Mitsubishi Gas Chemical Company, Inc.

Sony Corporation

Fumihiro Ito

Satoshi Okada

Shinpei Iwamoto

Shinichi Ikeda

Shota Arakawa

Kenichiro Usuda

Takashi Kashiba

Keiji Fukuzawa

Shun Ogawa

Shinobu Tsurumaru

Toshiya Takagi

Takumi Toida

Takuya Minezaki

Junichi Kajikuri

Takashi Otsuka

Haruka Okazaki

Toshiya Naito

Provided is a multilayer vessel excellent in gas barrier performance and transparency and its application. The multilayer vessel contains a layer (X) that contains at least one type of polyolefin resin as the major ingredient; and a layer (Y) that contains a polyamide resin (A) as the major ingredient, the polyamide resin (A) being composed of a structural unit derived from diamine, and a structural unit derived from dicarboxylic acid, 70 mol % or more of the structural unit derived from diamine being derived from metaxylylenediamine, meanwhile 30 to 60 mol % of the structural unit derived from dicarboxylic acid being derived from straight chain aliphatic α,ω-dicarboxylic acid having 4 to 20 carbon atoms, and 70 to 40 mol % being derived from isophthalic acid.

Multilayer vessel, and application thereof

A method for producing a sterilized oxygen-absorbing multilayer body is provided. The method may include: irradiating with radiation an oxygen-absorbing multilayer body comprising at least an oxygen-absorbing layer containing a transition metal catalyst and a thermoplastic resin (a) having a tetralin ring as a structural unit and a layer containing a thermoplastic resin (b); and heating the oxygen-absorbing multilayer body which has been irradiated with radiation in the sterilizing step at a temperature of the glass transition temperature of the thermoplastic resin (a) minus 20&#xb0; C. or more and lower than the glass transition temperature of the thermoplastic resin (a) for 50 hours or more.

Method for producing sterilized oxygen-absorbing multilayer body

Oxygen-absorbing resin composition comprising a polyester containing a constitutional unit (a) comprising tetralin ring structure, for example, an alkyl tetralin dicarboxylate, wherein the alkyl component has, for example, from 2 to 6 carbon atoms, and a constitutional unit (b) derived from a polyfunctional compound, selected from glycerin, trimethylol propane, pentaerythritol, trimellitic acid, trimellitic acid anhydride, pyromellitic acid, and pyromellitic acid anhydride, and a transition metal catalyst.

Oxygen-absorbing resin composition

Provided is an oxygen-absorbing multilayer body including an oxygen-absorbing layer containing an oxygen-absorbing composition and a thermoplastic resin layer containing a thermoplastic resin (b), wherein the oxygen-absorbing composition includes at least one compound having a tetralin ring represented by Formula (1), a transition metal catalyst, and a thermoplastic resin (a). 

Oxygen-absorbing multilayer body, oxygen-absorbing container, oxygen-absorbing airtight container, oxygen-absorbing push-through pack, and storage method using same

Oxygen-absorbing resin composition, not responsive to a metal detector, producing no odor after absorption of oxygen and has excellent oxygen-absorbing performance in a wide range of humidity conditions from low to high humidity. An oxygen-absorbing molded article, and a multilayer body, container, injection-molded article and medical containers also provided. The oxygen absorbing resin composition contains a polyester, comprising at least one constituent unit having a tetralin ring component compound, a transition metal catalyst, and a catalyst for producing the polyester. The oxygen-absorbing molded article of the present invention can be formed by molding the oxygen-absorbing resin composition into a film or a sheet. The multilayer body, container, injection-molded article, medical container, etc. of the present invention are obtained by using the oxygen-absorbing resin composition.

Oxygen-absorbing resin composition and oxygen-absorbing molded article using same and multilayer body, container, injection-molded article and medical container using these

An oxygen-absorbing resin composition containing a polyester compound, and a transition metal catalyst, and wherein the polyester compound is a polyester compound having a tetralin ring obtained by synthesis using a zinc compound contained in a catalyst; the zinc compound contained in a catalyst is present together with the obtained polyester compound in the oxygen-absorbing resin composition; the transition metal catalyst is different from the zinc compound contained in a catalyst; and the oxygen-absorbing resin composition is obtained by mixing the transition metal catalyst with the polyester compound present together with the zinc compound contained in a catalyst.

Oxygen-absorbing resin composition and oxygen-absorbing multilayer injection-molded article and oxygen-absorbing multilayer container using same

An oxygen absorbent composition which comprises a polyester oligomer containing a constitutional unit derived from a tetralin ring-containing carboxylic acid and a diol, wherein the polyester oligomer has a number average molecular weight of 500 to 10000, and a transition metal catalyst comprising at least one transition metal selected from the group consisting of manganese, iron, cobalt, nickel and copper.

Oxygen absorbent composition

Provided are a novel oxygen-absorbing resin composition not responsive to a metal detector, producing no odor after absorption of oxygen and having excellent oxygen-absorbing performance, and a multilayer body, container, injection-molded article and medical container using these. Further provided are an oxygen-absorbing resin composition etc. having excellent oxygen-absorbing performance in a wide range of humidity conditions from low humidity to high humidity. The oxygen-absorbing resin composition of the present invention is an oxygen-absorbing resin composition containing a polyamide compound and a transition metal catalyst, wherein the polyamide compound has at least one constituent unit having a tetralin ring. Moreover, the multilayer body, container, injection-molded article, medical container, etc. of the present invention are obtained by using the oxygen-absorbing resin composition of the present invention.

Oxygen-absorbing resin composition, and multilayer body, container, injection-molded body, and medical container using same

Provided is a novel oxygen-absorbing resin composition having excellent oxygen-absorbing performance and suppressing odor generation after absorption of oxygen even if a material responsive to a metal detector is not used. Further provided is an oxygen-absorbing resin composition having excellent oxygen-absorbing performance in a wide range of humidity conditions from low humidity to high humidity. Such an oxygen-absorbing resin composition contains a copolymerized polyolefin compound and a transition metal catalyst, in which the copolymerized polyolefin compound contains at least one constituent unit having a tetralin ring.

Oxygen-absorbing resin composition and oxygen-absorbing multilayer body using same, and molded article and medical container using these

The provision of an oxygen absorbent composition comprising a compound (A) having two or more tetralin rings, at least one of the tetralin rings having a hydrogen bond bonded to a benzylic position thereof, and having two or more imide bonds, and a transition metal catalyst.

Oxygen absorbent composition and molded body and package using the same

The present invention provides a sterilized oxygen-absorbing resin composition obtained by performing at least: a sterilizing step of irradiating with radiation an oxygen-absorbing resin composition containing a transition metal catalyst and a thermoplastic resin (a) having a tetralin ring as a constituent unit; and a step of heating the oxygen-absorbing resin composition at a temperature equal to or higher than the glass transition temperature of the thermoplastic resin (a) and equal to or lower than 200&#xb0; C., after the sterilizing step.

Sterilized oxygen-absorbing resin composition, sterilized oxygen-absorbing multilayer container and method for producing the same

A planar array antenna is comprised of an upper plate having a plurality of holes, a lower plate, and a circuit board having printed patterns of a plurality of array elements and located between the upper plate and the lower plate, wherein the lower plate has concave regions formed at positions corresponding to the positions of the plurality of holes of the upper plate.

Microwave planar array antenna

A suspended line feed type planar antenna is arranged with a number of antenna elements formed on a film-shaped substrate, and the film-shaped substrate is sandwiched between a plastic radome and a plastic rear cover, a conductive surface is plated on the rear surface of the plastic radome at its portion except the portions opposing the antenna elements and/or a conductive surface is plated on the whole front surface of the rear cover. The conductive surfaces and the antenna elements constitute resonance type printed path radiators, whereby the planar antenna of the invention can be simplified in construction and reduced in cost, thickness and weight, and the planar antenna of the invention can be increased in productivity and reliability.

Microwave antenna structure with intergral radome and rear cover

A planar microwave antenna of the suspended line feed type has a substrate sandwiched between a pair of conductive plates, each of the plates having aligned openings defining radiation elements. The substrate is held in place by holding portions surrounding the openings and wide grooves between the openings house a plurality of parallel suspended lines.

Microwave antenna

A planar antenna for circular polarized microwaves incorporates a substrate sandwiched between conductive layers having a plurality of openings arranged in a rectangular array, with a pair of perpendicular excitation probes supported on the substrate in alignment with each opening, and a feed circuit for interconnecting the excitation probes in a predetermined phase relationship. Two additional conductive elements may be supported on the substrate in alignment with the excitation probes to provide improved impedance matching. The feed circuit may incorporate a pair of quarter wavelength feed lines connected to the excitation probes, with a resistance element interconnected between the feed lines. The feed point of the antenna may be located near the center of the array, occupying a position normally occupied by one of the pairs of excitation probes.

Growing community of inventors

Kanagawa, Japan

Fumihiro Ito