Bell Communications Research, Inc.

Frough K Shokoohi

Jean-Marie Tarascon

Philippe Barboux

Paul C Warren

Caroline N Schmutz

Li-ion rechargeable battery cell electrode and electrolyte/separator elements formulated as layers of plasticized polymeric matrix compositions are laminated with electrically conductive collector elements to form a unitary battery cell structure. Adhesion between the electrode and collector elements is enhanced by pretreatment of the collector elements in which a 0.25% to 3.0% solution of a polymeric material compatible with said matrix polymer is applied to a collector foil or grid and dried to form a coated film, and the resulting coated collector element is heated within the range of about 250.degree. to 450.degree. C. for about 5 to 60 seconds.

Method of making a laminated lithium-ion rechargeable battery cell

Methods are described for the low temperature preparation of the spinel LiMn.sub.2 O.sub.4 and layered LiCoO.sub.2 phases which are intercalable compounds of interest for use in lithium secondary batteries. These phases can be prepared in bulk or thick film form at temperatures less than 400.degree. C. using acetate precursors.

Method for preparation of LiCoO.sub.2 intercalation compound for use in

Method is described for the low temperature preparation of the spinel LiMn.sub.2 O.sub.4 phase which is an intercalable compound of interest for use in lithium secondary batteries. This phase can be prepared in bulk or thick film form at temperatures less than 400.degree. C. using acetate precursors.

Method for preparation of LiMn.sub.2 O.sub.4 intercalation compounds and

A Thin film electrode for a rechargeable (secondary) battery is prepared by electron beam deposition of LiMn.sub.2 O.sub.4, LiCoO.sub.2, or LiNiO.sub.2 on a smooth, amorphous substrate surface and in situ annealing of the deposited lithium composition at a temperature below about 500.degree. C. The amorphous nature of the substrate surface prevents epitaxial growth or ordered orientation of the minute composition crystallites thus formed. The finely granular structure of the resulting electrode thin film presents abundant surface area that enables a 4V battery to provide current densities in the range of 500 microamps/cm.sup.2. The low annealing temperature enables formation of the electrode structure and subsequent battery assembly directly upon semiconductor devices and integrated circuitry.

Rechargeable lithiated thin film intercalation electrode battery

A system for etching superconducting films of yttrium-barium-copper-oxide (YBa.sub.2 Cu.sub.3 O.sub.2) is disclosed. The etchant comprises ethylenediaminetetraacetic acid of varying concentrations in water or a water/glycerol mixture. The described etchant permits superconducting transition temperatures to remain unaffected within the experimental accuracy of 1.degree. C. Additionally, films do not require reoxygenation after etching, and the etchant is suitable for micropatterning using standard photolithography.

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Bedminster, NJ, United States of America

Frough K Shokoohi