Lanxess Corporation

The Goodyear & Tire Rubber Company

Bayer Corporation

University of Akron

Edison Polymer Innovation Corporation

Edison Polymer Innovation Corp. (epic)

Gabor Kaszas

Judit Eva Puskas

Joseph P Kennedy

Gerhard Langstein

Martin Bohnenpoll

Stephan Glander

Stephan Rodewald

Joseph John Kulig

Adam Gronowski

Kevin Kulbaba

R Resendes

Mark J Drewitt

Giorgio Agostini

Rui Resendes

Claude Schweitzer

Andreas Frantzen

Jean-Louis Marie Félicien Thomas

Bodo Ahrens

Gregory Daniel Zartman

Rotraud Casper, Legal Representative

Karen Karas Burke

Robert Lloyd Nelson

William E App

Susmita Bhattacharjee

Dave Syme

Kenneth Norman Watson

Laurent Carmelo Joseph Andre Pravata

William G Hager

Mark Drewitt

The invention relates to a pneumatic tire comprising a carcass and a tread located radially outward of the carcass and extending between the tire sidewalls; the tread providing a radially outermost tread running surface; the tread comprising a first tread layer comprising a first rubber compound and a second tread layer comprising a second rubber compound; wherein the second tread layer is located radially adjacent to the first tread layer; wherein the first rubber compound is compositionally distinct from the second rubber compound; wherein the second tread layer comprises one or more integrally formed extensions of the second tread layer extending radially outwardly toward the tread running surface; wherein each of the integrally formed extensions of the second tread layer comprises a circumferentially continuous groove and a reinforcement zone disposed on a side of the groove; wherein the first rubber compound comprises 100 parts by weight of at least one diene based elastomer, and from 1 to 150 phr of silica; and the second rubber compound comprises a diene base elastomer, from 50 to 120 phr of a filler, wherein at least 20 phr of the filler is a high surface area carbon black having an iodine adsorption number of at least 100 g/kg, from 1 to 45 phr of a methylene acceptor, from 1 to 25 phr of a methylene donor, and from 1 to 30 phr of at least one additive selected from the group consisting of carbamic resins, liquid diene based polymers having a number average molecular weight ranging from 1000 to 25000, and aromatic hydrocarbon resins.

Pneumatic tire having a dual layer tread

The present invention is directed to a pneumatic tire comprising a radially outer circumferential rubber tread disposed on a supporting carcass, an inner liner rubber layer radially inwardly disposed on the supporting carcass, and a sealant layer adhered to and disposed inwardly of the rubber inner liner layer as a radially inner surface of the tire, wherein the sealant layer comprises 100 parts by weight of elastomer comprising 5 to 10 parts by weight, per 100 parts by weight of elastomer (phr) of butyl rubber, 10 to 25 phr of bromobutyl rubber, and 65 to 85 phr of polybutene: and from 0.05 to 2 phr of a polymeric amine.

Pneumatic tire with post cure sealant layer

The present invention achieves increased filler interaction by incorporating a small amount (a few units per chain of rubbery polymer) of a conjugated triene monomer, such as alloocimene, randomly throughout the polymer chain of a rubbery polymer or at the chain ends of the rubbery polymer. The incorporation of the conjugated triene monomer leads to the formation of a polymer containing highly reactive conjugated diene units. These conjugated diene units can chemically react with carbon black leading to superior reinforcement. Alternatively, these conjugated diene units can be used for functionalization of the polymer with silica interactive/reactive groups using Diels Alder reactions. This functionalization of the rubbery polymer can conveniently be conducted in a mixer, such as a Banbury mixer, a mill mixer, or the like.

Copolymers of conjugated triene monomers for improved filler interaction

This invention relates to preparation and use of in situ functionalized elastomers in a rubber composition, namely post polymerization functionalization of elastomers, in rubber compositions containing precipitated silica filler reinforcement and tires having components thereof.

Preparation and use of functionalized elastomers in rubber compositions containing silica filler and tire components thereof

The present invention achieves increased filler interaction by incorporating a small amount (a few units per chain of rubbery polymer) of a conjugated triene monomer, such as alloocimene, randomly throughout the polymer chain of a rubbery polymer or at the chain ends of the rubbery polymer. The incorporation of the conjugated triene monomer leads to the formation of a polymer containing highly reactive conjugated diene units. These conjugated diene units can chemically react with carbon black leading to superior reinforcement. Alternatively, these conjugated diene units can be used for functionalization of the polymer with silica interactive/reactive groups using Diels Alder reactions. This functionalization of the rubbery polymer can conveniently be conducted in a mixer, such as a Banbury mixer, a mill mixer, or the like. The present invention more specifically discloses a rubbery polymer having repeat units which are comprised of (1) an olefin monomer selected from the group consisting of conjugated diolefin monomers and monoolefin monomers and (2) a conjugated triene monomer. The subject invention further reveals a rubbery composition which is comprised of the reaction product of (I) a rubbery polymer having repeat units which are comprised of (1) an olefin monomer selected from the group consisting of conjugated diolefin monomers and monoolefin monomers and (2) a conjugated triene monomer and (II) a dienophile and/or dienophile which is functionalized with a group which is capable of reacting with a filler selected from the group consisting of carbon black, silica, starch, and cellulose.

The present invention relates to arborescent polymers and to a process for making same. In one embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with a polymer or copolymer having a low glass transition temperature (T), and to a process for making such arborescent polymers. In another embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with less than about 5 weight percent end blocks derived from a polymer or copolymer having a high glass transition temperature (T), and to a process for making such arborescent polymers.

Arborescent polymers and process for making same

The present invention is directed to a method of preparing a functionalized elastomer, comprising the steps of

Functionalized elastomers

A halogenated butyl polymer having improved properties, the butyl polymer derived from a monomer mixture comprising a Cto Cmonoolefin monomer, a Cto Cmultiolefin monomer and a styrenic monomer with a catalyst system to produce the butyl polymer. The improved properties include faster cure, higher maximum torque, higher delta torque, relatively stable modulus over time, improved hot air aging properties and improved aged flexure properties. These improved properties are believed to result from direct interaction between the styrenic moieties in the polymer backbone with a crosslinking agent added to vulcanize the halogenated butyl rubber.

Halogenated terpolymers of isobutylene, diolefin monomer and styrenic monomer

The present invention relates to a continuous process for producing polymers at conversions ranging from 50% to 95% having a Mooney viscosity of at least 25 Mooney-units and a gel content of less than 15 wt. % containing repeating units derived from at least one isoolefin monomer, more than 4.1 mol % of repeating units derived from at least one multiolefin monomer and optionally further copolymerizable monomers in the presence of AlCland a suitable proton source (e.g. water) or cationogen and at least one multiolefin cross-linking agent wherein the process is conducted in the absence of transition metal compounds and organic nitro compounds.

Process for production of high-isoprene butyl rubber

The present invention relates to a process for producing polymers comprising repeating units derived from at least one isoolefin monomer, at least one multiolefin monomer and optionally further copolymerization monomers in the presence of at least one organic nitro compound and AlCl/water wherein the process is conducted in the absence of compounds selected from the group consisting of vanadium compounds, zirconium halogenid, and hafnium hallogenides.

The present invention relates to a shaped article for high purity applications containing at least one peroxide curable compound containing a substantially gel-free butyl polymer. In another of its aspects, the present invention relates to a sealing material and a medical device containing at least one peroxide-curable compound containing a substantially gel-free butyl polymer. In still another of its aspects, the present invention relates to a fuel cell containing at least one peroxide curable compound containing a substantially gel-free butyl polymer. In still another of its aspects, the present invention relates to halogen-free and sulfur-free shaped articles.

Halogen- and sulfur-free shaped articles containing peroxide curable compounds of butyl rubber

Growing community of inventors

London, Canada

Gabor Kaszas