Kronos International, Inc.

Other

Frank Mersch

Uwe Wilkenhoener

Volker Juergens

Siegfried Bluemel

Volker Schmitt

Volker Jürgens

Alexander Breyder

Norbert Bendzko

The invention relates to composite pigment particles containing calcium phosphate, their manufacture and their use in coatings, plastics and laminates. The composite pigment particles contain titanium dioxide pigment particles and precipitated calcium phosphate. In one embodiment, the composite pigment particles additionally contain an inorganic and/or organic filler as an extender, preferably selected from the group comprising Ca, Ca&#x2014;Mg and Mg carbonates, natural and synthetic silicon dioxide and oxides. The composite pigment particles are manufactured in a combined process of dispersion and precipitation. Depending upon the combination selected, use of composite titanium dioxide pigment particles of the invention can provide improved optical properties such as tinting strength or permits pigment savings with little to no loss of optical properties. In particular, the composite pigment particles of the invention can be used to replace part or all of the titanium dioxide contained in the user's system.

Composite pigments containing calcium phosphate and method for their manufacture

The invention relates to the manufacture of composite pigments containing aluminum hydroxide, and their use for improving the pigment light-scattering efficiency in coatings, plastics, paper and laminates. The composite pigment particles contain pigment particles such as titanium dioxide and precipitated aluminum hydroxide and are manufactured by in-situ precipitation of aluminum hydroxide in an aqueous pigment particle suspension. Use of the composite pigment particles according to the invention, based on titanium dioxide, permits savings on pigment with little or no loss of optical properties. Alternatively, if the pigment content remains unchanged, it is also possible to achieve better optical properties.

Aluminiumhydroxide-containing composite pigments and method for production

The invention relates to a pigment composition for preparing pigmented matt coatings, such as matt paints and printing inks. Further, the invention relates to a process for preparing such pigment composition, and to a coating formulation containing such composition. Finally, the invention is directed to a pigmented matt surface of a substrate, and to the use of the pigment compositions disclosed herein for matting substrates.

Preparation of matt paints and printing inks

The invention relates to a method for the surface treatment of inorganic pigment particles with agglomerates of fine primary particles or single crystals of inorganic compounds, particularly of oxides or sulphates. The method is characterized in that the inorganic compounds are first precipitated from an aqueous solution under suitable pH conditions in a separate vessel in the form of fluffily structured agglomerates and/or single crystals. The precipitation product is subsequently added to an aqueous suspension of inorganic pigment particles. The method is particularly suitable for the surface treatment of titanium dioxide particles, in order to achieve high hiding power or high opacity when used in emulsion paints or laminates.

Method for surface treatment of inorganic pigment particles

The invention relates to the manufacture of pigment-containing composite pigment particles containing titanium dioxide pigment particles and at least one inorganic and/or organic filler as extender, as well as calcium carbonate that is precipitated in the process, and their use for improving the pigment light-scattering efficiency in coatings, plastics and laminates. The extender is preferably selected from Ca-, Ca&#x2014;Mg- and Mg-carbonates, natural and synthetic silicon dioxide and oxides and are manufactured in a combined process of precipitation and dispersion. Depending on the combination selected, the use of composite pigment particles according to the invention permits pigment savings with little or no loss of optical properties. Alternatively, if the pigment content remains unchanged, it is possible to achieve better values, e.g. for tinting strength. Particularly, a part or the whole TiOquantity in the user system can be replaced by the composite pigment particles according to the invention.

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Leichlingen, Germany

Frank Mersch