Dow Corning Corporation

Toray Industries, Inc.

Gary T Decker

Gerald A Gornowicz

Howard M Bank

Kuniaki Tobukuro

Daniel Graiver

Arthur James Tselepis

Dwight E Williams

Chi-long Lee

Gary T Burns

Peter Y Lo

Aroop K Roy

Substrates are rendered water repellent by applying to the substrate a hyperbranched polymer containing a silicon atom made by polymerizing a derivatized aminofunctional organosilicon monomer which is the reaction product of an amine functional silane monomer precursor or an amine functional polysiloxane monomer precursor and a derivative of carbonic acid or a cyclic lactone.

Method of rendering substrates water repellent using hyperbranched

An exchange reaction of hydroxyl and alkoxysilane is used as a polymerization avenue yielding hyperbranched polymers. A monomer containing hydroxy alcohol functionality and alkoxy functionality attached to a silicon atom in the monomer is employed, and a simple exchange reaction with driving off of alcohol by-product leads to the desired hyperbranched polymerization and materials.

Hyperbranched polymers containing silicon atoms

A hydrosilation process where a siloxyhydride is reacted with an unsaturated reactant in the presence of a platinum catalyst and an accelerator selected from a group consisting of acetylenic alcohols and acetylenic ethers. The accelerators are especially useful for the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene and cyclohexene.

Acetylenic alcohols and ethers as accelerators for hydrosilation of

A hydrosilation process where a silicon hydride is reacted with an unsaturated reactant in the presence of a platinum catalyst and an aldehyde accelerator. The aldehyde accelerators are especially useful for facilitating the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene and cyclohexene.

Aldehydes as accelerators for hydrosilation

A hydrosilation process where a silicon hydride is reacted with an unsaturated reactant in the presence of a platinum catalyst and an accelerator selected from a group consisting of ene-yne unsaturated compounds. The accelerators are especially useful for facilitating the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene and cyclohexene.

Ene-yne unsaturated compounds as accelerators for hydrosilation

A hydrosilation process where a silicon hydride is reacted with an unsaturated reactant in the presence of a platinum catalyst and an accelerator selected from a group consisting of unsaturated secondary and tertiary alcohols and silated unsaturated secondary and tertiary alcohols. The accelerators are especially useful for the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene and cyclohexene. The accelerators are believed to be effective in the presence or absence of oxygen.

Unsaturated alcohols as accelerators for hydrosilation

A hydrosilation process where a silicon hydride is reacted with an unsaturated reactant in the presence of a platinum catalyst and an accelerator selected from a group consisting of tertiary alcohols, silated tertiary alcohols, benzyl alcohol, and silated benzyl alcohol. The accelerators are especially useful for the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene and cyclohexene. The accelerators are believed to be effective in the presence or absence of oxygen.

Alcohols and silated alcohols as accelerators for hydrosilation

A process for preparing a cured, fiber-reinforced composite comprises (I) blending an aminofunctional silicone resin containing monophenyl siloxy units and aminofunctional siloxy units, an epoxy resin and a hardener for the epoxy resin such as an aromatic diamine, (II) impregnating reinforcing fibers with the blend, (III) laying up at least two layers of the impregnated fibers, and (IV) heating the layed-up laminate at a temperature and time sufficient to cure the epoxy resin.

Preparing epoxy resin/hardener/aminopolysiloxane composite

A hydrosilation process where a silicon hydride is reacted with an unsaturated reactant in the presence of a platinum catalyst and an accelerator selected from a group consisting of acetylenic alcohols, silated acetylenic alcohols, and acetylenic ethers. The accelerators are especially useful for the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene and cyclohexene. The unsaturated ketone accelerators are effective in the presence or absence of oxygen.

Acetylenic alcohols and ethers as accelerators for hydrosilation

A cured, fiber-reinforced composite is prepared by blending an amino-functional silicone resin containing monophenyl siloxy units and amino-functional siloxy units, an epoxy resin, a hardener for the epoxy resin and an aromatic oligomer such as a polyether optionally with reactive primary amine groups, impregnating fibers into said blend, laying up at least two layers of the impregnated fibers, and heating the layed-up laminate at a temperature and time sufficient to cure the epoxy resin.

Preparing epoxy resin/aminopolysiloxane/aromatic oligomer composite

A hydrosilation process where a silicon hydride is reacted with an unsaturated reactant in the presence of a platinum catalyst and an unsaturated ketone accelerator. The described unsaturated ketone accelerators are especially useful for the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene and cyclohexene. The unsaturated ketone accelerators are effective in the absence of oxygen activation of the platinum catalyst and are synergetic with oxygen activation of platinum catalyst.

Unsaturated ketones as accelerators for hydrosilation

A fiber-reinforced composite is prepared from fibers embedded in a composition comprising cured epoxy resin(s), an aromatic oligomer such as a polyether optionally with reactive primary amine groups, and an amino-functional silicone resin with monophenyl siloxy units and amino-functional siloxy units.

Epoxy resin/aminopolysiloxane/aromatic oligomer composite

A fiber-reinforced composite is prepared from fibers embedded in a cured epoxy resin(s) containing therein a amino-functional silicone resin with monophenyl siloxy units and amino-functional siloxy units.

Epoxy resin/aminofunctional polysiloxane fiber-reinforced composite

A composition useful in the fabrication of fiber-reinforced composites is prepared from a blend of an epoxy resin, a hardener for the epoxy resin, an aromatic oligomer and an aminofunctional silicone resin containing monophenyl siloxy units and aminofunctional siloxy units.

Growing community of inventors

Midland, MI, United States of America

Gary T Decker