Siemens Aktiengesellschaft

Frank Vangaever

Jacky Vanhumbeeck

Luc Boone

Laurent Danneels

Luc Demaegd

A method for determining current efficiency in a galvanic bath employs a measuring cell within which a sample is introduced from the galvanic bath. In this sample, onto a preferably rotating electrode metal is precipitated. A negative voltage is applied at constant current during a first predetermined time during the precipitating. Thereafter, the precipitated layer is anodically eroded by use of a suitable electrolyte solution upon pole-reversal of the DC voltage. The current efficiency is then calculated.

Method for determining current efficiency in galvanic baths

An additive-free, fast-precipitating electrolyte bath for precipitating lustrous, crack-free palladium layers on workpieces is formulated, by successively adding to distilled water heated up to about 90.degree. C., phosphoric acid, sufficient ammonia to neutralize the phosphoric acid and palladium, in the form of palladium chloride. After dissolution of the palladium salt, the operating pH value is adjusted by additions of ammonia or phosphoric acid as required and the volume of the bath can be increased as desired by additions of further distilled water. The bath can be filtered prior to use.

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Brugge, Belgium

Frank Vangaever