Umicore Ag & Co. Kg

Degussa - Huls Ag

Viessmann Werke Gmbh Co. Kg

Dmc2 Degussa Metals Catalysts Cerdec Ag

Dmc2 Degussa Metal Catalysts Cerdec Ag

Frank Baumann

Stefan Wieland

Klaus Heikrodt

Frank Adam

Rainer Ahlborn

Peter Britz

Matthias Duisberg

Stefan Andersch

The invention provides a multistep process for preparing a low-sulfur reformate gas for use in a fuel cell system. The process comprises catalytic steam reforming of a reactant gas mixture comprising sulfur-containing hydrocarbons and steam in a first step to make a reformate, reducing the carbon monoxide content of the reformate in a second step, passing the reformate over a sulfur absorber either directly after the first step or after passage through the second step, and desorbing the sulfur components optionally absorbed on the catalysts in the reforming and reducing process steps by periodically raising the temperature so as to cause the sulfer components to pass to the absorber, wherein the temperature of the absorber during operation of the process is always kept within a temperature interval which is an optimum for the absorber.

Process for preparing a low-sulfur reformate gas for use in a fuel cell system

The invention relates to a catalyst and a process for the autothermal, catalytic steam reforming of hydrocarbons using the catalyst. The catalyst has a multilayer structure and comprises a lower catalyst layer located directly on a support body and an upper catalyst layer located on the lower catalyst layer, with the lower catalyst layer preferentially catalysing the partial oxidation and the upper catalyst layer preferentially catalysing steam reforming. In a further embodiment, a three-layer catalyst having a further catalyst layer for the carbon monoxide conversion (water gas shift reaction) is described. Each catalyst layer comprises at least one platinum group metal on an oxidic support material. The steam reforming process is carried out in an adiabatic process by passing a feed mixture of hydrocarbons, oxygen and water or water vapour which has been heated to a preheating temperature over the multilayer catalyst. Catalyst and process are used for producing hydrogen-containing fuel gases in reformer systems, preferably for fuel cells.

Catalyst for autothermal reforming of hydrocarbons with increased water gas shift activity

A process for autothermal catalytic steam reforming of hydrocarbons by passing a reactant mixture of hydrocarbons, oxygen and water or water vapor, heated to a preheating temperature, over a catalyst. The process is operated adiabatically and the catalyst has a coating of a catalyst material on a support structure, the catalyst material containing at least one platinum group metal on an oxidic support material which can be aluminum oxide, silicon dioxide, titanium dioxide or mixed oxides thereof and zeolites.

Process for the autothermal catalytic steam reforming of hydrocarbons

The invention relates to a process for catalytic autothermal steam reforming of alcohols having two or more carbon atoms by directing a preheated educt or reactant mixture of the alcohols, oxygen and water or steam over a catalyst. The process is conducted in an adiabatic manner wherein the catalyst comprises at least one platinum group metal on an oxidic support selected from the group consisting of aluminum oxide, silicon dioxide, titanium dioxide or mixed oxides thereof and zeolites, and that the educt or reactant mixture contains additional hydrocarbons, which are reformed at the same time as the alcohols.

Process for catalytic autothermal steam reforming of alcohols

The invention provides a combined heat and power plant with an integrated gas production system. The combined heat and power plant contains a steam reformer heated with a gas burner which converts a mixture of hydrocarbons and water vapour into a reformate gas stream containing hydrogen and carbon monoxide. The plant further contains a reactor system with several stages for removing carbon monoxide from the reformate gas stream. The plant also contains a heat exchanger for removing heat energy from the reformate gas stream and a fuel cell unit for producing electrical energy by catalytic reaction of the hydrogen contained in the reformate gas with oxygen in the fuel cell, wherein the reformate gas stream is supplied to the anode in the fuel cell unit and the anode waste gas is taken to the gas burner of the steam reformer as fuel, via a gas pipe. The reactor system for removing carbon monoxide from the reformate gas stream contains, according to one embodiment of the invention, a low temperature shift reactor and a downstream methanisation reactor and the heat exchanger for cooling the reformate gas stream leaving the steam reformer to the inlet temperature of the low temperature shift reactor is located in the reformate gas stream between the steam reformer and the low temperature shift reactor. This combined heat and power plant is operated according to the invention in such a way that the reformate gas contains 5 to 10 vol. % of unreformed hydrocarbon which enables the flame in the gas burner to be monitored using an ionisation detector when burning the anode waste gas in the gas burner of the steam reformer.

Combined heat and power plant and a process for the operation thereof

A method for catalytic conversion of carbon monoxide with water to carbon dioxide and water in a hydrogen-containing gas mixture (carbon monoxide conversion) by passing the gas mixture over a shift catalyst that is at an operating temperature for the carbon monoxide conversion. The method is carried out with a shift catalyst based on noble metals that is applied to an inert support element in the form of a coating.

Method for catalytic conversion of carbon monoxide in a hydrogen-containing gas mixture

A method for conversion of carbon monoxide to carbon dioxide and hydrogen with water in a gas mixture containing hydrogen and other oxidizable components. An oxidation-active noble metal shift catalyst is the catalyst. The necessary operating temperature of the catalyst is established and optionally maintained by partial oxidation of the oxidizable components of the gas mixture.

Method for catalytic conversion of carbon monoxide in a hydrogen-containing gas mixture with improved cold start behavior

A catalyst is disclosed for the steam reforming of alcohols, which contains a palladium/zinc alloy and zinc oxide as catalytically active components. The alloy catalyst is a catalytically active component deposited on at least one support material which can be aluminum oxide, aluminum silicate, titanium oxide, zirconium oxide, zeoliths and mixtures or mixed oxides thereof.

Growing community of inventors

Alzenau, Germany

Frank Baumann