Tdk Corporation

Gakuho Isomichi

Tetsuya Ueno

Takashi Sasaki

Hiroshi Sato

Masahiro Oishi

Takeo Tsukada

Keiko Takeuchi

Taisuke Masuko

Hisaji Oyake

Haruna Kato

Hiroko Takayanagi

A solid electrolyte layer includes a solid electrolyte and a compound represented by a composition formula MZr(PO). In the composition formula, M represents at least one selected from the group consisting of Na, K, Mg, Ca, Sr, Ba, Cu, Zn, and Ni, x satisfies 0<x≤2.5, and y satisfies 2.7≤y≤3.5.

Solid electrolyte layer, all-solid-state secondary battery, and manufacturing method of same

An all-solid-state battery includes a positive electrode layer including a positive electrode current collector layer and a positive electrode active material layer provided on the positive electrode current collector layer, a negative electrode layer including a negative electrode current collector layer and a negative electrode active material layer provided on the negative electrode current collector layer, and a solid electrolyte layer which is arranged between the positive electrode layer and the negative electrode layer and contains a solid electrolyte, wherein the all-solid-state battery includes a power storage unit in which the positive electrode layer and the negative electrode layer face each other with the solid electrolyte layer therebetween and an exterior unit, and wherein the exterior unit has an ion conductivity of 10S/cm or less.

All-solid-state battery

An all-solid-state battery includes a positive electrode current collector layer; a positive electrode active material layer; a negative electrode current collector layer; a negative electrode active material layer; a solid electrolyte layer disposed between the positive electrode active material layer and the negative electrode active material layer and formed of a solid electrolyte; and at least one of a first intermediate layer formed between the positive electrode current collector layer and the positive electrode active material layer, and a second intermediate layer formed between the negative electrode current collector layer and the negative electrode active material layer.

An all-solid-state secondary battery includes: a positive electrode active material layer; a negative electrode active material layer; and a solid electrolyte layer located between the positive electrode active material layer and the negative electrode active material layer, wherein at least one of the positive electrode active material layer and the negative electrode active material layer contains lithium vanadium phosphate, the solid electrolyte layer contains lithium zirconium phosphate, and between the positive electrode active material layer or the negative electrode active material layer containing lithium vanadium phosphate and the solid electrolyte layer, a first intermediate layer, which contains lithium vanadium phosphate containing zirconium and is located on the side of the positive electrode active material layer or the negative electrode active material layer, and a second intermediate layer, which contains lithium zirconium phosphate containing vanadium and is located on the side of the solid electrolyte layer, are provided.

All-solid-state secondary battery

A solid electrolyte, in which an occupied impurity level that is formed by a part of elements contained in a mobile ion-containing material being substituted and that is occupied by electrons is included in a band gap of the mobile ion-containing material, and an amount of charge retention per composition formula of the occupied impurity level is equal to or greater than an amount of charge retention of mobile ions per composition formula of the mobile ion-containing material.

Solid electrolyte and all-solid secondary battery

This solid electrolyte is a zirconium phosphate-based solid electrolyte in which a part of phosphorous or zirconium that is contained in the solid electrolyte is substituted with an element with a variable valence.

Solid electrolyte and all-solid lithium-ion secondary battery

A solid electrolyte, in which a part of an element contained in a mobile ion-containing material is substituted, and an occupied impurity level that is occupied by electrons or an unoccupied impurity level that is not occupied by electrons is provided between a valence electron band and a conduction band of the mobile ion-containing material, and a smaller energy difference out of an energy difference between a highest level of energy in the occupied impurity level and an energy and a LUMO level difference between a lowest level of energy in the unoccupied impurity level and a HOMO level is greater than 0.3 eV.

A solid electrolyte according to an embodiment includes a lithium-containing phosphoric acid compound with a cubic crystal structure.

All-solid secondary battery

An electrochemical device has a laminated body including: a positive electrode; a negative electrode; and a solid electrolyte sandwiched between the positive electrode and the negative electrode, wherein the laminated body contains water, a content of the water contained in the laminated body is 0.001 mass % or more and less than 0.3 mass % with respect to the laminated body, a part of the water is a bound water bonding with a constituent of the laminated body, and a ratio of the bound water in the water is 50% or more and 90% or less.

Electrochemical device and solid-state lithium ion rechargeable battery

An all-solid lithium ion secondary battery has a pair of electrode layers and a solid electrolyte layer between the pair of electrode layers. In the all-solid lithium ion secondary battery, at least one electrode of the pair of electrodes has an active material layer and an intermediate layer on the surface of the active material layer on the side of the solid electrolyte layer, and each of the solid electrolyte layer, the intermediate layer, and the active material layer includes a compound containing Li and two or more shared types of metal elements other than Li, the two or more shared types of metal elements in the solid electrolyte layer, the intermediate layer, and the active material layer are identical between the solid electrolyte layer, the intermediate layer, and the active material layer.

All-solid lithium ion secondary battery

An active material layer containing a compound represented by a general formula (1): LiVAlTiPO(1), where a, b, c, d, and e in the general formula (1) are numbers satisfying 0.5&#x2264;a&#x2264;3.0, 1.20&#x3c;b&#x2264;2.00, 0.01&#x2264;c&#x3c;0.06, 0.01&#x2264;d&#x3c;0.60, and 2.80&#x2264;e&#x2264;3.20; and a solid electrolyte layer containing a compound represented by a general formula (2): LiVAlTiPO(2), where f, g, h, i, and j in general formula (2) are numbers satisfying 0.5&#x2264;f&#x2264;3.0, 0.01&#x2264;g&#x3c;1.00, 0.09&#x3c;h&#x2264;0.30, 1.40&#x3c;i&#x2264;2.00, and 2.80&#x2264;j&#x2264;3.20.

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Tokyo, Japan

Gakuho Isomichi