Institut Francais Du Pe'trole

Other

Fran&ccedil;ois Ropital

Paul Broutin

Xavier Longaygue

Philippe Lecour

Laurent Antoni

Jos&eacute; Mallen Herrero

Pascal Nisio

Marcel Fran&ccedil;ois

Alain Bertoli

Use of austenitic stainless steels in applications requiring anti-coking properties

A passivation method for the metallic surface of a nickel and iron-based superalloy which is used as the constituent material of reactor or furnace walls is described, in which the superalloy is coated on at least one of its surfaces which comes into contact with a corrosive atmosphere containing either hydrocarbons at high temperature or containing oxidizing gases at high temperature, with at least two successive layers resulting from successive chemical vapour deposition of its one or more constituent elements, the external phase, resulting from chemical vapour deposition of at least one silicon compound and the layer(s) deposited between the superalloy surface, and the external layer resulting from chemical vapour deposition of at least one of a metal or metalloid.

Passivation method for metallic articles of nickel and iron-based superalloy

Chromized refractory steel, a process for its production and its uses in anti-coking applications

The invention concerns a method for manufacturing steel wire comprising the following steps: manufacturing a reinforcing wire of sizeable length by rolling or hot wire drawing from steel containing the following elements: 0.18% to 0.45 % C, 0.4% to 1.8% Mn, 1% to 4% Cr, 0.1% to 0.6% Si, 0% to 1.5% Mo, 0% to 1.5% Ni, at most 0.01% S and 0.02% P, the reinforcing wire having, after being rolled or hot drawn, a temperature at least higher than the AC3 temperature, preferably by 50 to 200&deg; C. and in particular by 100 to 150&deg; C.; winding the wire in reels before air cooling the raw manufacturing wire to obtain a HRC hardness not less than 40 and preferably higher than 45. In a variant, the method consists in quenching and tempering so that the wire has a hardness between 20 HRC and 35 HRC. The invention also concerns a reinforcing wire and a flexible tube for carrying effluents.

Method for manufacturing self-hardening steel wire, reinforcing wire and application to a flexible duct

In order to produce elements for furnaces, reactors or conduits on the walls of which coke can appear, steels are used with a composition which is adapted to resist coking comprising, by weight, at most 0.25% of C, 1.5% to 5% of Si, 4% to 10% of Cr, 0.5% to 2% of Mo, 0.3% to 1% of Mn, at most 0.030% of S and at to most 0.03% of P, the complement to 100% being essentially iron. Novel steel compositions for use in these applications are those which comprise, by weight, at most 0.25% of C, more than 2.5% and up to 5% of Si, 4% to 10% of Cr, 0.5% to 2% of Mo, 0.3% to 1% of Mn, at most 0.03% of S and at most 0.03% of P, the complement to 100% being essentially iron.

Apparatus comprising furnaces, reactors or conduits having internal walls comprising at least partly of a steel alloy

Growing community of inventors

Rueil Malmaison, France

François Ropital

Growing community of inventors

Rueil Malmaison, France

Fran&ccedil;ois Ropital

François Ropital