Raychem Limited

Scimat Limited

George B Park

Robert H McLoughlin

John A Cook

Stephen Michael Baigrie

George M Gansbuehler

James A Rinde

Robert P Saltman

Edward F Chu

Frank James Lowe

Per J Jensen

John M Senior

Vijay N Reddy

Norman Hutt

David J Barker

Hendrick Graulus

George Michael Ganbuehler

Stephen Alan Webb

Richard J Penneck

Stephen E Myers

Mike G Dorling

A cable splice case or other article for environmental sealing comprises a composite material having multifilament fibres therein, which fibres are blocked in order to prevent passage of fluid through the material in a direction parallel to its major surfaces.

Radially-recoverable sleeve of composite

A cable splice case or other article for environmental sealing comprises a composite material having multifilament fibers therein, which fibers are blocked in order to prevent passage of fluid through the material in a direction parallel to its major surfaces.

Composite material

A conductive polymer composition in which a particulate conductive filler is dispsered in a polymeric component which is a mixture of an essentially amorphous thermoplastic resin and a thermosetting resin. In preferred compositions, the amorphous thermoplastic resin and the thermosetting resin are substantially mutually soluble. In order to improve the thermal stability of the composition on exposure to successive thermal cycles, it is preferred that the composition be cured by heating the uncured mixture of amorphous thermoplastic resin, thermosetting resin, and particulate conductive filler at a rate of at least 15.degree. C./minute to the cure temperature.

Conductive polymer composition

A conductive polymer composition in which a particulate conductive filler is dispersed in a polymeric component which is a mixture of an essentially amorphous thermoplastic resin and a thermosetting resin. In preferred compositions, the amorphous thermoplastic resin and the thermosetting resin are substantially mutually soluble. In order to improve the thermal stability of the composition on exposure to successive thermal cycles, it is preferred that the composition be cured by heating the uncured mixture of amorphous thermoplastic resin, thermosetting resin, and particulate conductive filler at a rate of at least 15.degree. C./minute to the cure temperature.

A microporous polymeric film of high porosity comprises a halopolymer in which the repeating units are --(C.sub.n H.sub.2n)-- and --(C.sub.m X.sub.2m)-- in which each X independently represents fluorine or chlorine and the values of n and m are greater than one and less than six. The film is the result of firstly melt processing a mixture of the halopolymer, more than 150 parts by weight of an extractable salt and not more than 80 parts by weight of an extractable polymer per 100 parts by weight of the halopolymer, the extractable polymer not being completely and homogeneously mixed with the halopolymer and being less viscous than the halopolymer when both are molten so that the surfaces of the film resulting from melt processing are rich in the extractible polymer, and secondly extracting at least some of the extractable salt to render the film porous and extracting at least some of said polymer to impart surface porosity to the film. The film has a porosity of more than 50% by volume and more usually 60-70%. The film may be used as the separator of an electrochemical cell e.g. a battery having a lithium anode and a thionyl chloride electrolyte.

Microporous films

A method and article for joining two substrates or repairing a substrate comprising positioning in thermal contact with and surrounding the substrate(s) a tubular article comprising conductive polymeric material. Two electrodes extending along the whole or part of the article as connected to a source of electrical power to cause current to pass through and heat the article. The conductive polymeric material is urged radially inwards towards the substrate(s). The radially inward movement may be caused by recovery of the conductive polymeric material, or by the use of elastomeric material.

Conductive polymeric heater

A tubular heat recoverable article comprises conductive polymeric material and is heated to effect recovery by the passage of electrical current therethrough. Elongate electrodes are attached on the surface or embedded in longitudinal flanges extending along the article. The flanges also comprise conductive polymeric material but are not heat recoverable, and therefore remain substantially undeformed on recovery other than bending to accommodate transitions. This means that the contact resistance between the electrode and the conductive material of the flange does not increase significantly on recovery.

Heat recoverable article

A particulate or filamentary coating, preferably curable, is provided on indelible labels or heat-recoverable articles, the coating comprising 4 to 90% by weight of an elastomeric binder incorporated in the coating in the form of an aqueous latex. Curable particulate materials described include epoxies and polyesters, and rubber latices include SBS, nitrile, chloroprene, EVA, and acrylates. The use of latices can enhance adhesion, ink receptivity, and humidity tolerance of the coatings.

Article surface coated with curable particulate or filamentary material

Sensitive electrode material, e.g. lithium electrode material, protected by a flexible layer of material which is swellable by liquid with which it will come into contact in use, and can thus, for example, act as an electrode separator when assembled in an electrical cell containing such a liquid. The protected electrode material can be processed, e.g. rolled into thin sheets, and can conveniently be fed to automatic cell assembly apparatus.

Electrode article

Sensitive material, e.g. lithium electrode material, is provided with a protective layer of fluid-impermeable material, which is subsequantly rendered permeable by altering its physical structure, e.g. by perforation, without altering its composition. The permeable material can act, for example, as an electrode separator when the resulting article is assembled into an electrolytic cell, and the protected material can be processed, e.g. rolled into thin sheets, and conveniently fed to automatic assembly apparatus.

Protection of sensitive material

Melt-extruded polymeric electrolyte material for electrochemical power cells may be coextruded with other components of the cell, notably a lithium metal anode.

Materials for electrical devices

A dimensionally recoverable article, preferably a heat-recoverable article, has on at least part of a surface thereof an adhesive composition that will cure by reaction of a plurality of mutually reactive components. The components are in the form of particles which are mixed together and which will fuse when heated. Preferred adhesives are based on combinations of an epoxy with a polyamide, carboxylic acid, phenolic resin or blocked isocyanate curing agent. The particulate adhesives show a synergistic increase in rate and/or level of cure when used in conjunction with a recoverable article.

Heat-recoverable article

A protected electrode article comprising sensitive electrode material having a layer of protective material bonded to at least part of its surface by means of an adhesive which can be made to swell by treatment with liquid, so as to increase the permeability of the adhesive to electrolyte which is encountered by the protected electrode material when incorporated in an electrochemical device.

Protected electrode article

Continuous metal electrodes are protected by non-porous fluid-impermeable material which is convertible to a fluid-permeable (porous) state, enabling the protective material to act as an electrode separator after the conversion. Conversion by contact with the non-aqueous fluid in a lithium cell is preferred, using strips of lithium protected with a blend of polyethylene and polyethylene oxide, the latter being extractable by the cell liquids.

Protected metal components

Electrode material, preferably lithium metal, is protected by a layer of material ready to function as an electrode separator and capable of sufficient ionic conductivity to provide an electrolyte, preferably a solvent-free polymeric electrolyte. The electrode material may be rolled to reduce its thickness while so protected.

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Swindon, United Kingdom

George B Park