Minnesota Mining and Manufacturing Company

Gary L Holmes

Robert V Heiti

Scott R Culler

Kathryn M Spurgeon

David H Hardy

Thomas P Klun

William A Hendrickson

Kimberly K Harmon

Charles J Studiner, Iii

Mahfuza B Ali

Terrance P Smith

David W Macomber

Jon R Pieper

Michael V Mucci

Richard M Olson

M Zaki Ali

Ronald K Thery

Verna J LeMire

Karl F Roenigk

A Dale Otteson

Reactive polymeric dyes are provided comprising a chromophoric moiety derived from at least one free radically polymerizable dye and an azlactone moiety derived from 2-alkenylazlactone such that the free radically polymerizable dye is incorporated into the backbone of the polymer. Alternatively, 2-alkenylazlactone is polymerized and then derivatized with a nucleophilic dye or dyes, such that the chromophoric potion of the dye is pendent to the polymer backbone. Both types of reactive polymeric dyes may also contain additional polymerized monomeric units. The reactive polymeric dyes of the present invention can be used in a photoresist system and in particular in a color proofing construction.

Reactive polymeric dyes

Precisely shaped abrasive composites are disclosed. The abrasive composites comprise from 20 to 75 percent by weight at a plurality of abrasive grits and a binder.

Precisely shaped abrasive composite

Precisely shaped composites and methods for making these composites are disclosed. The method of this invention comprises the steps of:

Method of making a coated abrasive article comprising precisely shaped

Precisely shaped particles and method of making the same

Reactive polymeric dyes are provided comprising a chromophoric moiety derived from at least one free radically polymerizable dye and an azlactone moiety derived from 2-alkenylazlactone such that the free radically polymerizable dye is incorporated into the backbone of the polymer. Alternatively, 2-alkenylazlactone is polymerized and then derivatized with a nucleophilic dye or dyes, such that the chromophoric portion of the dye is pendent to the polymer backbone. Both types of reactive polymeric dyes may also contain additional polymerized monomeric units. The reactive polymeric dyes of the present invention can be used in a photoresist system and in particular in a color proofing construction.

Abrasive articles comprising precisely shaped particles are disclosed. The particles are bonded together to form a shaped mass, e.g., a wheel; alternatively, the particles can be bonded to a backing to form a coated abrasive article; or the particles can be bonded into a fibrous, nonwoven substrate to form a non-woven abrasive article.

Abrasive articles comprising precisely shaped particles

This invention provides a method of making an abrasive article. The method of this invention comprises the steps of:

Method of making an abrasive article

Most color proofing constructions use photooligomers that are tacky, require an oxygen barrier to protect the colorant layer and have a short shelf life. The use of alkali soluble photopolymers in the colorant layer of a color proofing construction provides a more easily processable proofing construction, eliminates the need for an oxygen barrier and has improved shelf life of the photopolymer. The proofing construction has a flexible support base film and a colorant layer coated thereon, wherein the colorant layer comprises a colorant and an alkali soluble photopolymer.

Alkali soluble photopolymer in color proofing constructions

A coated abrasive article comprising a backing bearing on at least one major surface thereof abrasive composites comprising a plurality of abrasive grains dispersed in a binder. The binder serves as a medium for dispersing abrasive grains, and it may also bond the abrasive composites to the backing. The abrasive composites have a predetermined shape, e.g., pyramidal. The dimensions of a given shape can be made substantially uniform. Furthermore, the composites are disposed in a predetermined array. The predetermined array can exhibit some degree of repetitiveness. The repeating pattern of a predetermined array can be in linear form or in the form of a matrix. The coated abrasive article can be prepared by a method comprising the steps of: (1) introducing a slurry containing a mixture of a binder and a plurality of abrasive grains onto a production tool; (2) introducing a backing to the outer surface of the production tool such that the slurry wets one major surface of the backing to form an intermediate article; (3) at least partially curing or gelling the binder before the intermediate article departs from the outer surface of the production tool to form a coated abrasive article; and (4) removing said coated abrasive article from the production tool.

Structured abrasive article

Thermal transfer dyesheets are disclosed containing highly efficient back-side antistick coatings. These are particularly useful in thermal dye transfer printing materials where relatively high temperatures are used in the thermal head and where dye offset from the front of one sheet to the back of an adjacent sheet is often a problem. These coatings comprise at least one polyfluorinated resin having an acrylate functionality, and at least one more resin having an acrylate functionality to provide a crosslinked matrix.

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Vadnais Heights, MN, United States of America

Gary L Holmes