Nec Tokin Corporation

Nec Corporation

Gaku Harada

Toshihiko Nishiyama

Masato Kurosaki

Tomoki Nobuta

Masaya Mitani

Hiroyuki Kamisuki

Masaki Fujiwara

Shinako Kaneko

Shinako Okada

Yuji Nakagawa

Koji Sakata

Junko Kurihara

Yuuji Nakagawa

Shinya Yoshida

Katsuhiko Naoi

Yutaka Nakazawa

Kazuya Mimura

Kouji Sakata

Masaki Fuziwara

Ari Manago

Shunzou Suematsu

A proton-conducting electric double layer capacitor comprising a electrolytic solution containing an aqueous solution of an organic or inorganic acid whereto a water-soluble N-containing heterocyclic compound is added.

Proton-conducting electric double layer capacitor using electrolytic solution

The present invention provides a secondary battery and a capacitor which may provide an excellent high rate and cycle characteristic as well as sufficient electromotive force and capacity. The secondary battery and a capacitor have an active material of an electrode comprising a trimer compound comprising three units of indole or indole derivatives in condensed ring form, wherein the second position and the third position of each unit form a six-membered ring, and a proton which can be utilized as a charge carrier of the trimer compound.

Secondary battery and capacitor utilizing indole compounds

Secondary batteries and capacitors have a high electromotive force together with a high cyclic property and are capable of fast charging and discharging, using a polymeric compound having a high stability and high reactivity in an acidic ambient, as an electrode active material. The secondary batteries and capacitors include an indole polymeric compound as an electrode active material. The polymeric compound uses a proton as a charge carrier and has a constituent represented by general formula (1):wherein each R denotes a hydrogen atom, a halogen atom, a hydroxyl group, a carboxyl group, a sulfonic group, a sulfuric acid group, a nitro group, a cyano group, an alkyl group, an aryl group, an alkoxyl group, an amino group, an alkylthio group and an arylthio group, which may be the same or different from each other, and at least one R is a substituent other than a hydrogen atom.

Secondary battery and capacitor using indole polymeric compound

A small battery and an electric double layer capacitor exhibit adequate cell voltage and capacitor withstand voltage. Specifically, the battery or electric double layer capacitor includes basic cells having a pair of electrodes oppositely laminated via the separator, and an electrolyte are packaged in a resin sheet package. The basic cells are laminated in series via a sheet current collector. The sheet current collector extends to an edge of the resin sheet package around the periphery of the basic cells laminated on both sides of the current collector. The sheet current collector is glued or fused to the resin sheet in its edge. The adjacent basic cells via the sheet current collector are fluid-tightly separated within the resin sheet package.

Battery having a sheet current collector fluid-tightly separating basic cells

A secondary battery of a proton conductive polymer, wherein a positive electrodeand a negative electrodeare arranged facing to each other via a separator in an electrolytic solution and only a proton in a &#x3c0; conjugated polymer or a proton of a hydroxyl group in a hydroxyl-containing macromolecular as an active material of an electrode in the positive and negative electrodes participates in a charge/discharge; the secondary battery uses a membrane, which has acid resistance, oxidation resistance and a functional group having cation exchange function, as the separator

Secondary battery of proton conductive polymer

An electrochemical cell contains, as an electrode active material, a mixture of trimer compounds each in the form of indoles or indole derivatives coupled to each other in second and third positions thereof, and tetramer compounds each of indoles or indole derivatives. In the cell, protons are used as charge carriers.

Electrochemical cell using indole-related compounds

The object of the present invention is to provide a method of producing electric cells which can improve the production yield, and for that purpose there is provided a method of producing an electric cell, wherein an acidic solution as an electrolytic solution and electrically conductive rubber as an exterior material are used, characterized in that sealing both of the positive electrode and the negative electrode piled via the separator with both of the gasket, through which the stainless needle is inserted, and the electrically conductive rubber, performing a vulcanization binding, after said vulcanization binding, forming a hole by pulling off the stainless needle from the gasket, injecting the electrolytic solution through said hole and sealing said hole; thus obtaining electric cells at high production yield.

Method of producing electric cells using substance injection

The present invention relates to an electrolytic solution comprising an aqueous solution of an organic or inorganic acid whereto a water-soluble N-containing heterocyclic compound is added, and an electrochemical cell such as a secondary battery and an electric double layer capacitor that uses such an electrolytic solution.

Electrolytic solution and electrochemical cell using the same

A molded electrode into one-piece is obtained by hot pressing an electrode material obtained by mixing a polymer active material, a conductivity-enhancing agent and a plasticizer, and a current collector sheet. The electrode structure permits significant freedom when designing a secondary battery which uses this electrode with a high energy density and a high power density.

Molded electrode, method for production thereof, and secondary battery using thereof

A secondary battery of a proton conductive polymer, wherein a positive electrode and a negative electrode are arranged facing to each other via a separator in an electrolyte and only a proton or a proton of a hydroxyl group in an indole trimer and a &pgr; conjugated polymer, i.e., an active material of electrode in the positive electrode and in the negative electrode participates in a charge/discharge, and a proton concentration is 5 to 40% and an anion concentration is 30 to 60% in the solution, respectively, and the anion concentration is at least higher than the proton concentration.

Secondary battery utilizing indole compounds

A battery electrode is obtained by coating an electrically conductive film serving as a collector with an aqueous solution of formic acid containing polypyridine, which is an active material, in dissolved form as well as carbon powder serving as a conduction aid, and drying the solution on the film. A secondary battery is manufactured using such electrodes.

Battery electrode, secondary battery, and method of manufacturing same

An electric energy storage element is provided which contains a secondary battery or a capacitor, and which uses a quinoxaline trimer compound as an electrode active substance and a proton as a charge carrier for the trimer compound. The trimer compound includes a quinoxaline or a quinoxaline derivative.

Capacitor element using quinoxaline compound

A structure that is constituted by disposing a laminate film and a collector rubber with a metal terminal plate interposed therebetween and a structure that is constituted by disposing a laminate film and a collector rubber with a metal terminal plate interposed therebetween are disposed so as to sandwich a fundamental cell that is constituted by disposing a positive electrode layer and a negative electrode layer, respectively, on surfaces of a separator, the laminate films are fusion bonded at peripheries thereof, and thereby the fundamental cell is sealed in a package cell. In the laminate film, a window portion or an opening is disposed, and a metal terminal plate is partially exposed and used as an external connection terminal. Owing to this configuration, a laminate film packaged storage device in which sealing properties and the volume efficiency are improved can be provided.

Laminate film packaged storage device and fabricating method thereof

Powder of a polymer active material exhibiting an electro-chemical oxidation-reduction reaction is mixed with powder of a conductivity assisting agent to obtain a mixture. The mixture is molded by a thermal press into a unitary block. Thus, a cell electrode having a large film thickness is produced without causing cracks or breakage. The electrode having a large film thickness improves the energy density of the polymer secondary cell.

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Tokyo, Japan

Gaku Harada