The Dow Chemical Company

Fred A Sherrod

Allen R Smith

Dane Chang

Rebecca G Moore

Bobby R Ezzell

William L Howard

Joanne D Burger

Gregg E Lewis

Philip W Dellinger

Phillip W Dellinger

This invention includes catalysts comprising rhenium (atomic number 75), nickel, cobalt, boron and copper and/or ruthenium impregnated on a support material and a process for preparing said catalyst, said process comprising (i) impregnating a mixture of metals comprising rhenium, cobalt, copper and/or ruthenium, boron and nickel on a support material selected from the group consisting of alpha-alumina, silica, silica-alumina, kiesolguhrs or diatomaceous earths, and silica-titanias; and (ii) activating said catalyst by heating the catalyst in the presence of hydrogen at an effective temperature preferably in the range of about 150.degree. C. to about 500.degree. C. for a sufficient period preferably of from about 30 minutes to about 6 hours. A further feature of the present invention is a method for producing amine products by the catalytic amination of alkane or arylalkane derivatives including epoxides, monols, diols, polyethers, polyols, alcoholamines, ketones, imino compounds iminoalcohols, ether alcohols, and mixtures thereof, said process comprising contacting said lower alkane or arylalkane derivatives with ammonia and/or reactant amine at an effective temperature preferably from 150.degree. C. to about 500.degree. C. and in the presence of hydrogen and the nickel-rhenium-cobalt-boron-copper and/or ruthenium catalyst as described hereinabove.

Catalyst and process for producing amines

This invention includes catalysts comprising rhenium (atomic number 75), nickel, cobalt, boron and copper and/or ruthenium impregnated on a support material and a process for preparing said catalyst, said process comprising (i) impregnating a mixture of metals comprising rhenium, cobalt, copper and/or ruthenium, boron and nickel on a support material selected from the group consisting of alpha-alumina, silica, silica-alumina, kieselguhrs or diatomaceous earths, and silica-titanias; and (ii) activating said catalyst by heating the catalyst in the presence of hydrogen at an effective temperature preferably in the range of about 150.degree. C. to about 500.degree. C. for a sufficient period preferably of from about 30 minutes to about 6 hours. A further feature of the present invention is a method for producing amine products by the catalytic amination of alkane or arylalkane derivatives including epoxides, monols, diols, polyethers, polyols, alcoholamines, ketones, imino compounds iminoalcohols, ether alcohols, and mixtures thereof, said process comprising contacting said lower alkane or arylalkane derivatives with ammonia and/or reactant amine at an effective temperature preferably from 150.degree. C. to about 500.degree. C. and in the presence of hydrogen and the nickel-rhenium-cobalt-boron-copper and/or ruthenium catalyst as described hereinabove.

A process using a particular catalyst in the dehydrogenation of an alkyl aromatic compound, e.g., ethylbenzene, to form a vinyl aromatic compound, e.g., styrene. The catalyst comprises a calcination product of (a) at least one iron oxide; (b) at least one carbonate, bicarbonate, oxide or hydroxide of potassium and/or cesium; (c) an oxide, carbonate, nitrate or hydroxide of cerium, or a mixture of at least two thereof; (d) an hydraulic cement; (e) an hydroxide, carbonate, bicarbonate, acetate, oxalate, nitrate, or sulfate of sodium, in an amount sufficient to provide from 0.2 to 10 percent sodium, calculated as sodium oxide, by weight of the calcined catalyst; and (f) a carbonate, sulfate, or hydroxide, of calcium or a mixture of at least two thereof, in an amount sufficient to provide from 1.5 to 20 percent calcium, calculated as calcium oxide, by weight of the calcined catalyst. The catalyst has improved moisture stability compared to catalysts in which at least one of (e) or (f) is not met.

Process using a catalyst to dehydrogenate an alkyl aromatic compound

A calcined dehydrogenation catalyst comprising at least one sodium compound and one calcium compound is disclosed. The catalyst exhibits improved moisture stability as evidenced by improved crush strength and resistance to swelling and cracking.

Dehydrogenation catalyst and process for preparing same

A process for the alkylation/transalkylation of benzene is improved by the use of a catalyst prepared by exchanging a sodium Y zeolite with an ammonium salt to replace from about 40 percent to about 90 percent of the sodium ions with ammonium ions; calcining the resulting ammonium-sodium zeolite in steam under conditions sufficient to reduce the unit cell size to about 24.48 to 24.60 angstroms; contacting the calcined catalyst with a rare earth salt and an aluminum salt either simultaneously or sequentially; and calcining the catalyst a second time in the absence of steam.

Alkylation process using dual metal ultrastable Y zeolite

A dehydrogenation catalyst containing iron and promoted with potassium and cerium has been shown to have improved activity when a copper compound is added thereto as a component. The improvement in activity is obtained without substantially sacrificing selectivity.

Dehydrogenation catalyst

An improved dehydrogenation catalyst, useful in converting alkylaromatics to alkenylaromatics, e.g. ethylbenzene to styrene, has been discovered which contains lower amounts of iron and relatively larger amounts of cerium and potassium than those known to the art.

Process for changing the volatile aluminum chloride complex contained in an ethylbenzene production stream into a non-volatile, aluminum chloride product of a nature such that the ethylbenzene in the stream can be separated from the aluminum chloride catalyst by flash distillation. Conversion of the volatile aluminum chloride complex to a non-volatile aluminum chloride product is accomplished by adding selected alcohols, aldehydes, or ketones to the ethylbenzene stream.

Anhydrous separation of volatile aluminum chloride complex from an

A process for recovering monomeric glycols and glycerine from polyoxyalkylene glycols and polyglycerines which comprises heating the polymeric compounds together with a lower saturated mono-carboxylic acid, containing from 2 to 4 carbon atoms such as acetic acid, in the presence of a strong acid, e.g. sulfuric acid, or a strong acid cation exchange resin. The product, which is the diester of the monomeric glycol or the triester of glycerine, is recovered and subsequently hydrolyzed to obtain the desired monoglycol or glycerine product. If it is desired to obtain the ester itself, the latter step of hydrolyzing can be omitted.

Process for obtaining glycols and glycerine or di- and triesters thereof

The title compounds correspond to formulas O--CH.sub.2 CH.sub.2 NH.sub.3.sup..sym.).sub.2.2HSO.sub.4.sup..crclbar. and )--CH.sub.2 CH.sub.2 NH.sub.3.sup..sym.).sub.2 SO.sub.4.sup..crclbar.. They are prepared by (A) reacting by contacting HOCH.sub.2 CH.sub.2 NH.sub.3.sup..sym. HSO.sub.4.sup..crclbar. with .sup..sym. NH.sub.3 CH.sub.2 CH.sub.2 O--SO.sub.3.sup..crclbar. in the presence of a catalytic amount of sulfuric acid at a temperature greater than about 140.degree. C, thereby forming a reaction product comprising O--CH.sub.2 CH.sub.2 NH.sub.3.sup..sym.).sub.2. 2HSO.sub.4.sup..crclbar. ; and (B) reacting by contacting the reaction product of step (A) or O--CH.sub.2 CH.sub.2 NH.sub.3.sup..sym.).sub.2 . 2HSO.sub.4.sup..crclbar. with a methanol solution of HOCH.sub.2 CH.sub.2 NH.sub.2, thereby forming O--CH.sub.2 CH.sub.2 NH.sub.3.sup..sym.).sub.2 SO.sub.4.sup..crclbar. as a solid precipitate. The latter compound is extremely useful as a chemical intermediate in forming bis(2-aminoethyl) ether.

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Lake Jackson, TX, United States of America

Fred A Sherrod