Ethyl Corporation

Frederick W Frey

Everett M Marlett

Herbert D Kaesz

Steven W Johnston

John Y Lee

Marcelian F Gautreaux

Donald O Hutchinson

Walter E Foster

John H McCarthy

Process for retarding the decomposition of an amine alane, said process comprising contacting an amine alane which is substantially free of zirconium, hafnium, niobium, uranium, vanadium, and chromium, with an effective amount of a decomposition retarding agent selected from the class consisting of O.sub.2, CO, nitrogen axides and alkyl nitrites.

Stabilization of amine alanes

Process for retarding the decomposition of an amine alane, said process comprising contacting an amine alane which is substantially titanium-free, with an effective amount of a decomposition retarding agent selected from the class consisting of O.sub.2, CO, nitrogen oxides and alkyl nitrites.

Process for the preparation of silane and a tertiary amine alane, said process comprising reacting:

Preparation of silane and amine alanes

Amine alane decomposition is catalyzed by titanium. This effect of titanium can be suppressed by treating it with a passivating agent such as air, nitrous oxide, carbon monoxide and alkyl nitrites. Such agents may be used (1) to treat titanium-containing NaAlH.sub.4 preparations to be used in preparing amine alanes, or (2) to treat amine alanes containing titanium as an impurity, e.g. in finely divided form. Furthermore, the reaction of NaAlH.sub.4, amine, and a halide substance to produce an amine alane can be conducted in the presence of a passivating agent.

Tertiary phosphine oxides, such as triphenylphosphine oxide, are reduced to the corresponding phosphines in the presence of a trialkylaluminum/trialkyl borate reducing agent.

Process for preparing tertiary phosphines

Tertiary phosphine oxides, such as triphenylphosphine oxide, are reduced to the corresponding phosphines in the presence of a trialkylaluminum/boron trihalide reducing agent.

A process for producing aluminum from raw aluminum silicate ore, especially kyanite, including comminuting a natural or raw mined kyanite ore to a desired particle size, beneficiating the ore to form a kyanite concentrate, compacting the concentrate along with a carbon reductant into agglomerates such as briquettes, pellets or other suitable form and to a desired size, carbothermically reducing the compacts in an electric arc furnace into an aluminum-silicon alloy, comminuting the aluminum-silicon alloy into a desired particle size, reacting the aluminum-silicon alloy particles with hydrogen and propylene to form tripropylaluminum and dipropylaluminum hydride, pyrolyzing or decomposing the tripropylaluminum and dipropylaluminum hydride in an oil medium or bath to form an aluminum powder, filtering, washing and drying the aluminum powder, and fluxing and casting the aluminum powder into pigs or other suitable form, thereby forming a substantially pure aluminum product.

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Baton Rouge, LA, United States of America

Frederick W Frey