Celanese International Corporation

Other

Hoechst Celanese Corporation

George C Seaman

Hung-Cheun Cheung

Carolyn Supplee

C V McSwain

Rodolfo W Laurel

H Robert Gerberich

Robert M Miller

John H Thuerman

The present invention describes a n-butane absorption process for purifying the ethylene product from an ethane oxidation process. The ethane oxidation product is fed to a series of absorption towers using a n-butane solvent that remove the inert components as well as purifying the ethylene from the product. A first absorption tower uses n-butane as a solvent to absorb both the ethane and ethylene, allowing for inert gasses to be removed from the stream. An ethylene-rich side stream from this tower is sent to an ethylene purification tower where ethylene is purified using n-butane solvent. The bottom stream from the first absorption tower is then sent to an intermediate ethylene recovery tower where crude ethylene is purified, and the overhead ethylene stream being sent to the ethylene purification tower. The bottoms stream, along with the bottoms stream of the ethylene purification tower, both of which comprise mostly ethane and n-butane, are then sent to a stripper tower for ethane recovery and n-butane solvent recover.

Butane absorption system for vent control and ethylene purification

Described herein is a process in which acetic acid is produced by ethane oxidation. One byproduct of the ethane oxidation is water, which is commonly removed from the process in the same stream as the acetic acid process. As described herein, the ethane oxidation reactor effluent is processed in a predehydration tower so as to separately recover water, acetic acid, and a gas stream for recycle back to the ethane oxidation reactor.

Use of predehydration towers in an ethane oxidation to acetic acid/ethylene process

Disclosed is a process for acquiring crude trimethylolpropane (TMP) of low reacted color. TMP is generally prepared by the condensation of n-butyraldehyde and formaldehyde in an alkali solution. The mixture is then concentrated and placed through an extractor. It has been found that a high concentration of low color TMP is present in the extractor and may by obtained by taking a slip stream of hot organic/water/TMP from the extractor and allowing the mixture to cool and phase separate. Upon separation of the phases, TMP generally having an acid wash color of about or less than 5 GU is recovered from the water phase. Disclosed is use of a single and multistage extractor.

Process improvement to produce low color trimethylolpropane

Disclosed is a process to produce paraformaldehyde prills having a low dissolution time and low concentration of insoluble formation. The insolubles are believed to lead to stickiness, tackiness, and loss of flowability of the product, loss of handling, and lead to storage problems of the final prill product. To address this problem, a concentrated formaldehyde solution is prepared having a purity ranging from 37%-99% and may be mixed with an amine additive, an amine and alcohol additive, or amine, alcohol, and caustic additive. Alternatively, the final prill may be sprayed with an amine or amine mixture stabilizer.

Addition of amine to improve parafomaldehyde

This invention relates to a process for improving the color of trimethylolpropane (TMP) by extracting color-causing impurities generated in the reaction to produce TMP. This improved color TMP is characterized by a reduced acid wash color and phthalic anhydride color--color measurement tests commonly used in the industry for assessing product quality and suitability of the TMP for certain color sensitive end-uses.

Trimethylolpropane color improvement

The invention provides sealing members for a chain. A pair of sealing members is provided for each end of a bushing. The sealing members respectively surround the ends of the bushing and are housed between inner sidebar portions and the outer sidebar portions of the chain. Each of the sealing members includes a collar which is pressed onto one of the ends of the bushing and which is positioned in closely spaced relation to one of the inner sidebars. Each collar has a circumferential flange or outer and inner collar portions which extend toward and engage one of the outer sidebars. Each collar defines an annular groove surrounding the bushing. Each sealing member further includes a resilient sealing ring housed in each annular groove. Each resilient sealing ring surrounds the bushing and engages in a sealing relation with the outer sidebar engaged by the collar in which it is housed.

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Corpus Christi, TX, United States of America

George C Seaman