University of Texas System

Gary T Rochelle

John C Chang

Wojciech Jozewicz

Charles B Sedman

Theodore G Brna

Claus Jorgensen

John Cullinane

Thu Nguyen

Yang Du

Xi Chen

Stephanie Freeman

Le Li

Alexander Voice

Yu-Jeng Lin

Humera Rafique

Tarun Madan

Omkar Namjoshi

Marcus Hilliard

Babatunde A Oyenekan

An apparatus for and method of removing acidic gas from a gaseous stream and regenerating an aqueous solution allows for the recovery of waste heat of stripping steam and more economical regeneration of the aqueous solution. In at least one embodiment, one or more rich solvent bypasses combine with a rich solvent heat exchanger to recover waste heat. In another embodiment, the apparatus and method include one or more rich solvent bypasses and a heater positioned upstream of the stripper to more economically regenerate an aqueous solution.

Apparatus for and method of removing acidic gas from a gaseous stream and regenerating an absorbent solution

Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a blend of piperazine and at least one diamine or triamine.

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Compositions and methods related to the removal of acidic gas. In one embodiment, compositions and methods are provided for the removal of acidic gas from a gas mixture using an aqueous amine solvent comprising water, a first amine, and a second amine, wherein the first amine contributes at least 50% by weight of the solvent's total amine concentration.

Acidic gas removal by aqueous amine solvents

Novel solvents and methods of use for the removal of COfrom flue gas, natural gas, hydrogen gas, synthesis gas, and other process and waste gas streams are provided. The solvent contains an alkali salt such as potassium carbonate and a polyamine such as piperazine (PZ) where the polyamine concentration is at least 1.5 equivalents/Kg HO and the alkali salt concentration is at least 0.5 equivalents/Kg HO. The preferred alkali salt/polyamine ratio is from approximately 1:2 to 2:1, and no additional alcohol is required for solubilizing the PZ. This chemical solvent and method of use provides efficient and effective removal of COfrom gaseous streams and other sources.

Polyamine/alkali salt blends for carbon dioxide removal from gas streams

Novel solvents and methods of use for the removal of COfrom flue gas, natural gas, hydrogen gas, synthesis gas, and other process and waste gas streams are provided. The solvent contains an alkali salt such as potassium carbonate and a polyamine such as piperazine (PZ) where the polyamine concentration is at least 1.5 equivalents/Kg HO and the alkali salt concentration is at least 0.5 equivalents/Kg HO. The preferred alkali salt/polyamine ratio is from approximately 1:2 to 2:1, and no additional alcohol is required for solubilizng the PZ. This chemical solvent and method of use provides efficient and effective removal of COfrom gaseous streams and other sources.

Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a diamine (e.g., piperazine) and carbon dioxide. One example of a method may involve a method for removing acidic gas comprising contacting a gas mixture having an acidic gas with a solvent, wherein the solvent comprises piperazine in an amount of from about 4 to about 20 moles/kg of water, and carbon dioxide in an amount of from about 0.3 to about 0.9 moles per mole of piperazine.

Acidic gas capture by diamines

Carbon dioxide and other acid gases are removed from gaseous streams using aqueous absorption and stripping processes. By replacing the conventional stripper used to regenerate the aqueous solvent and capture the acid gas with a matrix stripping configuration, less energy is consumed. The matrix stripping configuration uses two or more reboiled strippers at different pressures. The rich feed from the absorption equipment is split among the strippers, and partially regenerated solvent from the highest pressure stripper flows to the middle of sequentially lower pressure strippers in a 'matrix' pattern. By selecting certain parameters of the matrix stripping configuration such that the total energy required by the strippers to achieve a desired percentage of acid gas removal from the gaseous stream is minimized, further energy savings can be realized.

Regeneration of an aqueous solution from an acid gas absorption process by matrix stripping

An acid gas such as carbon dioxide, hydrogen sulfide, or a mixture thereof is removed from gaseous streams using aqueous absorption and stripping processes. By replacing the conventional stripper used to regenerate the aqueous solvent and capture the acid gas with a multipressure stripper () that combines acid gas compression with stripping, less energy is consumed. The multipressure stripper is a multistage flash () in which the total vapor flow from each stage is compressed and fed to the bottom of the previous flash stage at a higher pressure. In this process, the heat in the water content of the vapor exiting each stage is utilized at a higher pressure in the previous stage. The described stripping process generates the acid gas at a higher pressure without operating the stripper at a higher temperature, thereby reducing the energy consumption of the system.

Regeneration of an aqueous solution from an acid gas absorption process by multistage flashing and stripping

The present disclosure relates to improved processes for treating acid gases to remove acid gas components therefrom. Processes in accordance with the present invention include preparing a calcium silicate hydrate sorbent in the form of a semi-dry, free-flowing powder, and treating the gas with the powdery sorbent, such as by injecting the sorbent into a stream of the gas. The powdery sorbents may be prepared by slurrying/drying or pressure hydration techniques. Examples disclosed herein demonstrate the utility of these processes in achieving improved acid gas-absorbing capabilities in both lab-scale and pilot plant studies. Additionally, disclosure is provided which illustrates preferred plant design configurations for employing the present processes using conventional dry sorbent injection equipment. Retrofit application to existing plants is also addressed.

Processes for removing acid components from gas streams

Apparatus for removing sulfur from sulfur containing gases

The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

Process for removing sulfur from sulfur-containing gases: high calcium

The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperature for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry compounds. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

Processes for removing sulfur from sulfur-containing gases

Process for removing sulfur from sulfur-containing gases

The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda

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Austin, TX, United States of America

Gary T Rochelle