National Starch and Chemical Investment Holding Corporation

National Starch and Chemical Company Investment Holding Corporation

Gary T Martino

Martin M Tessler

Ian W Cottrell

Daniel B Solarek

John J Tsai

John C Leighton

Rama S Chandran

Frank A Nowak, Jr

Jean-Pierre Leblanc

Jacob J Guth

Melissa J Vitale

Maria Tolchinsky

Doreen L Howard

Michael J Hasuly

Natalie A Morawsky

Chung-Wai Chiu

John Socrates Thomaides

Dilip K Ray-Chaudhuri

James L Eden

Roger Jeffcoat

Joseph Pasapane

Manjit Singh Chowdhary

John L Gormley

William M Rouse, 3

Natalie Morawsky

Dinesh C Patel

Maria Valles

Julie V Russo

Kimberly A Koltai

The present invention is directed to a low VOC, non-aerosol, polyacrylic acid containing hair cosmetic compositions which contain stabilized starches, particularly those derivatized by alkylene oxides, about 01.-0.0% polyacrylic acid, up to about 15% solvent, and water. The derivatized starch may be hydrolyzed, particularly enzymatically hydrolyzed by at least one endo-enzyme. In addition, the starch may be cationically modified with a low degree of substitution. Use of such starches is novel and advantageous in that they are compatible with polyacrylic acid, providing a clear, solution with a stable viscosity. Further, the resultant composition provides a clear film which is not tacky, good stiffness, and improved humidity resistance.

Use of stabilized starches in low VOC, polyacrylic acid-containing hair cosmetic compositions

The present invention is directed to low VOC, non-aerosol hair cosmetic compositions, which contain nonionically modified starches. The starch may be additionally hydrolyzed, particularly enzymatically hydrolyzed. Further, the starch may be modified using ionic substituents. Use of such starches is novel and advantageous in that they provide a clear solution with a low viscosity, and good pump spray characteristics. Further, the resultant composition provides a clear film which is not tacky, good stiffness, and improved humidity resistance.

Nonionically derivatized starches and their use in non-aerosol, low VOC hair cosmetic compositions

This invention involves skin cleaning products and tapes for removing keratotic plugs, dirt and other debris found on the skin and in skin pores and comprising a poly(vinyl acetamide) polymer based adhesive composition applied to a substrate backing material.

Poly(vinyl acetamide) adhesive for skin cleaning tape

A composition for treating keratin substances comprising selected amphoteric polysaccharide derivatives, preferably guar gum which contain a cationic group comprising an amino, ammonium, imino, sulfonium or phosphonium group and an anionic group comprising a carboxyl, sulfonate, sulfate, phosphate or phosphonate group.

Keratin treating cosmetic compositions containing amphoteric polysaccharide derivatives

This invention involves skin cleaning products and tapes for removing keratotic plugs, dirt and other debris found on the skin and in skin pores and comprising a starch based remoistenable adhesive composition wherein the starch has from about 0 to 70% by weight amylose content and is converted to from about 30 WF to 20 DE.

Starch based adhesives for skin cleaning tape

A low volatile organic compound hair cosmetic composition containing a water insoluble, hydrolytically stable polypropylene oxide-modified polydimethylsiloxane block copolymer exhibits excellent spray characteristics and minimized contact foaming while providing high curl retention, fast drying time and low initial curl droop. The composition contains 0.001 to 0.9% of a polypropylene oxide-modified polydimethylsiloxane block copolymer which contains essentially no ethylene oxide, 1 to 15% of a film-forming resin, up to 70% of a solvent, 10 to 60% of a propellant, and water.

Hydro-alcoholic aerosol hair cosmetic compositions containing a

The present invention is directed to compositions, particularly cosmetic compositions, in which the oil is thickened using at least one copolymer which has a hydrophobic functionality sufficient to provide at least partial solubility and optionally stability in oil and a hydrophilic functionality sufficient to provide thickening of the oil. Use of such copolymers as thickening agents are advantageous in that they are soluble and stable in the oil phase. Further, sufficient thickening may be accomplished using very low amounts of these copolymers without the use of additional polymeric thickeners.

Compositions containing copolymers as a thickening agent

The present invention relates to hair care compositions which contain a polymer which is prepared from N-vinyl formamide (NVF) monomer and the use of those hair care compositions to treat hair. The polymer may be a homopolymer of NVF or an interpolymer of NVF and at least one vinyl monomer. The polymer is present in amounts effective to provide the hair care compositions with hair fixative properties and/or hair conditioning properties.

Hair care compositions containing polymeric N-vinyl formamide and

A polyurethane, soluble or dispersible in water, prepared from an organic diisocyante, a diol, and a 2,2-hydroxymethyl-substituted carboxylic acid is neutralized with a cosmetically acceptable organic or inorganic base and formulated into a hair fixative composition containing low amounts of volatile organic solvent.

Use of polyurethanes with carboxylate functionality for hair fixative

Low molecular weight polyaldehydes are prepared by converting the acetal groups of the low molecular weight polyacetal to aldehyde groups or by reacting an aldehyde-containing reagent (e.g., glyoxal) with a polyamide.

Low molecular weight polyaldehydes

The present invention relates to hair conditioning compositions which utilize as a hair conditioning additive a water-soluble polymer in amounts effective to impart hair conditioning properties to the hair conditioning composition, wherein the polymer contains the residue of N-vinyl formamide and the residue of at least one vinyl polymerizable moiety which contains an amine selected from the group consisting of secondary, tertiary and quaternary amines. The conditioning composition also includes one or more ingredients such as conditioning agents, emulsifiers, viscosity modifiers, gelling agents, opacifiers, stabilizers, preservatives, sequestering agents, chellating agents, pearling agents, clarifying agents, fragrances, colorants, and propellants; and water. The invention also relates to methods of conditioning hair.

Methods of conditioning hair which utilize polymeric N-vinyl formamide

Hair spray compositions in aqueous based systems containing 80% or less of volatile organic compounds exhibit a loss of spray performance properties resulting from viscosity and surface tension increases. The addition of 0.6 to 5% of one or more hydrophobic additives selected from the group consisting of hexamethyl disiloxane, bisphenyl hexamethicone and isocetyl alcohol improves the spray characteristics by eliminating foaming at the spray actuator and on the hair.

Low VOC hair sprays with improved spray characteristics

This invention relates to hair fixing compositions containing a natural based hydrolyzed zein fixative which has a selected molecular weight, the composition having low volatile organic compound (VOC) content.

Hydrolyzed zein as hair fixative in hair compositions

Emulsion-containing cosmetic compositions, wherein the emulsion comprises an aqueous dispersion of 15 to 40% solids, by weight, of an enzymatically degraded starch, which starch has been debranched by treatment with an alpha-1,6-D-glucanohydrolase to yield up to 100%, by weight, short chain amylose, are provided herein. Also provided are oil-free cosmetic compositions and cosmetic stick compositions, comprising 1 to 16% enzymatically debranched starch; 2 to 35% water; 35 to 90% hydrophobic base, selected from the group consisting of oil, wax and fat, and 5 to 20% emulsifier(s), with the balance of the compositions comprising one or more adjuncts selected from dye(s), fragrance(s), flavor(s), sunscreen agent(s), opacifier(s), and filler(s). Also provided is a method for formulating a cosmetic stick composition.

Cosmetics containing enzymatically debranched starch

The present invention relates to hair fixative compositions which utilize as the hair fixative resin a polymer which is prepared from N-vinyl formamide (NVF). The polymer may be a homopolymer of NVF or an interpolymer of NVF and at least one vinyl monomer(s). The polymer is present in amounts effective to provide the inventive hair fixative compositions with hair fixative properties. In preferred embodiments, the hair fixative composition is a stable, aqueous gel which forms a clear, non-tacky film upon drying. In certain embodiments, the gel has a rheology effective to allow the gel to be applied to the hair via a spray pump.

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Plainsboro, NJ, United States of America

Gary T Martino