Samsung Sdi Co., Inc.

Industry-University Cooperation Foundation Hanyang University

Gain Kim

Yongkyoung Kim

Jungyoon Lee

Yangseob Kim

Yeonjoo Choi

Hyeonsun Choi

Dongwan Seo

Jae Hoon Kim

Young Moo Lee

Byung-Soo Kim

Seyeong Kang

Jayeon Gu

Sun Ju Moon

The present invention relates to a heat resistant layer composition, a heat resistant layer formed therefrom, and a separator for a lithium secondary battery, and a lithium secondary battery including same, wherein the heat resistant layer composition includes an acrylic copolymer including a first structural unit derived from (meth)acrylamide, and a second structural unit including at least one of a structural unit derived from (meth)acrylic acid or a (meth)acrylate, a structural unit derived from (meth)acrylonitrile, and a structural unit derived from (meth)acrylamidosulfonic acid or a salt thereof; a cross-linking agent including at least one functional group of an aldehyde group, an epoxy group, an amide group, an imide group, an amine group, and a silane-based group; and a solvent.

Heat resistant layer composition, lithium secondary battery separator comprising heat resistant layer formed therefrom, and lithium secondary battery comprising same

The present invention relates to a separator for a lithium secondary battery and a lithium secondary battery including same, the separator including: a porous substrate; and a coating layer on at least one surface of the porous substrate. The coating layer includes a (meth)acrylic copolymer including a first structural unit derived from (meth)acrylamide, a second structural unit derived from (meth)acrylonitrile, and a third structural unit derived from (meth)acrylamido sulfonic acid, (meth)acrylamido sulfonic acid salt, or a combination thereof. The first structural unit is included in an amount of 55 mol % to 90 mol % based on 100 mol % of the (meth)acrylic copolymer and the second structural unit and third structural unit are each independently included in 5 mol % to 40 mol % based on 100 mol % of the (meth)acrylic copolymer. The (meth)acrylic copolymer has a weight average molecular weight of 200,000 to 700,000.

Separator for lithium secondary battery and lithium secondary battery comprising same

The present invention relates to a separator for a lithium secondary battery, and a lithium secondary battery including the same. The separator includes a porous substrate, and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes a (meth)acrylic copolymer including a first structural unit derived from (meth)acrylamide, a second structural unit derived from (meth)acrylonitrile, and a third structural unit including at least one of structural units derived from (meth)acrylamidosulfonic acid, a (meth)acrylamidosulfonic acid salt, or a combination thereof; inorganic particles; and an organic filler; wherein the organic filler is included in an amount of 0.1 to 50 wt % based on a total amount of the organic filler and the inorganic particles.

The present invention relates to a separator for a lithium secondary battery, and a lithium secondary battery including same. The separator includes a porous substrate, and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes a heat-resistant binder including a (meth)acrylic copolymer including a first structural unit derived from (meth)acrylamide, and a second structural unit including at least one of a structural unit derived from (meth)acrylic acid or (meth)acrylate, and a structural unit derived from (meth)acrylamidosulfonic acid or a salt; an adhesive binder having a core-shell structure; and inorganic particles, wherein the adhesive binder has an average particle diameter of 0.2 μm to 1.0 μm, and the inorganic particles have an average particle diameter of 0.2 μm to 1.0 μm.

The present invention relates to a separator for a lithium secondary battery, and a lithium secondary battery including the same. The separator includes a porous substrate, and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes a binder including a (meth)acrylic copolymer including a first structural unit derived from (meth)acrylamide, and a second structural unit including at least one of a structural unit derived from (meth)acrylic acid or (meth)acrylate, and a structural unit derived from (meth)acrylamidosulfonic acid or a salt thereof; first inorganic particles; and second inorganic particles, wherein the first inorganic particles have an average particle diameter of 400 to 600 nm, the average particle diameter of the second inorganic particles is smaller than the average particle diameter of the first inorganic particles.

Separator having coating layer with ternary acrylic copolymer and inorganic particles with different particle diameters, and lithium secondary battery comprising same

The present invention relates to a separator for a lithium secondary battery, and a lithium secondary battery including the same. The separator includes a porous substrate, and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes an acrylic copolymer including a first structural unit derived from (meth)acrylamide, and a second structural unit including at least one of a structural unit derived from (meth)acrylic acid or (meth)acrylate, and a structural unit derived from (meth)acrylamidosulfonic acid or a salt thereof; an organic filler; and inorganic particles, wherein the organic filler is included in an amount of 0.1 to 50 wt % based on a total amount of the organic filler and the inorganic particles.

Separator including porous substrate and coating layer of acrylic copolymer, organic filler, and inorganic particles, and lithium secondary battery including the same

Disclosed are a separator for a lithium secondary battery and a lithium secondary battery comprising same. The separator for a lithium secondary battery comprises: a porous substrate; and a coating layer disposed on at least one side of the porous substrate, wherein the coating layer contains heat-resistant organic particles, an organic heat-resistant binder, and an organic adhesive binder, wherein the heat-resistant organic particles have a thermal decomposition temperature of 150° C. or higher and a particle diameter of 100 nm to 300 nm, the organic heat-resistant binder is a first organic material having a glass transition temperature of 130° C. to 200° C., the organic adhesive binder is a second organic material having a glass transition temperature of −40° C. or lower, and the mixing weight ratio of the organic heat-resistant binder and the organic adhesive binder is 7:3 to 9:1.

The present invention relates to a separator for a lithium secondary battery, and a lithium secondary battery including the same. The separator includes a porous substrate and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes a binder including a (meth)acrylic copolymer including a first structural unit derived from (meth)acrylamide, a second structural unit derived from (meth)acrylonitrile, and a third structural unit derived from (meth)acrylamidosulfonic acid, a (meth)acrylamidosulfonic acid salt or a combination thereof; first inorganic particles; and second inorganic particles, wherein the average diameter of the first inorganic particles is 400 nm to 600 nm, and the average diameter of the second inorganic particles is smaller than the average diameter of the first inorganic particles.

Separator for lithium secondary battery, and lithium secondary battery comprising same

This application relates to a coating layer composition and a coating layer formed using the coating layer composition. The coating layer composition includes a heat-resistant binder, a hydroxy group-containing polyimide particle, a silane cross-linking agent, and a solvent. The hydroxy group-containing polyimide particle and the functional group-containing silane cross-linking agent form a core-shell structured organic particle in which a core portion is derived from the hydroxy group-containing polyimide particles and a shell portion that is derived from the functional group-containing silane cross-linking agent. The shell portion is on the surface of the core portion in the core-shell structured organic particle. The application also relates to a separator for a rechargeable lithium battery and a rechargeable lithium battery including the separator having a coating layer formed using the coating layer composition.

Composition for coating layer including heat-resistant binder, hydroxy-containing polyimide particle, and silane crosslinker, separator for rechargeable lithium battery including coating layer formed therefrom and rechargeable lithium battery including the same

The present invention relates to a separator, a manufacturing method therefor, and a lithium secondary battery comprising the same, the separator comprising: a porous substrate; and a porous adhesive layer formed on one surface or both surfaces of the porous substrate, wherein the porous adhesive layer comprises a nitrogen-containing binder and polyvinylidene fluoride-based polymer microparticles having an average diameter of 200 nm to 700 nm, and the total thickness of the porous adhesive layer is 1 μm or less.

Separator comprising porous adhesive layer, and lithium secondary battery using same

A separator for a rechargeable lithium battery and a rechargeable lithium battery including the separator, the separator including a porous substrate; and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes organic filler particles, fluorine organic binder particles, and (meth)acryl organic binder particles, an average particle diameter of the organic filler particles is equal to or greater than an average particle diameter of the fluorine organic binder particles, and the fluorine organic binder particles are coated on the porous substrate as a part of the coating layer in an amount of less than about 0.1 g/mper surface.

Separator for rechargeable lithium battery and rechargeable lithium battery including the same

A separator includes a substrate and a coating layer on at least one surface of the substrate, wherein the coating layer includes first organic particles and second organic particles, and an average particle diameter of the first organic particles is larger than an average particle diameter of the second organic particles. The first organic particles protrude or extend to a height of about 0.1 &#x3bc;m to about 0.5 &#x3bc;m from a dented portion of a surface of the coating layer, and are distributed on the surface of the coating layer in an area ratio of about 5% or greater to less than 30% with respect to a total surface area of the coating layer. The separator may have improved adhesion to electrodes, insulation characteristics, and air permeability, and a battery including the separator may have improved lifespan characteristics.

Separator, method of preparing the same, and lithium battery including the same

A separator includes a substrate and a coating layer on at least a surface of the substrate, the coating layer including first organic particles, second organic particles, and a first binder, the first organic particles have a smaller mean particle diameter (D) than that of the second organic particles, and at least one selected from the first organic particles and the second organic particles has a core-shell structure.

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Yongin-si, South Korea

Gain Kim