Shanghai Huayi Acrylic Acid Co., Ltd.

Huawei Technologies Co., Limited

Shanghai Huayi New Material Co., Ltd.

Other

Ge Luo

Yan Zhuang

Xiaodong Chu

Tonghao Wu

Xin Wen

Jianxue Ma

Zhenguo Li

Ke Yi

Xinlei Jin

Xiaoqi Zhao

Jinhua Ji

Wei Fan

Cheng He

Jingming Shao

Chunhua Qin

Jinghua Ji

Desheng Xiong

Yong Chen

Xiaoxia Wang

Xuemei Li

Xiadong Chu

Jiangxue Ma

Linghua Zuo

Zhigang Qian

A (methyl)acrolein oxidation catalyst and a preparation method therefor-in which the catalyst has a composition represented by the following formula: x(Mo12PaCsbVcDeOf)+tC/yZ in which MoPCVDOis a heteropolyacid salt main catalyst; C is a nano carbon fiber additive, and Z is a carrier thermal conduction diluent; Mo, P, Cs, V, and O represent the elements of molybdenum, phosphorus, cesium, vanadium, and oxygen, respectively; D represents at least one element selected from the group consisting of copper, iron, magnesium, manganese, antimony, zinc, tungsten, silicon, nickel, and palladium; a, b, c, e, and f represent the atomic ratio of each element, a=0.1-3, b=0.01-3, c=0.01-5, e=0.01-2, and f being the atomic ratio of oxygen required to satisfy the valence of each of the described components; x and y represent the weights of the main catalyst and the carrier thermal conduction diluent Z, and y/x=11.1-50%; and t represents the weight of the nano carbon fiber, and t/x=3-10%.

(Meth)acrolein oxidation catalyst and preparation method thereof

Disclosed is a method for preparing a heteropolyacid salt catalyst, comprising dissolving the lead compounds for each element to prepare a suspension and dispersion slurry of catalyst precursor, which comprises all of the catalyst components; drying the catalyst precursor, mixing them with an organic compound, molding, and calcining to produce the catalyst.

Heteropolyacid salt catalysts and their preparation method

A data processing method, includes receiving a data flow; generating a triplet set according to the data flow, where each triplet in the set includes three items, the first item is a first element in the data flow, the second item includes a first time point at which the first element appears in the data flow and a first quantity of times that corresponds to the first time point, and the third item includes a second time point at which the first element appears in the data flow and a second quantity of times that corresponds to the second time point; and performing data processing on the data flow according to the triplet set. In the embodiments of the present application, the triplet set may be generated based on the data flow.

Data processing method and apparatus

A method for compressing flow data, including: generating multiple line segments according to flow data and a predefined maximum error that are acquired; obtaining a target piecewise linear function according to the multiple line segments, where the target piecewise linear function includes multiple linear functions, and an intersection set of value ranges of independent variables of every two linear functions among the multiple linear functions includes a maximum of one value; and outputting a reference data point according to the target piecewise linear function, where the reference data point includes a point of continuity and a point of discontinuity of the target piecewise linear function. In this way, a maximum error, a target piecewise linear function is further determined according to the multiple line segments, and a point of continuity and a point of discontinuity of the target piecewise linear function are used to represent compressed flow data.

Method and device for compressing flow data

A method for compressing flow data, including: constructing multiple line segments according to flow data and a predefined maximum error that are acquired; obtaining a target piecewise linear function according to the multiple line segments, where the target piecewise linear function includes multiple linear functions, and an intersection set of value ranges of independent variables of every two linear functions among the multiple linear functions includes a maximum of one value; and outputting a reference data point according to the target piecewise linear function, where the reference data point includes a point of continuity and a point of discontinuity of the target piecewise linear function. In this way, a maximum error, a target piecewise linear function is further determined according to the multiple line segments, and a point of continuity and a point of discontinuity of the target piecewise linear function are used to represent compressed flow data.

Disclosed are a molybdenum based composite oxide catalyst, its preparation method and use. The catalyst has the following general formula: BiMoMNO; wherein M is one of V, Cr, Mn, Fe, Co, Ni and Cu, or a mixture of two or more of V, Cr, Mn, Fe, Co, Ni and Cu in any ratio; N is one of Na, K, Cs, Ca and Ba, or a mixture of two or more of Na, K, Cs, Ca and Ba in any ratio; x=0.5&#x2dc;20; y=0.05&#x2dc;20; z=0.01&#x2dc;5; a is a number satisfying the valance of each atom. The catalyst is prepared by the following method: firstly mixing a certain amount of the lead metal oxides according to the chemical proportion and then grinding the mixture with high-energy ball milling for a period of time to obtain the molybdenum based composite oxide catalyst. The catalyst exhibits excellent performance when using for preparation of butadiene by oxidative dehydrogenation of butene, and the preparation process is simple, controllable, and repeatable. Waste water or waste gas that is difficult to be treated is not produced during preparation.

Molybdenum based complex oxide catalyst, its preparation method and use

Disclosed are a ferrite catalyst and preparation methods thereof. The catalyst is provided with a formula below, wherein A is Mg atom, Zn atom or a mixture of both atoms at any ratio; D is one or more atoms selected from the group consisting of Ni, Co, W, Mn, Ca, Mo or V atom; Z is a catalyst carrier, which is one or more selected from the group consisting of calcium phosphate, calcium dihydrogen phosphate, aluminum phosphate, aluminum dihydrogen phosphate, ferric phosphate, magnesium phosphate, zinc phosphate, Mg&#x2014;Al hydrotalcite, calcium carbonate, magnesium carbonate; a=0.01-0.6; b=0-0.30; c is a number balancing each valence; x, y represent the amounts of principal catalyst and carrier Z respectively, wherein the weight ratio y/x=0.5:1-7:1.(FeADO)/Z

Ferrite catalyst and preparation method thereof

A method for preparing methacrolein from t-butanol, specifically a method for preparing methacrolein by using t-butanol as a starting material, is disclosed, comprising passing the starting material through a fixed bed reactor filled with catalyst, wherein the fixed bed reactor is divided to n reaction zones from the inlet of the starting material to the outlet of the starting material and each zone is filled with catalysts of different catalytic activities; wherein the catalytic activity of the catalyst in the first reaction zone is higher than the catalytic activity of the catalyst in the second reaction zone, and the catalytic activity of the catalyst is gradually increased from the second reaction zone to the last reaction zone; and n is an integer between 3 to 10.

Methods for preparing methacrolein from t-butanol

Disclosed are a catalyst and preparation method and use thereof. The catalyst has a constitution represented as the formula below, wherein, D represents at least one element selected from the group consisting of copper, magnesium, manganese, stibium and zinc; E represents at least one element selected from the group consisting of tungsten, silicon, nickel, palladium, ferrum and plumbum; Z is selected from the group consisting of SiC, MoO, WO, TiOand ZrO; y/x=11.1-50:100; a=0.1-3; b=0.01-5; c=0.01-5; d=0.01-3; e=0.01-2; f is the proportion of oxygen atom balancing the valence. The method comprises: (i) formulating Solution A with molybdenum, phosphorus, and vanadium compounds; formulating Solution B with dissolve potassium compound and a D-containing compound; formulating Solution C with an E-containing compound; (ii) mix Solutions A, B and C under a temperature of &#x2212;5-10&#xb0; C.; (iii) pre-calcination (iv) adding graphite powder and the diluting heat-conductive agent, wherein the weight ratio between the diluting heat-conductive agent and the catalyst precursor (y/x) is 11.1-50%; and (v) calcination.(MoPKVDEO)/Z

Heteropoly acid salt catalyst and its preparation method

The present invention provides a process for regenerating a deactivated heteropolymolybdophosphoric acid catalyst, comprising the steps of grinding the deactivated catalyst into particles having a particle size of 40 mesh or less, mixing the particles with a mixture comprising aqua ammonia, an aqueous solution containing ammonium ions and organic auxiliaries, kneading the same in a kneader to obtain a paste, drying the paste, molding the paste into cylindrical particles with a through hole in its longitudinal axis, and heating the paste in atmosphere at 350&#x2dc;450&#xb0; C. for 1&#x2dc;10 hours to produce the generated catalyst.

Process for regenerating a deactivated heteropolymolybdophosphoric acid catalyst

The present invention provides a preparation process of complex oxides catalyst containing Mo, Bi, Fe and Co, which comprising steps as following: dissolving precursor compounds of the components for catalyst and complexing agent in water to obtain a solution, and then drying, molding and calcining the solution to obtain catalyst. The catalyst is used for gas phase oxidation of light alkenes to unsaturated aldehydes. The catalyst has high activity, selectivity and stability. The reaction condition is mild. The preparation process of the catalyst is easy to operate and can be used for mass production.

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Shanghai, China

Ge Luo