Cryovac, Inc.

W. R. Grace Co.-conn.

Frank Bryan Edwards

Drew V Speer

Thomas Duane Kennedy

Janet W Rivett

Scott W Beckwith

Thomas Andrew Blinka

Nathanael Rustia Miranda

Jeffrey A Thomas

Stephen Floyd Compton

Cynthia Louise Ebner

Ronald L Cotterman

Mitchell W Smith, Sr

Brian L Butler

Roger J Morrissette

Rachel McDowell

Scott Beckwith

Rachel Mcdowell

Janet Rivett

The present invention is directed to a multilayer film having an active oxygen barrier layer that comprises an oxygen scavenging composition that is a blend of a thermoplastic resin (A) having carbon-carbon double bonds substantially in its main chain, a transition metal salt (B), and an oxygen barrier polymer (C) having oxygen barrier properties that can be further enhanced by exposing the composition to a source of ionizing radiation e.g., electron beam radiation. Irradiation improves the oxygen scavenging abilities of the oxygen scavenging composition so that oxygen can be intercepted and scavenged as it passes through the film. The resulting irradiated multilayer film has improved active barrier properties in comparison to the same film prior to irradiation. As result, the multilayer film of the present invention can be used in packaging applications to help maintain a low oxygen atmosphere in the interior of a package.

Multilayer film having an active oxygen barrier layer with radiation enhanced active barrier properties

The present invention provides a multilayer film having an active oxygen barrier multilayer core comprising at least one of 1) an active oxygen barrier layer is sandwiched between two passive oxygen barrier layers, or 2) a passive oxygen barrier layer is sandwiched between two active oxygen barrier layers. In one embodiment, the active barrier layer comprises a composition that is a blend of a thermoplastic resin (A) having carbon-carbon double bonds substantially in its main chain, a transition metal salt (B), and an oxygen barrier polymer (C). In some embodiments the active barrier layer may also include a compatibilizer (D). The passive oxygen barrier layers help to maintain the oxygen barrier properties of the multilayer film after the oxygen absorbing capacity of the active barrier layer has been exhausted. As a result, the useful shelf life of the film can be extended.

Multilayer film having passive and active oxygen barrier layers

A method of triggering a film containing an oxygen scavenger includes providing composition including a peroxide; and packaging the composition in a film including an oxygen scavenger; whereby the oxygen scavenger is triggered in the absence of ultraviolet light, visible light, and electron beam radiation by exposure to the peroxide or an associated enriched oxygen environment.

Method of triggering a film containing an oxygen scavenger

A package includes a non-thermoformed thermoplastic pouch including a first and second panel; and an optical data storage medium disposed in the pouch; wherein the pouch comprises an oxygen barrier material, and an oxygen scavenger. Two methods of making a package include (1) providing a web; providing an optical data storage medium; forming a non-thermoformed pouch from the thermoplastic web, the pouch comprising a first and second panel; placing the optical data storage medium in the pouch; and sealing the pouch; wherein the web includes an oxygen barrier material and an oxygen scavenger; or (2) providing a first and second web; providing an optical data storage medium; forming a non-thermoformed pouch from the webs; placing the optical data storage medium in the pouch; and sealing the pouch; wherein at least one of the webs includes an oxygen barrier material, and at least one of the webs includes an oxygen scavenger.

Oxygen scavenging form/fill/seal package for limited lifetime optical data storage media

A package includes a thermoformed web or support member, an optical data storage medium disposed in a cavity of the thermoformed web, or on the support member; and a covering web disposed on the optical data storage medium, and on the thermoformed web or support member, and in sealing relationship to the thermoformed web or support member; where each of the thermoformed web or support member, and the covering web, includes an oxygen barrier; and where at least one of the thermoformed web or support member, and the covering web, includes an oxygen scavenger. Methods of making the package are also disclosed. In addition to, or alternatively to including the oxygen scavenger in at least one of the thermoformed or support member, and the covering web, the oxygen scavenger can be disposed on the optical medium, e.g. in the form of a disc, coating, label, pellet, wafer, or flattened sachet.

Packaging for limited lifetime optical data storage media

An easy-opening feature in a flexible package is provided by forming a tear feature in the package material by slitting, perforating, or otherwise forming a stress riser in the material, and affixing a label to the package material so that the label adheres to the tear feature. The formation of the tear feature and affixing of the label are performed prior to wrapping a product in the package material and sealing the material, and preferably are performed while the package material is moving along a path in a packaging apparatus. The label in one embodiment includes a detachable middle portion that tears free of the rest of the label upon pulling the detachable portion, such that remaining portions of the label remain on the package adjacent the opening created by the tear feature.

Easy-opening feature for flexible packages and process and apparatus for forming same

An article of manufacture includes an oxygen scavenger and a zeolite. The article can be in the form of e.g. a film or sealing compound. A package can be made from the article for containing an oxygen-sensitive article such as food. The zeolite reduces migration of odor causing by-products of the oxygen scavenging process. A method of making an article of manufacture having reduced migration of by-products of an oxygen scavenging reaction includes providing an article including an oxygen scavenger and a zeolite; and exposing the article to actinic radiation.

Zeolite in packaging film

An article of manufacture includes an oxygen scavenger and a zeolite. The article can be in the form of e.g. a film or sealing compound. A package can be made from the article for containing an oxygen-sensitive article such as food. The zeolite reduces migration of odor causing by-products of the oxygen scavenging process. A method of making an article of manufacture having reduced migration of byproducts of an oxygen scavenging reaction includes providing an article including an oxygen scavenger and a zeolite; and exposing the article to actinic radiation.

Growing community of inventors

Simpsonville, SC, United States of America

Frank Bryan Edwards