Pall Corporation

Frank Onyemauwa

Hassan Ait-Haddou

Marcin Stasiak

Lixiang Xiao

Khaled Abdel-Hakim Helmy Aamer

Amarnauth Singh

Samuel Nochumson

Jian Qiu

Ying Labreche

Lauren A Spielman

Shant M Hambarsoomian

Jonathan Haigh

Disclosed is a porous medium, e.g., a bead, fiber, or membrane, comprising a porous support and a crosslinked polymer coating, wherein the polymer of the crosslinked polymer coating comprises at least one of polymerized monomer (A), at least one of polymerized monomer (B), at least one of polymerized monomer (C), wherein monomers (A)-(C) are as defined herein. Also disclosed are methods of preparing the porous medium and of treating a fluid containing a desired protein and one or more negatively charged species or of removing metals from organic solvents used in the microelectronics industry.

Salt tolerant porous medium

Disclosed is an anion exchange porous medium, e.g., a porous membrane, that includes a porous support and a crosslinked cationic polymer coating disposed thereon, wherein the cationic polymer of the crosslinked cationic polymer coating comprises polymerized monomer (A) and polymerized monomer (B) wherein A and B are as defined herein. Also disclosed are methods of preparing the anion exchange porous medium and of treating a fluid containing a biologic.

Salt tolerant anion exchange medium

Disclosed are a copolymer, porous membranes made from the copolymer, and a method of treating fluids to remove metal ions using the porous membranes, for example, from fluids originating in the microelectronics industry, wherein the copolymer includes monomeric units I and II, wherein monomeric unit I is of the formula A-X&#x2014;CH&#x2014;B, wherein A is Rf&#x2014;(CH)n, Rf is a perfluoro alkyl group of the formula CF&#x2014;(CF)&#x2014;, wherein x is 3-12, n is 1-6, X is O or S, and B is vinylphenyl, and monomeric unit II is vinylpyridine.

Fluoropolymers and membranes comprising fluoropolymers (II)

Disclosed are a copolymer, porous membranes made from the copolymer, and a method of treating fluids using the porous membranes to remove metal ions, for example, from fluids originating in the microelectronics industry, wherein the copolymer includes polymerized monomeric units I and II, wherein monomeric unit I is of the formula A-X&#x2014;CH&#x2014;B, wherein A is Rf&#x2014;(CH)n, Rf is a perfluoro alkyl group of the formula CF&#x2014;(CF)&#x2014;, wherein x is 3-12, n is 1-6, X is O or S, and B is vinylphenyl, the monomeric unit II is haloalkyl styrene, and optionally wherein the halo group of haloalkyl is replaced with an optional substituent, for example, ethylenediamine tetra acetic acid, iminodiacetic acid, or iminodisuccinic acid.

Fluoropolymers and membranes comprising fluoropolymers (I)

Disclosed are hydrophilic porous PTFE membranes comprising PTFE and an amphiphilic copolymer of the formula (I): wherein Rf, Rh, Rh, Y, m, n, and o are as described herein. Also disclosed are a method of preparing hydrophilic porous PTFE membranes and a method of filtering fluids through such membranes.

Hydrophilic porous polytetrafluoroethylene membrane (II)

Disclosed are fluoropolymers with low CWST values and porous membranes made from the fluoropolymers. The fluoropolymer is made up of polymerized monomeric units of the formula A-X&#x2014;CH&#x2014;B, wherein A is CF&#x2014;(CH), X is O or S, and B is vinylphenyl, and the fluoropolymer has a weight average molecular weight (Mw) of at least 100 Kd and/or a glass transition temperature of at least 33&#xb0; C. copolymer. The porous membranes are suitable for degassing a variety of fluids.

Fluoropolymers and membranes comprising fluoropolymers (III)

Disclosed is a fluorinated polymer of the formula: R&#x2014;S&#x2014;P, wherein R is a fluorocarbyl group, S is sulfur, and P is: (i) polyglycerol; (ii) poly(allyl glycidyl ether); (iii) a copolymer of glycidol and allyl glycidyl ether, the copolymer having one or more allyl groups; or (iv) poly(allyl glycidyl ether) or copolymer of glycidol and allyl glycidyl ether, wherein one more of the allyl groups have been replaced with a functional group as described herein. Also disclosed is a method of preparing the fluorinated polymer. The fluorinated polymer finds use in improving the hydrophilicity of porous hydrophobic membranes such as PTFE and PVDF.

Fluorinated polymer and use thereof in the preparation of hydrophilic membranes (vi)

Disclosed is a block copolymer of the formula: A-B-A (I) or A-B (II), wherein block A is: (i) a polymer of allyl glycidyl ether or (ii) a polymer of allyl glycidyl ether wherein one more of the allyl groups have been replaced with 1,2-dihydroxypropyl group or a group of the formula: &#x2014;(CH)&#x2014;S&#x2014;(CH)&#x2014;X, wherein a, b, and X are defined herein. The block copolymers find use as wetting agents in the preparation of porous membranes from aromatic hydrophobic polymers such as polyethersulfone. Also disclosed are methods of preparing such block copolymers and porous membranes therefrom.

Hydrophilic block copolymers and membranes prepared therefrom (II)

Disclosed are copolymers suitable for hydrophilically modifying the surface of fluoropolymer membranes. An example of the copolymers is: Also disclosed are a method of preparing the copolymers, a method of hydrophilically modifying porous fluoropolymer supports, hydrophilic porous fluoropolymer membranes prepared from the copolymers, and a method of filtering fluids by the use of the hydrophilic porous fluoropolymer membranes.

Hydrophilically modified fluorinated membrane (III)

Disclosed are block copolymers of the formula A-B-A (I) or A-B (II), comprising blocks A and B, wherein block A is a hydrophilic polymeric segment comprising polyglycerol and block B is an aromatic hydrophobic polymeric segment. The block copolymers find use as wetting agents in the preparation of porous membranes from aromatic hydrophobic polymers such as polyethersulfone.

Hydrophilic block copolymers and membranes prepared therefrom (I)

Disclosed is a porous membrane comprising a cellulosic material and a copolymer of the formula: A-B-A (I) or A-B (II), wherein block A, for example, polyglycerol, a polymer of allyl glycidyl ether, or a copolymer of glycidol and allyl glycidyl ether, or a polymer of allyl glycidyl ether or a copolymer of glycidol and allyl glycidyl ether wherein one or more allyl groups having been replaced by hydrophilic groups. Also disclosed is a method for preparing such a membrane.

Membranes comprising cellulosic material and hydrophilic block copolymer (V)

Disclosed is a hydrophilic porous membrane comprising a block copolymer of the formula: A-B-A (I) or A-B (II), wherein block A is (i) a copolymer of glycidol and allyl glycidyl ether, the copolymer having one or more allyl groups; or (ii) a copolymer of glycidol and allyl glycidyl ether, wherein one or more of the allyl groups of the copolymer have been replaced with 1,2-dihydroxypropyl group or a group of the formula: &#x2014;(CH)&#x2014;S&#x2014;(CH)&#x2014;X, wherein a, b, and X are as defined herein, and block B is an aromatic hydrophobic polymeric segment, for example, polyethersulfone. Also disclosure is a method of preparing such porous membranes.

Hydrophilic membranes and method of preparation thereof (IV)

Disclosed are block copolymers suitable for preparing hydrophilic porous membranes, wherein the block copolymers are of the formula: A-B-A (I) and A-B (II), wherein block A is (i) a copolymer of glycidol and allyl glycidyl ether, the copolymer having one or more allyl groups; or (ii) a copolymer of glycidol and allyl glycidyl ether, wherein one or more of the allyl groups of the copolymer have been replaced with 1,2-dihydroxypropyl group or a group of the formula: &#x2014;(CH)&#x2014;S&#x2014;(CH)&#x2014;X, wherein a, b, and X are as defined herein, and block B is an aromatic hydrophobic polymeric segment, for example, polyethersulfone. Also disclosed is a method of preparing such block copolymers.

Hydrophilic block copolymers and method of preparation thereof (III)

Disclosed are crosslinked porous membranes comprising a cellulosic material and an aromatic hydrophobic moiety or a copolymer of the formula A-B-A (I) or A-B (II), wherein block A, for example, polyglycerol, a polymer of allylglycidyl ether, or a copolymer of glycidol and allyl glycidyl ether, or a polymer of allyl glycidyl ether or a copolymer of glycidol and allyl glycidyl ether wherein one or more allyl groups having been replaced by hydrophilic groups. Block B is an aromatic hydrophobic moiety. An example of the aromatic hydrophobic moiety is polyethersulfone. Also disclosed is a method for preparing such membranes.

Crosslinked cellulosic membranes

Substrates comprising a solid support, a ligand, and a linker comprising at least one C, O, N, or S atom covalently connecting the solid support to the ligand, are disclosed, along with methods of using and making the substrates, and devices including the substrates.

Growing community of inventors

Pace, FL, United States of America

Frank Onyemauwa