Aluminum Company of America

Fred S Williams

Anthony J Perrotta

Paul J The

Thinnalur J Sivakumar

Sodium oxalate is precipitated from spent Bayer process liquor by mixture with a low total alkalinity (TA) sodium oxalate seed solution that has been treated with two or more adsorbents to remove organic poisons from the sodium oxalate. The adsorbents are preferably two different adsorbents selected from activated carbon, ESP dust, calcium oxide and magnesium oxide. Surprisingly, combination treatments with activated carbon and ESP dust are most effective even though ESP dust alone has little effect on oxalate removal.

Adsorbent combinations for enhanced removal of sodium oxalate from bayer

Wet oxidation of organic contaminants in aqueous sodium aluminate solutions is enhanced when a heated and oxygenated solution is passed through a packed bed containing a metal packing member that is chemically inert to sodium aluminate solutions at elevated temperatures. Process temperature is about 180.degree.-300.degree. C. and oxygen partial pressure is at least about 345 kPa. The packed bed has a packing surface of at least 100 square meters per cubic meter bed volume and preferably at least 50% free space.

Growing community of inventors

Victoria, TX, United States of America

Fred S Williams