Clariant International Ltd

Sud-chemie Inc.

Sued-chemie IP Gmbh & Co. Kg

Süd-Chemie Ip Gmbh & Co Kg

Sud-chemie Ag

Frank Grossmann

Alfred Gerhard Hagemeyer

Gerhard Mestl

Martin Paulus

Karl-Heinz Stadler

David M Lowe

Michael A Urbancic

Richard Fischer

Alfred Hagemeyer

Jennifer Boyer

Klaus Wanninger

Silvia Neumann

Hans-Jörg Wölk

Mingyong Sun

Normen Szesni

Oliver Wegner

Hongyi C Hou

Claus Lugmair

Jürgen Koy

Wolfgang Gabriel

Tiberius Regula

Manuel Pfanzelt

Hans-Joerg Woelk

Jürgen Ladebeck

Van Klaas Gorp

This invention relates to heterogeneous catalysts useful for selective hydrogenation of unsaturated hydrocarbons, comprising palladium and optionally a promoter, supported on a substrate, having an uncoated BET surface area of ≤9 m/g, the surface being coated with an ionic liquid. Also described are methods of making the catalysts and methods of selective hydrogenation of acetylene and/or dienes in front-end mixed olefin feed streams.

Catalyst composition for selective hydrogenation with improved characteristics

The invention relates to a copper manganese-based catalyst on the basis of a tablet-form shaped catalyst body, comprising calcium aluminate as a binder, for hydrating carbonyl groups in organic compounds, characterised in that said shaped catalyst body comprises calcium aluminate in an amount of 0.5 to 20 wt. %. The invention also relates to the production of the catalyst and to the use of same in the hydration of carbonyl groups in organic compound.

Tablet-form copper manganese-based catalyst with increased stability against the action of acid

The invention relates to Cu&#x2014;Al&#x2014;Mn shaped catalyst bodies in extruded form, and to a process for their preparation. The shaped catalyst body is suitable for the hydrogenation of organic compounds containing a carbonyl function, in particular for the hydrogenation of aldehydes, ketones and carboxylic acids and/or their esters. In particular, the shaped catalyst body is suitable for the hydrogenation of fatty acids or their esters, such as fatty acid methyl esters, to form the corresponding alcohols and dicarboxylic acid anhydrides, such as maleic anhydride, or esters of di-acids and di-alcohols, such as butane diol.

Extruded Cu&#x2014;Al&#x2014;Mn hydrogenation catalyst

The invention relates to a process for preparing a shaped Cu&#x2014;Al catalyst body for the hydrogenation of organic compounds containing a carbonyl function. More particularly, the shaped catalyst body is suitable for the hydrogenation of aldehydes, ketones and of carboxylic acids or esters thereof, specifically of fatty acids or esters thereof, such as fatty acid methyl esters, to the corresponding alcohols such as butanediol. The present invention further relates to Cu&#x2014;Al catalysts obtainable by the preparation process.

Hydrogenation catalyst and process for production thereof by the use of uncalcined starting material

The invention relates to a catalyst molded body, which is produced by deforming a mixture of a metal oxide and a special graphite. The invention further relates to a method for producing the corresponding catalyst molded bodies and to the use of the catalyst molded bodies for catalytic reactions in which hydrogen acts as a reaction reactant or reaction product, in particular hydrogenation, hydrogenolysis, and dehydrogenation reactions. The catalysts are characterized by an improvement in the activity and selectivity in particular in hydrogenation, hydrogenolysis, and dehydrogenation reactions, said improvement being achieved by adding special graphites.

Catalyst molded body containing graphite

A method for producing a shaped Cu&#x2014;Zn catalyst for hydrogenating organic compounds containing a carbonyl function. The shaped catalyst is suitable for hydrogenating aldehydes, ketones and also carboxylic acids and/or their esters, fatty acids and/or their esters, such as fatty acid methyl esters, to the corresponding alcohols, dicarboxylic anhydrides, such as maleic anhydride (MAn), or esters of diacids to dialcohols, such as butanediol. The present invention further relates to Cu&#x2014;Zn catalysts obtainable by the production method.

Hydrogenation catalyst and method for producing same

A highly active nickel carrier catalyst based on aluminium oxide has a nickel content of approximately 20 to 70 wt.-% (as Ni) and optionally comprises a bonding agent and optionally a promoter, selected from the compounds of Mg, Ti, Pb, Pt, Ba, Ca and/or Cu, wherein the size of the Ni crystallites in the reduced state is in the range of approximately 3.5 to 4.5 nm and the distortion factor of the Ni crystallites is approximately 2 to 5%. In a method for the reduction of the content of sulphur compounds in hydrocarbon-based fuels by selective adsorption of the sulphur compounds on a nickel catalyst, a nickel catalyst based on aluminium oxide is used, particularly the nickel catalyst described above. A nickel catalyst based on aluminium oxide may be used for reducing the sulphur compound content in hydrocarbon-based fuels by selective adsorption of the sulphur compounds on said catalyst and/or for the hydrogenation of aromatic compounds.

Method for the desulfurization of fuels and highly active nickel carrier catalyst based on aluminum oxide suitable for said method

A nanocrystalline supported or unsupported copper oxide with a residual carbon content of &#x3c;10% and a BET surface area &#x3e;95 m/g. Further, a method for the production of a supported, or unsupported nanocrystalline copper oxide is disclosed, as well as the use thereof in catalysis, in particular in the steam reforming of methanol or in the hydrogenation of esters.

Nanocrystalline copper oxide and method for the production thereof

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Munich, Germany

Frank Grossmann