Chinese Academy of Sciences

Gaobo Xu

Qiuxia Xu

Huilong Zhu

Huajie Zhou

Dapeng Chen

Qingqing Liang

Chao Zhao

Tao Yang

Huaxiang Yin

Yongliang Li

Tianchun Ye

Lingkuan Meng

There is disclosed a method for manufacturing a semiconductor device comprising two opposite types of MOSFETs formed on one semiconductor substrate, the method comprising: forming a portion of the MOSFET on the semiconductor substrate, said portion of said MOSFET comprising source/drains regions located in the semiconductor substrate, a dummy gate stack located between the source/drain region and above the semiconductor substrate and a gate spacer surrounding the dummy gate stack; removing the dummy gate stack of said MOSFET to form a gate opening which exposes the surface of the semiconductor substrate; forming an interfacial oxide layer on the exposed surface of the semiconductor structure; forming a high-K gate dielectric on the interfacial oxide layer within the gate opening; forming a first metal gate layer on the high-K gate dielectric; implanting doping ions in the first metal gate layer; forming a second metal gate layer on the first metal gate layer to fill up the gate opening; and annealing to diffuse and accumulate the doping ions at an upper interface between the high-K gate dielectric and the first metal gate layer and at a lower interface between the high-K gate dielectric and the interfacial oxide, and generating an electric dipole at the lower interface between the high-K gate dielectric and the interfacial oxide by interfacial reaction.

Methods for manufacturing semiconductor devices

A method for manufacturing a semiconductor device that comprises two opposite types of MOSFETs formed on one semiconductor substrate, comprising: defining an active region for each of the MOSFETs on the semiconductor substrate; forming an interfacial oxide layer on a surface of the semiconductor substrate; forming a high-K gate dielectric layer on the interfacial oxide layer; forming a metal gate layer on the high-K gate dielectric layer; implanting dopant ions in the metal gate layer; forming a Poly-Si layer on the metal gate layer; patterning the Poly-Si layer, the metal gate layer, the high-K gate dielectric layer and the interfacial oxide layer to form a plurality of gate stack structures; forming a plurality of gate spacer surrounding each of the plurality of gate stack structures; and forming a plurality of S/D regions. During activation annealing for forming the S/D regions, the dopant ions implanted in the metal gate layer diffuse and accumulate at an upper interface of the high-K gate dielectric layer to change the characteristics of the metal gates, and at a lower interface of the high-K gate dielectric layer to form electric dipoles with appropriate polarities by interfacial reaction, so as to realize adjusting of the effective work functions of the metal gates of the opposite types of MOSFETs, respectively.

Method for manufacturing semiconductor device

Provided is a method for manufacturing a p-type MOSFET, including: forming a part of the MOSFET on a semiconductor substrate including source/drain regions, a replacement gate, and a gate spacer; removing the replacement gate stack of the MOSFET to form a gate opening; forming an interface oxide layer on the exposed surface of the semiconductor substrate; forming a high-K gate dielectric layer on the interface oxide layer; forming a first metal gate layer; implanting dopant ions into the first metal gate layer; and performing annealing to cause the dopant ions to diffuse and accumulate at an upper interface between the high K gate dielectric layer and the first metal gate layer and a lower interface between the high-K gate dielectric layer and the interface oxide layer, and also to generate electric dipoles by interfacial reaction at the lower interface between the high-K gate dielectric layer and the interface oxide layer.

Method for manufacturing P-type MOSFET

A method for manufacturing a semiconductor device, comprising: defining an active region on the semiconductor substrate; forming an interfacial oxide layer on a surface of the semiconductor substrate; forming a high-K gate dielectric on the interfacial oxide layer; forming a first metal gate layer on the high-K gate dielectric; forming a dummy gate layer on the first metal gate layer; patterning the dummy gate layer, the first metal gate layer, the high-K gate dielectric and the interfacial oxide layer to form a gate stack structure; forming a gate spacer surrounding the gate stack structure; forming S/D regions for NMOS and PMOS respectively; depositing interlayer dielectric and planarization by CMP to expose the surface of dummy gate layer; removing the dummy gate layer so as to form a gate opening; implanting dopant ions into the first metal gate layer; forming a second metal gate layer on the first metal gate layer so as to fill the gate opening; and performing annealing, so that the dopant ions diffuse and accumulate at an upper interface between the high-K gate dielectric and the first metal gate layer and at a lower interface between the high-K gate dielectric and the interfacial oxide layer, and electric dipoles are generated by interfacial reaction at the lower interface between the high-K gate dielectric and the interfacial oxide layer.

This invention discloses a CMOS device, which includes: a first MOSFET; a second MOSFET different from the type of the first MOSFET; a first stressed layer covering the first MOSFET and having a first stress; and a second stressed layer covering the second MOSFET, wherein the second stressed layer is doped with ions, and thus has a second stress different from the first stress. This invention's CMOS device and method for manufacturing the same make use of a partitioned ion implantation method to realize a dual stress liner, without the need of removing the tensile stressed layer on the PMOS region or the compressive stressed layer on the NMOS region by photolithography/etching, thus simplifying the process and reducing the cost, and at the same time, preventing the stress in the liner on the NMOS region or PMOS region from the damage that might be caused by the thermal process of the deposition process.

CMOS device and method for manufacturing the same

The present disclosure discloses a method for manufacturing an N-type MOSFET, comprising: forming a part of the MOSFET on a semiconductor substrate, the part of the MOSFET comprising source/drain regions in the semiconductor substrate, a replacement gate stack between the source/drain regions above the semiconductor substrate, and a gate spacer surrounding the replacement gate stack; removing the replacement gate stack of the MOSFET to form a gate opening exposing a surface of the semiconductor substrate; forming an interface oxide layer on the exposed surface of the semiconductor; forming a high-K gate dielectric layer on the interface oxide layer in the gate opening; forming a first metal gate layer on the high-K gate dielectric layer; implanting dopant ions into the first metal gate layer; and performing annealing to cause the dopant ions to diffuse and accumulate at an upper interface between the high-K gate dielectric layer and the first metal gate layer and a lower interface between the high-K gate dielectric layer and the interface oxide layer, and also to generate electric dipoles by interfacial reaction at the lower interface between the high-K gate dielectric layer and the interface oxide layer.

Method for manufacturing N-type MOSFET

The present disclosure provides a method for forming and controlling a molecular level SiOinterface layer, mainly comprising: cleansing before growing the SiOinterface layer, growing the molecular level ultra-thin SiOinterface layer; and controlling reaction between high-K gate dielectric and the SiOinterface layer to further reduce the SiOinterface layer. The present disclosure can strictly prevent invasion of oxygen during process integration. The present disclosure can obtain a good-quality high-K dielectric film having a small EOT. The manufacturing process is simple and easy to integrate. It is also compatible with planar CMOS process, and can satisfy requirement of high-performance nanometer level CMOS metal gate/high-K device of 45 nm node and below.

Method for forming and controlling molecular level SiO2 interface layer

The present application provides a p-type semiconductor device and a method for manufacturing the same. The structure of the device comprises: a semiconductor substrate; a channel region positioned in the semiconductor substrate; a gate stack which is positioned on the channel region comprising a gate dielectric layer and a gate electrode, wherein the gate dielectric layer is positioned on the channel region and the gate electrode is positioned on the gate dielectric layer; and source/drain regions positioned at the two sides of the channel region and embedded into the semiconductor substrate; wherein the element Al is distributed in at least one of the upper surface, the bottom surface of the gate dielectric layer and the bottom surface of the gate electrode. The embodiments of the present invention are applicable for manufacturing MOSFET.

P-type semiconductor device and method for manufacturing the same

The present invention provides a method for integrating the dual metal gates and the dual gate dielectrics into a CMOS device, comprising: growing an ultra-thin interfacial oxide layer or oxynitride layer by rapid thermal oxidation; forming a high-k gate dielectric layer on the ultra-thin interfacial oxide layer by physical vapor deposition; performing a rapid thermal annealing after the deposition of the high-k; depositing a metal nitride gate by physical vapor deposition; doping the metal nitride gate by ion implantation with P-type dopants for a PMOS device, and with N-type dopants for an NMOS device, with a photoresist layer as a mask; depositing a polysilicon layer and a hard mask by a low pressure CVD process, and then performing photolithography process and etching the hard mask; removing the photoresist, and then etching the polysilicon layer/the metal gate/the high-k dielectric layer sequentially to provide a metal gate stack; forming a first spacer, and performing ion implantation with a low energy and a large angle for source/drain extensions; forming a second spacer, and performing ion implantation for source/drain regions; performing a thermal annealing so as to adjust of the metal gate work functions for the NMOS and PMOS devices, respectively, in the course when the dopants in the source/drain regions are activated.

Method for integration of dual metal gates and dual high-K dielectrics in CMOS devices

A method for manufacturing a CMOS FET comprises forming a first interfacial SiOlayer on a semiconductor substrate after formation a conventional dielectric isolation; forming a stack a first high-K gate dielectric/a first metal gate; depositing a first hard mask; patterning the first hard mask by lithography and etching; etching the portions of the first metal gate and the first high-K gate dielectric that are not covered by the first hard mask. A second interfacial SiOlayer and a stack of a second high-K gate dielectric/a second metal gate are then formed; a second hard mask is deposited and patterned by lithograph and etching; the portions of the second metal gate and the second high-K gate dielectric that are not covered by the second hard mask are etched to expose the first hard mask on the first metal gate. The first hard mask and the second hard mask are removed by etching; a polysilicon layer and a third hard mask are deposited and patterned by lithography and etching to form a gate stack; a dielectric layer is deposited and etched to form first spacers. Source/drain regions and their extensions are then formed by a conventional process, and silicides are formed by silicidation to provide contact and metallization.

Method for manufacturing CMOS FET

A method for integrating a replacement gate in a semiconductor device is disclosed. The method may comprise: forming a well region on a semiconductor substrate, and defining a N-type device region and/or a P-type device region; forming a sacrificial gate stack or sacrificial gate stacks respectively on the N-type device region and/or the P-type device region, the sacrificial gate stack or each of the sacrificial gate stacks comprising a sacrificial gate dielectric layer and a sacrificial gate electrode layer, wherein the sacrificial gate dielectric layer is disposed on the semiconductor substrate, and the sacrificial gate electrode layer is disposed on the sacrificial gate dielectric layer; forming a spacer or spacers surrounding the sacrificial gate stack or the respective sacrificial gate stacks; forming source/drain regions on both sides of the sacrificial gate stack or the respective sacrificial gate stacks and embedded into the semiconductor substrate; forming a SiOlayer on the semiconductor substrate; forming a SOG layer on the SiOlayer; etching the SOG layer until the SiOlayer is exposed; etching the SOG layer and the SiOlayer at different rates in such a manner that the SiOlayer is planarized; and forming a N-type replacement gate stack on the N-type device region and/or a P-type replacement gate stack on the P-type device region, respectively.

Method for integrating replacement gate in semiconductor device

A method for tuning the work function of a metal gate of the PMOS device is disclosed. The method comprises depositing a layer of metal nitride or a metal on a layer of high-k gate dielectric by physical vapor deposition (PVD), as a metal gate; doping the metal gate with dopants such as Al, Pt, Ru, Ga, Ir by ion implantation; and driving the doped metal ions to the interface between the high-k gate dielectric and interfacial SiO2 by high-temperature annealing so that the doped metal ions accumulate at the interface or generate dipoles by interfacial reaction, which in turn tunes the work function of the metal gate. The method can be widely used and its process is simple and convenient, has a better ability of tuning the work function of the metal gate, and is compatible with the conventional CMOS process.

Method for tuning the work function of a metal gate of the PMOS device

A method for manufacturing a semiconductor device includes the steps of: forming a first gate stack on a semiconductor substrate, the first gate stack includes a first gate conductor and a first gate dielectric between the first gate conductor and the semiconductor substrate; forming source/drain regions on the semiconductor substrate; forming a multilayer structure including at least one sacrificial layer and at least one insulating layer under the sacrificial layer on the semiconductor substrate and the first gate stack; performing a first RIE on the multilayer structure; performing a second RIE on the multilayer structure; selectively etching the first gate stack with respect to the insulating layer, in which the first gate conductor is removed and an opening is formed in the insulating layer; and forming a second gate conductor in the opening.

A method of adjusting a metal gate work function of an NMOS device comprises: depositing a layer of metal nitride film or metal film on a high K dielectric as a metal gate electrode by a physical vapor deposition process; implanting elements such as Tb, Er, Yb or Sr into the metal gate electrode by an ion implantation process; performing a high temperature annealing so that the doped metal ions are driven to and accumulate on the interface between the metal gate electrode and the high K gate dielectric, or form dipoles by an interface reaction on the interface between the high K gate dielectric and SiO. The method is capable of adjusting the metal gate work function, and is well-compatible with CMOS process.

Method of adjusting metal gate work function of NMOS device

A method for improving the efficiency of the electron-beam exposure is provided, comprising: step 1) coating a positive photoresist on a wafer to be processed, and performing a pre-baking; step 2) separating pattern data, optically exposing a group of relatively large patterns, and then performing a post-baking; step 3) developing the positive photoresist; step 4) performing a plasma fluorination; step 5) performing a baking to solidify the photoresist; step 6) coating a negative electron-beam resist and performing a pre-baking; step 7) electron-beam exposing a group of fine patterns; step 8) performing a post-baking; and step 9) developing the negative electron-beam resist, so that the fabrication of the patterns is finished. According to the invention, it is possible to save 30-60% of the exposure time. Thus, the exposure efficiency is significantly improved, and the cost is greatly reduced. Further, the method is totally compatible with the CMOS processes, without the need of any special equipments.

Growing community of inventors

Beijing, China

Gaobo Xu