Gulf Research & Development Company

Francis Ross Galiano

Raymond P Anderson

Joseph Calvin Davis

Robert William Hill

An improvement in the fibril formation process which includes dissolving at an elevated temperature an olefin polymer having an inherent viscosity of at least 3.5 in a hot hydrocarbon solvent, shearing the hot polyolefin solution to thereby orient the polymer molecules therein, passing the sheared solution through a cooling zone maintained at a temperature well below the precipitation temperature of the solution while maintaining the orientation of the polymer molecules within the solution to thereby precipitate by thermal means the polymer solute of the solution in the form of a solvent swollen fibrous strand, separating a substantial portion of the polymer solvent from the fibrous strand, chopping and then beating the chopped fibrous strand in a liquid which is a nonsolvent for the polymer and which is soluble in the polymer solvent for a time sufficient to break down the fibrous strand into a plurality of fibrils, and separating the fibrils from the nonsolvent liquid. The improvement consists of homogenizing the hot polyolefin/hydrocarbon solvent solution by passing same through a device, such as a gear pump, which imposes a high shear on the solution to thereby remove any small, invisible globules of partially dissolved polyolefin that may be present in the solution prior to the fibril formation steps of the process whereby paper sheets fabricated from the resultant fibrils are free of small knots and lumps and possess a completely smooth surface.

Fibril formation process

A process is disclosed for producing extremely fine polyamide/polystyrene fibers which include the steps of forming a molten blend consisting of from about 35 weight percent up to about 45 weight percent of a polyamide, preferably polycaprolactam and, correspondingly, from about 65 weight percent down to about 55 weight percent of a polystyrene, forcing this molten blend through an extrusion die to form a structure such as a strand, monofilament, sheet or film, melt drawing the extruded structure at a draw ratio of at least 4:1 to orient the same and thereby obtain a fibrillatable structure, and thereafter mechanically fibrillating the oriented, fibrillatable structure by cold drawing whereby the structure spontaneously and completely breaks up into extremely fine polyamide/polystyrene fibers. The blend may optionally additionally contain up to about 15 weight percent of an ethylene/acrylic acid copolymer containing about 20 weight percent acrylic acid.

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Overland Park, KS, United States of America

Francis Ross Galiano