Vb metals, Group VIb metals and Group VIIb metals, most preferably Ti, Ta, W and Mo. The present invention additionally provides methods of making such catalysts, preferably by alternate deposition of platinum and second metals in the presence of substoichiometric amounts of gaseous oxygen.

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Cottage Grove, MN, United States of America

George D Vernstrom