Praxair Technology, Inc.

Union Carbide Corporation

Union Carbide Industrial Gases Technology Corporation

Frank Notaro

Frederick Wells Leavitt

Mark William Ackley

Jeffert John Nowobilski

Ravi Prasad

Joseph Timothy Mullhaupt

Arun Acharya

Mohamed Safdar Allie Baksh

Mohamed Safdar Baksh

Oscar W Haas

Guoming Zhong

Alan Barnard Stewart

Michael Scott Kane

Christian Friedrich Gottzmann

Neil Andrew Stephenson

David R Thompson

Gregory William Henzler

Kenneth C Kather

Atanas Serbezov

Dariush Habibollih Zadeh

This invention discloses an optimum set of adsorbents for use in H-PSA processes. Each adsorbent bed is divided into four regions; Regioncontains adsorbent for removing water; Regioncontains a mixture of strong and weak adsorbents to remove bulk impurities like CO; Regioncontains a high bulk density (&#x3e;38 lb/ft) adsorbent to remove remaining CO; and most of CHand CO present in Hcontaining feed mixtures; and Regioncontains adsorbent having high Henry's law constants for the final cleanup of Nand residual impurities to produce hydrogen at the desired high purity.

Process and adsorbent for hydrogen purification

A low void pressure swing adsorption system wherein flow movement and pressure pulse are influenced from the same source comprised of at least one hermetically sealed vessel containing an adsorbent bed with an inlet coupled to the adsorbent bed by way of an inlet header and an outlet coupled to the adsorbent bed by way of an outlet header. Void volume of the inlet and outlet headers can be limited to less than 20% of the adsorbent bed volume, preferably to less than 10%, and most preferably to less than 5%, by mounting high pressure source(s) and/or low pressure sink(s) proximate to, or nearly proximate to, the adsorbent bed/vessel. Low void volumes and reduced cycle times may be achieved in all bed configurations, including flat header beds, segmented beds, and vertical beds. Radial beds may be configured so that the void volume of the inlet and outlet headers is less than 50% of the volume of the radial adsorbent bed, preferably to less than 20%, and most preferably to less than

Low void adsorption systems and uses thereof

A process for making microporous membranes that incorporate selected gas selective species as surface sites in a controlled spacing and orientation manner and such membranes so formed being suitable for separating and purifying the selected gas from selected gas containing gas mixtures. An example is the use of oxygen selective transition element complexes (TECs) as surface sites for separating and purifying oxygen from oxygen-containing gas mixtures.

Process for making microporous membranes having selected gas-selective sites and the membranes so made

An improved pressure swing adsorption process and system for producing a high recovery of a highly purified product gas, such as argon, from a feed gas stream containing the product gas and impurity gases employs first and second adsorption stages with beds for adsorbing impurity gases. The system and process provides for sequential steps of: feed pressurization; simultaneous feed pressurization and product pressurization; adsorption; adsorption and purge; adsorption in the absence of purge; pressure equalization between beds; evacuation and depressurization of adsorbent bed; evacuation with product purge; evacuation without purge; and pressure equalization between beds.

Pressure swing adsorption process for high recovery of high purity gas

The present invention is a two stage PSA process for producing high purity oxygen from a feed air stream. Water, carbon dioxide and nitrogen are removed in a first stage. An oxygen selective adsorbent is used to adsorb oxygen in the second stage. High purity oxygen product is recovered during regeneration of the second stage. Importantly, the high purity of the oxygen product is achieved without inclusion of an oxygen rinse step in the process cycle. The high purity oxygen product is obtained by collecting the middle cut of the second stage effluent stream during regeneration.

Pressure swing adsorption method for production of an oxygen-enriched gas

The invention relates to the use of adsorbent materials that have been selected on the basis of their relationship between that material's intrinsic rate and equilibrium properties.

VPSA process using adsorbent materials

Separation of one or more fluidic components from a feed fluid containing a plurality of components is accomplished by adsorbent powder entrained in a stream of fluid, such as gas, and preferably is operated as a temperature swing adsorption process using waste thermal energy from a plant.

Fluid separation process and separation system therefor

A low pressure swing adsorption process and apparatus for the recovery of carbon dioxide from multi-component gas mixtures, utilizing the simultaneous purge and evacuation of opposite ends of the adsorber(s) to effect controlled depressurization in the adsorber bed(s) to maintain the constant purity of a carbon dioxide-enriched product stream recovered from the adsorber inlet(s).

Pressure swing adsorption process and apparatus

The invention comprises a PSA apparatus for the separation of a heavy component from a light component in a feed stream. The apparatus includes an adsorbent bed comprising either a mixture of adsorbents or composite adsorbent particles wherein each particle comprises two or more adsorbents. At least one of the adsorbents is comparatively weak and the other is comparatively strong. Another embodiment of the invention is a PSA prepurifier having a bed of adsorbent material which comprises a mixture of, or composite adsorbent particles wherein each particle comprises at least two adsorbents, at least one of the adsorbents being comparatively strong and at least another of the adsorbents being comparatively weak.

PSA apparatus and process using adsorbent mixtures

A PSA process involving the storage of products of various purities in segregated storage tanks for subsequent usage is disclosed. Products of increasing purities, admitted at the product end of the bed, are used during purging and repressurization steps. In addition, different composition streams collected at the feed end of the bed during the countercurrent depressurization step are admitted at the feed end of the bed, in the order of increasing product component content, during the rising pressure step(s). This cycle gives higher recovery and lower bed size factor than prior art PSA cycles.

PSA process and system

An adsorption process and system for the selective adsorption of a more readily adsorbable component, such as nitrogen, as from air or other feed gas mixture is carried out using a composite adsorbent bed containing different adsorbent materials positioned in separate zones in which the temperature conditions favor adsorption performance of the particular adsorbent material under applicable processing conditions in each zone. A method for the selection of the adsorbent materials is based on Adsorption Figure of Merit values.

Adsorption process and system using multilayer adsorbent beds

Multiple thermal pulses are employed to regenerate segments of an adsorber bed simultaneously in thermal swing adsorption processes. The invention is particularly applicable to air purification as it helps to reduce purge flow and improve regeneration efficiency.

Multi-thermal pulse PSA system

A PSA method incorporating the invention is applicable to the separation of a preferred gas from a mixture of the preferred gas and a less preferred gas. The PSA method uses an adsorbent bed including one or more layers of O.sub.2 equilibrium selective adsorbents, and comprises the steps of: pressurizing the adsorbent bed to a high pressure with a feed of air to enable the adsorbent bed to adsorb O.sub.2 ; extracting from the bed at bed pressure, a flow of N.sub.2 and storing at least some of the flow in a product tank; desorbing O.sub.2 from the adsorbent bed by feeding void gas in the bed enclosure to a storage tank and venting the adsorbent bed to a low pressure region; purging the adsorbent bed by feeding thereto the void gas from the storage tank; and repressurizing the adsorbent bed to an intermediate pressure with a flow of void gas from the storage tank.

Method for production of nitrogen using oxygen selective adsorbents

Segregated external gas storage tanks are used to store gases of varying purity for use in the purge and pressure equalization and product repressurization steps of pressure swing adsorption operations, thereby enabling the bed size factor and the power requirements of pressure swing adsorption-gas separation operations to be significantly reduced.

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Amherst, NY, United States of America

Frank Notaro