Mobil Oil Corporation

Phillips Petroleum Company

Mobile Oil Corporation

Frederick J Krambeck

Paul H Schipper

Klaus W Schatz

Samuel A Tabak

Amos A Avidan

Sergei Yurchak

William E Garwood

Albin Huss, Jr

Ajit V Sapre

Jonathan E Child

Michael S Sarli

Stephen J McGovern

Donald M Nace

John D Kushnerick

Anthony Y Kam

Richard C Kovacs

John E Sauer

Hartley Owen

Mohsen N Harandi

John Scott Buchanan

Stephen S Wong

James H Haddad

Francis G Dwyer

Kenneth J Del Rossi

Tai-Sheng Chou

Arthur A Chin

Clinton R Kennedy

Robert T Thomson

Carmo Joseph Pereira

Joe E Penick

Francis P Ragonese

J Scott Buchanan

William A Stover

William E Cormier, Jr

Gary M Pasquale

Susan Patricia Donnelly

Chiu T Lam

David H Anderson

Conroy D Anderson

Thomas R Melli

Chou Tai-Sheng

Tu Ching Cheng

Mou-neng M Lo

A component mapper is provided in connection with a process wherein a fluid stream having multiple physical components is modeled as a plurality of pseudo-components. Each physical component has a boiling point, and each pseudo-component has a pre-defined boiling point and includes all physical components from the fluid stream having approximately the pre-defined boiling point. Each pseudo-component in the model of the fluid stream has a varying pre-defined property and a varying amount. A plurality of sub-pseudo-components are defined for each pseudo-component such that the pseudo-component is replaceable therewith. Each sub-pseudo component has the pre-defined boiling point of the pseudo-component, a pre-defined value for the pre-defined property, and a varying amount. For each pseudo-component, a current value of the pre-defined property and a current amount of the pseudo-component are obtained, and a current amount for each sub-pseudo-component of the pseudo-component is then calculated. The pre-defined value of the pre-defined property and the calculated current amount for each sub-pseudo-component of each pseudo-component are then utilized in a real-time optimization process. In one embodiment of the present invention, the pre-defined property is density, and the amount is percentage weight and percentage volume.

Component mapper for use in connection with real-time optimization process

A system for containing and neutralizing a heavy vapor cloud from a potential source of hazardous vapor, such as HF from an HF alkylation unit, comprising a primary containment enclosure for containing and neutralizing a major portion of the vapor in the event of a leak, and a secondary fence line spaced from the primary enclosure for absorbing the vapor as the cloud passes therethrough.

Containment of heavy vapor clouds

A system for containment of heavy vapor cloud and aerosol from a potential source of hazardous vapor comprising walled surfaces surrounding the vapor source and a roof above the vapor source and forming with the walled surfaces an enclosure for the vapor source. The roof is porous with openings therethrough dimensioned for minimizing wind shear and extending over at least about 20% of the surface area of the roof, and a device is located within the enclosure for absorbing the vapor.

Containment of heavy vapor clouds and aerosols

A continuous alkylation process for the production of high octane gasoline comprising contacting a mixture of an isoparaffin and an olefin with a catalyst complex comprising BF3:H.sub.3 PO.sub.4 in a continuous hydrocarbon downflow reactor.

Alkylation process using co-current downflow reactor with a continuous

A process for thermally and catalytically upgrading a heavy feed in a single riser reactor FCC unit is disclosed. A heavy feed is added to a blast zone in the base of the riser, and sufficient hot regenerated FCC catalyst is added to induce both thermal and catalytic cracking of the heavy feed. A reactive quench material, which cools the material discharged from the blast zone is added to a quench zone downstream of the blast zone, to reduce temperature at least in part by undergoing endothermic reactions in the riser. Quench liquids can be distillable FCC feeds such as gas oil, slack wax, or alcohols or ethers. The quench material is added in an amount equal to 100 to 1000 wt % of the non-distillable material in the heavy feed. A preferred catalyst, with a high zeolite content, is used which retains activity in the quench despite initial contact with the heavy feed, which tends to overwhelm conventional FCC catalysts.

Catalytic cracking of coke producing hydrocarbons

A process has been discovered for the conversion of C.sub.5 -C.sub.7 olefinic hydrocarbons, such as those contained in FCC light naphtha, to iso-butene-rich and isoamylene-rich streams in an integrated process for the production of MTBE and TAME. The process involves the initial separation of the isoamylene-rich C.sub.5 -fraction of the feedstream which is converted to TAME. The C.sub.6 -C.sub.7 fraction plus unreacted C.sub.5 's are converted by olefin interconversion with medium pore zeolite catalyst into an isobutylene and isoamylene-rich stream which is then used as feedstream for etherification to MTBE and TAME.

Process for the production of tertiary alkytl ethers from FCC light

A process for alkylation of isoparaffins and olefins employing a fixed bed of catalyst. The catalyst composition includes an unpromoted synthetic zeolite. The alkylate product contains highly branched paraffins and has an octane suitable for blending into motor gasolines. Alternatively multiple fixed beds can be employed with direct effluent recycle or split olefin feeds.

Process for alkylating olefins and isoparaffins in a fixed bed reactor

An FCC catalyst regeneration technique in which the catalyst is regenerated in a dense bed regenerator. Regeneration effluent gases are collected from different parts of the regenerator vessel in a common collection zone and passed through the catalyst separation cyclones from the common collection zone. The cyclones may be arranged with their inlet horns adjacent one another in the common collection zone or a cyclone inlet manifold with a common inlet may be connected to the cyclone inlets. The inlet port to the manifold may be extended to form an elongated vertical duct through which regeneration effluent gases and entrained catalyst pass from the dilute phase of the dense bed to the cyclone so that mixing of the effluent gases is promoted to ensure combustion in residual quantities of oxygen present in the effluent gases before the gases enter the cyclones. Improved operating flexibility is obtained together with a reduced likelihood of cyclone damage as a result of localized high temperature excursions. In addition, the NO.sub.x level of the regenerator stack gases is reduced.

Fluid catalytic cracking regeneration with reduction of nitrogen oxide

Modified ZSM-5 type zeolite catalyst is prepared by controlled aging in a moving bed catalytic cracking unit. The modified catalyst exhibits significant olefin isomerization activity and reduced paraffin cracking activity. Hydrocarbons are cracked to products boiling in the motor fuel range, e.g., gasoline, by using the modified catalyst mixture comprising a ZSM-5 type zeolite and a conventional cracking catalyst. The ZSM-5 type zeolite is treated with partial pressure steam under conditions which increase the gasoline octane number of the product fuel without decreasing gasoline plus distillate yield. A process for changing a catalytic cracking unit's inventory from a conventional catalyst to a modified ZSM-5 type containing catalyst is also disclosed.

Method of adding zsm-5 containing catalyst to fluid bed catalytic

A fluidized catalytic riser cracking process is disclosed wherein a quench stream, preferably water or steam, is injected downstream of the riser reactor outlet to decrease the residence time and temperature of a majority of the hydrocarbons in a reactor vessel accepting a riser reactor effluent.

Quenched catalytic cracking process

A continuous multistage catalytic conversion system for upgrading lower olefins comprising

Multistage system for conversion of lower olefins with reactor quenching

Octane improvement of gasoline in catalytic cracking without decreasing

An FCC catalyst regeneration technique in which the catalyst is regenerated in a dense bed regenerator. Regeneration effluent gases are collected from different parts of the regenerator vessel in a common collection zone and passed through the catalyst separation cyclones from the common collection zone. The cyclones may be arranged with their inlet horns adajcent one another in the common collection zone or a cyclone inlet manifold with a common inlet may be connected to the cyclone inlets. The inlet port to the manifold may be extended to form an elongated vertical duct through which regeneration effluent gases and entrained catalyst pass from the dilute phase of the dense bed to the cyclone so that mixing of the effluent gases is promoted to ensure combustion in residual quantities of oxygen present in the effluent gases before the gases enter the cyclones. Improved operating flexibility is obtained together with a reduced likelihood of cyclone damage as a result of localized high temperature excursions. In addition, the NO.sub.x level of the regenerator stack gases is reduced.

Fluid catalytic cracking regeneration with reduction of nitrogen

The separation and recovery of liquid hydrocarbons in a FCC gas plant is removed by integrating therewith an oligomerization reactor which produces liquid hydrocarbons from one of several olefinic streams within the gas plant.

Catalytic conversion of light olefinic feedstocks in a FCC plant

The invention combines two unit operations i.e. fluid catalytic cracking (FCC) and circulating fluid bed (CFB) boiler technologies. The circulating solid inventory of the CFB boiler is introduced to the bottom of a conventional FCC unit to supply the endothermic heat of reaction. A once-through FCC catalyst is introduced under high-temperature, short residence time conditions whereby improved yields are achieved through the reduction of coke made in the FCC unit.

FCC unit combined with a circulating fluid bed combustor

Growing community of inventors

Cherry Hill, NJ, United States of America

Frederick J Krambeck