Roehm Gmbh & Co Kg

Agomer Gesellschaft MIT Beschrankter

Barlocher Gesellschaftmit Beschrankter Hatfung

Evonik Rohm Gmbh

Barlocher Gmbh

Georg Schneider

Klaus Dorn

Pavel Belik

Gerd Loehden

Natascha Schickel

Bernd Frischkemuth

Mauren Traebing

Stefan Forster

There are provided plastisols based on poly(meth)acrylate which have a mean molecular weight in excess of 3,500,000 which have superior shelf life, tensile strength extensibility and viscosity as well as gel formation and filmforming propeties to those known heretofore. These plastisols are formed by emulsion polymerization.

Poly(meth)acrylate plastisols

There are provided foamable, foamable polyvinyl halide resin masses containing: A) 1 to 25 parts relative to 100 parts of polyvinyl halide, of a polymerizate obtainable through the emulsion polymerization of i) up to 20 to not more than 75 parts of methylmethacrylate, ii) 25 to 80 parts of one or more C.sub.2 -C.sub.18 alkylmethacrylates, iii) 0 to 5 parts of one or more vinyl unsaturated monomers copolymerizable with (i) and/or (ii, wherein the components (i)-(iii) together yield 100 parts and are polymerized with up to a further 100 parts of usual additives for emulsion polymerization, wherein the emulsion polymerizate is single stepped and has a viscosity number of &gt;700 cm.sup.3 /g and wherein copolymers are excluded which contain iv) MMA per se, or less than 20 or more than 75 parts of MMA together with either v) one or more acrylic acid esters, and/or vi) ethyl methacrylate, n-butyl-methacrylate, or ethylhexyl methacrylate. The resin mass further includes: B) 0.1-10 parts based on 100 parts of the polyvinyl halide of one or more foaming materials, C) 0-100 parts based on 100 parts polyvinyl halide of the usual additives. This polyvinyl halide resin mass, after foaming, yields a resin mass which, as well as of good surface properties, has a foam density of &lt;0.7 g/cm.sup.3.

Foamable polyvinyl halogenated resin mass, use of polymerizates thereof

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Freigericht, Germany

Georg Schneider