Nanjing Tech University

Fulan Wei

Hui Zhu

Kai Guo

Siming Chen

Yu Gao

Zhenjiang Li

Disclosed is a method for preparing polylactone by ring opening, belonging to the technical fields of organic catalysis and polymer materials. The invention proposes a new catalytic mechanism, wherein an organic alcohol is used as an initiator to initiate ring opening polymerization of a cyclic monomer under the catalysis of an organic catalyst to obtain a polylactone; and the catalyst is a pyridinium salt. The present invention has the advantages of non-toxic reaction, simple conditions and controllable process; further, the invention can obtain a narrow molecular weight distribution in the absence of solution polymerization, and can effectively inhibit the occurrence of the transesterification compared with the catalysis of 4-(N,N-dimethylamino)pyridine.

Method for preparing polylactone by ring opening

Disclosed in the present invention is a preparation method for a polyester, relating to the technical field of organic catalysis and polymeric materials. The preparation method in the present invention comprises: (1) using pyridine and saccharin in a ratio of 1:1 to prepare pyridine saccharin salt in tetrahydrofuran at 60&#xb0; C. and separating the pyridine saccharin salt out in methanol and hexane. (2) Freeing out a small amount of pyridine from the pyridine saccharin salt in a heating state, catalyzing by the pyridine saccharin salt and pyridine a cyclic lactone or a carbonate to be ring-opened and polymerized to form the polyester; and the system has no other compound residues. (3) In the presence of an alcohol initiator, catalyzing by the pyridine saccharin salt the cyclic lactone to be ring-opened and polymerized to obtain the polyester. The catalytic system can efficiently synthesize a specific polylactone. Compared with a method for synthesizing a polyester by the use of a metal-containing catalyst in the prior art, the system has wide application. Moreover, the system is advantageous of no metal residue, narrow molecular weight distribution and no chain transesterification, and therefore has great commercial application potential in bio-pharmaceutical field and microelectronic field.

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Jiangsu, China

Fulan Wei